期刊
INORGANIC CHEMISTRY
卷 55, 期 14, 页码 6833-6835出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b00901
关键词
-
资金
- 973 Program [2014CB845603]
- Natural Science Foundation of China [21390390, 21301145, 21473139, 20720150038]
A 64-nuclearity silver cluster encapsulating a unique POM anion [(MnMn2Mo14O56)-Mn-III-Mo-IV](17-) has been synthesized. The formation of the templating core performs a reassembly process for increasing nuclearities from {MnMo9} to {Mn3Mo14}. It represents a rare inorganic meso anion containing mixed-valent Mn that is built up by D-{(MnMo7)-Mo-IV} and L-{(MnMo7)-Mo-IV} units connecting together through a {Mn-III} fragment.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据