Article
Engineering, Environmental
Sabarish Radoor, Jasila Karayil, Aswathy Jayakumar, Jyotishkumar Parameswaranpillai, Suchart Siengchin
Summary: In this study, ZSM-5 zeolite was successfully modified for the removal of methylene blue, showing high adsorption capacity under optimized conditions. Factors affecting adsorption efficiency include zeolite dosage, initial dye concentration, temperature, pH, and contact time, and the adsorption process follows Freundlich isotherm and pseudo-second-order kinetics. The reusable nature of the adsorbent was demonstrated through multiple cycles without a significant loss in efficiency.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2021)
Article
Chemistry, Applied
Betul Bulut, Emrah Isbilen, Husnu Atakul, S. Birgul Tantekin-Ersolmaz
Summary: In this study, NaX and NaY zeolites modified with Cu2+, Zn2+, and Cu2+-Zn2+ metal ions were used for desulfurization of LPG. The modified zeolites showed enhanced desulfurization performance, with Cu-Y zeolite exhibiting the highest adsorption capacity. The addition of Cu2+ ions improved the surface properties of the zeolites and increased their adsorption capacity.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Chemistry, Physical
Sabarish Radoor, Jasila Karayil, Aswathy Jayakumar, Jyotishkumar Parameswaranpillai, Suchart Siengchin
Summary: Mesoporous ZSM-5 zeolite has high adsorption capacity and stable regeneration ability, showing potential as an efficient adsorbent for organic contaminants. Its porous structure can be synthesized using cellulose, and it exhibits high removal efficiency for dyes like methyl orange.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Green & Sustainable Science & Technology
Mahboobeh Monjezi, Vahid Javanbakht
Summary: Geopolymers can be synthesized using waste materials and by-products, and a geopolymer foam adsorbent based on ZSM-5 zeolite is effective in removing low-concentration dye. The adsorption process is affected by parameters such as temperature, concentration, and pH, and is described by the pseudo-second-order model and the Temkin model. Thermodynamically, the process is exothermic. Continuous experiments show compatibility with the Thomas and Bohart-Adams models, with a maximum adsorption capacity of 9.82 and 8.17 mg/g for methylene blue in batch and continuous processes, respectively. Reduction of the adsorbent is achieved through chemical and thermal processes.
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
(2023)
Article
Engineering, Chemical
Tianyu Mo, Miao Yu, Hongyan Li, Songnan Li, Bin Lu, Jingxiang Zhao, Qinghai Cai
Summary: CrOx nanoparticle-and H+-modified NaZSM5 composites were prepared and characterized. The composites showed moderate surface acidity and basicity, resulting from the substitution of Cr species or H+ for counter Na+ and the highly dispersed CrOx nanoparticles on zeolites. The composites exhibited excellent performance in catalyzing methanol dehydration to dimethyl ether, with over 90% conversion and nearly 100% selectivity at lower reaction temperature. The activity remained stable over 500 hours of continuous operation, indicating excellent running stability.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Energy & Fuels
Xingyuan Cheng, Jie Gu, Bingtian Huang, Liancheng Bing, Dezhi Han, Guangjian Wang, Fang Wang
Summary: In this study, various metal-modified ZSM-5 zeolite adsorbents were prepared by the impregnation method and applied to the removal of organic chlorides from model naphtha. The adsorption performance and regeneration stability were investigated, and the Mg/ZSM-5 zeolite adsorbent showed the best dechlorination and regeneration performance. The introduction of the metal significantly influenced the acidic properties of the catalyst surface.
CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY
(2023)
Article
Engineering, Multidisciplinary
Amir Hossein Salimi, Ali Shamshiri, Ehsan Jaberi, Hossein Bonakdari, Azam Akhbari, Robert Delatolla, Mohammad Reza Hassanvand, Mohammad Agharazi, Yuk Feng Huang, Ali Najah Ahmed, Ahmed Elshafie
Summary: Nanotechnologies show promise in the production of potable water from natural sources through treatment. This study examines a simple method for preparing and modifying natural adsorbents using different acids and bases, with convenient desorption. Characterization techniques such as XRD, FT-IR, SEM, and TEM are used, along with the Response Surface Method to analyze the influence of operational variables. The results show optimal conditions for iron removal and the best isothermal model to describe the adsorption process.
AIN SHAMS ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Anka Jevremovic, Ana Stanojkovic, Dragana Arsenijevic, Aleksandar Arsenijevic, Grigory Arzumanyan, Kahramon Mamatkulov, Jelena Petrovic, Bojana Nedic Vasiljevic, Danica Bajuk-Bogdanovic, Maja Milojevic-Rakic
Summary: This study investigates the effects of different pesticide remediation methods on cytotoxicity and finds that materials used for adsorption and oxidative degradation can have different effects on cells. It is concluded that a combination of adsorption and catalytic degradation is the optimal approach for reducing pesticide toxicity.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Applied
Shouyi Li, Beibei Lu, Yonggang Wang, Xiongchao Lin
Summary: In order to improve the catalytic performance of zeolite catalysts in alkylphenol dealkylation, TPAOH was used to introduce mesoporous structure to ZSM-5 zeolite in weak base NH4OH, and the content and dimension of mesoporous were changed by TPAOH concentration. The catalytic activity and lifetime of hierarchical zeolite were studied. The results showed that the phenol selectivity of hierarchical zeolite was slightly reduced, but the phenol yield was relatively stable. Higher TPAOH concentration expanded the introduced mesoporous structure, resulting in increased complexity of the catalytic products, including a certain amount of cresol, xylene, etc.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Florinela Pirvu, Cristina Ileana Covaliu-Mierla, Gina Alina Catrina
Summary: This study investigated the adsorption of acetaminophen by Fe3O4 and ZSM-5 nanomaterials in wastewater treatment. The results showed that Fe3O4 nanomaterial had a higher removal efficiency (84.6%) compared to ZSM-5 nanomaterial (75.4%). Both materials have the potential to be effective adsorbents for the removal of acetaminophen from wastewater.
Article
Engineering, Environmental
Sama M. Al-Jubouri, Haider A. Al-Jendeel, Sarmad A. Rashid, Sirhan Al-Batty
Summary: In this study, the efficient adsorption capacity of eco-friendly ZSM-5 nanocrystals-carbon composite (NZC) for ciprofloxacin antibiotics was investigated. The results showed that NZC exhibited outstanding adsorption performance for ciprofloxacin antibiotics, making it a highly efficient adsorbent for the removal of ciprofloxacin-loaded effluents.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Engineering, Environmental
Shuang Liu, Ye Li, Jiashuai Yan, Yuzhi Zhou, Cong Liu, Yangyang Zuo, Dongxue Liu
Summary: Xanthate-modified cross-linked chitosan (chitosan-SH) was synthesized by hydrothermal method for the removal of ruthenium [Ru(III)] from aqueous solutions. The adsorption process by chitosan-SH was found to be fast, reaching equilibrium within 30 minutes with a removal percentage of 94.7% at pH 7.0. Parameters like pH, contact time, initial Ru(III) concentration, solution volume, and adsorbent concentration were investigated to understand their effects on adsorption capacity, showing potential application of chitosan-SH as an adsorbent for Ru(III) in wastewater treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
R. Sabarish, K. Jasila, J. Aswathy, P. Jyotishkumar, S. Suchart
Summary: A novel PVA/agar/ZSM-5 zeolite membrane was successfully fabricated for the removal of Congo red from aqueous streams. Through characterization and experiments, the membrane exhibited high adsorption capacity and good regeneration capacity. Optimization of operational parameters led to high adsorption efficiency, following pseudo-second-order kinetics and Freundlich isotherm model.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Wei Ma, Dong Ye, Haining Wang
Summary: In this study, Co-Fe mixed oxide modified ZSM-5 adsorbents were successfully synthesized using the ultrasonic-assisted impregnation method for the capture of elemental mercury. Among the samples, Co4Fe1-ZSM-5 showed the best performance with high removal efficiency and adsorption capacity. The study also investigated the effects of various gas components during the mercury adsorption process.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Analytical
Wei Wang, Qinyi Zhang, Ruonan Lv, Dong Wu, Shunping Zhang
Summary: This study successfully enhanced the selectivity to formaldehyde by modifying the surface of metal oxide semiconductors with a zeolite layer, and controlled the thickness of the layer to achieve outstanding performance.