期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 55, 期 11, 页码 2959-2969出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.6b00061
关键词
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资金
- National Natural Science Foundation of China [51363001]
- Guangxi Natural Science Foundation [2014GXNSFDA118009]
- Guangxi scientific and technological project [12118008-12-3]
- Experimental Innovation Project Foundation of Guangxi University, PR China [20120322]
To mimic the activity regulated by a cysteinate axial ligand in cytochrome P450 enzymes, metal tetrakis(4-carboxyphenyl)porphyrins (M TCPP) were immobilized on ZnS. They were characterized by a variety of spectroscopic techniques and were used as a catalyst for cyclohexane oxidation. The small amount of metal (Co, Fe, or Mn) TCPP (1.1 mu mol) in the immobilized catalyst could be reused three times for oxidation, providing more than 6.5 X 10(5) turnover number and 20% molar yield of cyclohexanone and cyclohexanol (KA oil) on average. The coordination of ZnS played a key role. These catalysts were applied to green catalytic oxidation of cyclohexane to produce KA oil products.
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