4.6 Article

Investigation on the thermal expansion behavior of FeCoNi and Fe30Co30Ni30Cr10-xMnx high entropy alloys

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 271, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2021.124907

关键词

Coefficient of thermal expansion; High entropy alloy; Curie temperature; Invar effect

资金

  1. China Steel Corporation [RE105620]
  2. NIMS under the International Cooperative Graduate Program
  3. Ministry of Science and Technology (MOST) in Taiwan [MOST110-2221-E-007-020-MY3, MOST110-2224-E-007 -001, MOST109-2634-F-007-024]
  4. High Entropy Materials Center from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education

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This study found that reducing the Cr and Mn content in the Co-Cr-Fe-Mn-Ni system can significantly decrease the thermal expansion coefficient of high entropy alloys, exhibiting similar thermal expansion behavior to that of Invar alloys; the abrupt change in thermal expansion behavior of high entropy alloys is associated with the transition from ferromagnetism to paramagnetism, and these alloys may exhibit the dimensional stability of the Invar effect.
This work investigates the thermal expansion behaviors of Fe30Co30Ni30Cr10-xMnx High Entropy Alloys (HEAs) (x = 0, 5, 10 at.%) from 400 K to 1200 K. Interestingly, comparing to that of Cantor alloy, a decrease in Cr and Mn in Co-Cr-Fe-Mn-Ni system could significantly decrease the thermal expansion coefficient by 45.2%; Fe30Co30-Ni30Cr10-xMnx (x = 0, 5, 10) also showed an abrupt change in thermal expansion behaviors similar to that of Invar alloys. Experimental and theoretical analysis suggest the abrupt change in thermal expansion behaviors of these HEAs were associated with the transition from ferromagnetism to paramagnetism, and these alloys appear to exhibit the dimensional stability of the Invar effect. Since the Invar effect is related to ferromagnetic properties, the amount of Cr and Mn in the HEAs would influence the suppression of thermal expansion due to different intensity of anti-ferromagnetic coupling effect. This research contributes to the understanding of the thermal expansion behaviors of Co-Cr-Fe-Mn-Ni high entropy alloys and the effects of antiferromagnetic elements.

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