Nickel-Catalyzed Enantioselective Arylative Activation of Aromatic C–O Bond

Nickel-Catalyzed Cross-Coupling of Aryl 2-Pyridyl Ethers with Organozinc Reagents: Removal of the Directing Group via Cleavage of the Carbon–Oxygen Bonds

(2021) Wei-Can Dai et al.   JOURNAL OF ORGANIC CHEMISTRY

Biaryl Construction Based on Nickel-catalyzed C-O Bond Activation

(2021) Hai-Yan Diao et al.   SYNLETT

Deciphering the dichotomy exerted by Zn(ii) in the catalytic sp2 C–O bond functionalization of aryl esters at the molecular level

(2021) Craig S. Day et al.   Nature Catalysis

Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization

(2021) Xuefeng Cong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Selective C–O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium–Aluminum Heterobimetallic Complex

(2021) Rin Seki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Ring-Opening C–O Functionalization of peri-Xanthenoxanthenes for 8-Substituted Binaphthol Synthesis

(2021) Naoki Matsuyama et al.   ORGANIC LETTERS

Natural Feedstock in Catalysis: A Sustainable Route Towards Organic Transformations

(2021) U. P. Patil et al.   Topics in Current Chemistry

Direct Transformation of Arenols Based on C—O Activation

(2020) Feng Liu et al.   CHINESE JOURNAL OF CHEMISTRY

Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts

(2020) Javier Miró et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis

(2020) Jinghua Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atroposelective Ring Opening of Cyclic Diaryliodonium Salts with Bulky Anilines Controlled by a Chiral Cobalt(III) Anion

(2020) Zhenhua Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation

(2020) Jia Feng et al.   Nature Communications

Activation of C–O and C–N Bonds Using Non-Precious-Metal Catalysis

(2020) Timothy B. Boit et al.   ACS Catalysis

Diols Activation via Cu/Borinic Acids Synergistic Catalysis in Atroposelective Ring‐Opening of Cyclic Diaryliodoniums

(2020) Zhenhua Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines

(2019) Akihiro Nishizawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Carbon-Carbon Bond Cleavage for Biaryl Atropisomers Synthesis

(2019) Ruixian Deng et al.   Chem

CuH-Catalyzed Atropoenantioselective Reduction of Bringmann’s Lactones via Dynamic Kinetic Resolution

(2019) Le’an Hu et al.   ORGANIC LETTERS

Co(II)‐salen catalyzed stereoselective cyclopropanation of fluorinated styrenes

(2019) Serene Tai et al.   CHIRALITY

A Review on the Feedstocks for the Sustainable Production of Bioactive Compounds in Biorefineries

(2019) Serna-Loaiza et al.   Sustainability

Recent Advances in Chromium-Catalyzed Organic Transformations

(2019) Xiaoming Zeng   SYNLETT

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Amination of Silyloxyarenes through C-O Bond Activation

(2018) Eric M. Wiensch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of Arenols through Ni-catalyzed C-O Activation with Methyl Magnesium Bromide

(2018) Wen-Juan Shi et al.   CHINESE JOURNAL OF CHEMISTRY

Design and Synthesis of Chiral oxa-Spirocyclic Ligands for Ir-Catalyzed Direct Asymmetric Reduction of Bringmann’s Lactones with Molecular H2

(2018) Gen-Qiang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Enantioselective Ring Opening of Cyclic Diaryliodoniums toward the Synthesis of Chiral Diarylmethanes

(2018) Bin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Aldehyde Catalysis for the Catalytic Asymmetric Activation of Glycine Esters

(2018) Wei Wen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–O Bond Alkynylation of Aryl Carbamates with Propargyl Alcohols

(2018) Kosuke Yasui et al.   ORGANIC LETTERS

Enhanced Reactivity by Torsional Strain of Cyclic Diaryliodonium in Cu-Catalyzed Enantioselective Ring-Opening Reaction

(2018) Kun Zhao et al.   Chem

Cu-Catalyzed Enantioselective Atropisomer Synthesis via Thiolative Ring Opening of Five-Membered Cyclic Diaryliodoniums

(2018) Mengqing Hou et al.   ORGANIC LETTERS

Ni-Catalyzed Cross-Coupling of Dimethyl Aryl Amines with Arylboronic Esters under Reductive Conditions

(2018) Zhi-Chao Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands

(2017) Noam I. Saper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild and Ligand-Free Ni-Catalyzed Silylation via C–OMe Cleavage

(2017) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with Nickel-Catalyzed Ring-Opening C–O Arylation

(2017) Yuto Kurata et al.   ORGANIC LETTERS

Chemoselective Ruthenium-Catalyzed C–O Bond Activation: Orthogonality of Nickel- and Palladium-Catalyzed Reactions for the Synthesis of Polyaryl Fluorenones

(2017) Victor Snieckus et al.   SYNLETT

Lewis Acid Assisted Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers by C−O Bond-Cleaving Alkylation: Prevention of Undesired β-Hydride Elimination

(2016) Xiangqian Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Alkoxy-Alkyl Interconversion with Alkylborane Reagents through C−O Bond Activation of Aryl and Enol Ethers

(2016) Lin Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Hydrogenolysis of Arenols with Hydrosilanes by Nickel Catalysis

(2016) Akito Ohgi et al.   CHEMISTRY LETTERS

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals

(2016) Pauline Loxq et al.   COORDINATION CHEMISTRY REVIEWS

Nickel/N-Heterocyclic Carbene-Catalyzed Suzuki–Miyaura Type Cross-Coupling of Aryl Carbamates

(2016) Akimichi Ohtsuki et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Alkylative Cross-Coupling of Anisoles with Grignard Reagents via C–O Bond Activation

(2016) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–Silicon Bond Formation in the Synthesis of Benzylic Silanes

(2016) Michael D. Visco et al.   ORGANIC LETTERS

C–O/C–H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis

(2016) Yang Wang et al.   ORGANIC LETTERS

Nickel-Catalyzed Csp2–Csp3 Cross-Coupling via C–O Bond Activation

(2016) Lin Guo et al.   ACS Catalysis

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

(2015) Mamoru Tobisu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C−O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments

(2015) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Nickel-catalyzed Cross-coupling of Anisole Derivatives with Trimethylaluminum through the Cleavage of Carbon–Oxygen Bonds

(2015) Toshifumi Morioka et al.   CHEMISTRY LETTERS

How and Why Does Ni0Promote Smooth Etheric CO Bond Cleavage and CC Bond Formation? A Theoretical Study

(2015) Hiroyuki Ogawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C–OMe Cleavage

(2015) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Chemoselective Kumada–Tamao–Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions

(2015) Xuefeng Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon–Oxygen Bond: Borylative Removal of the Directing Group

(2015) Hirotaka Kinuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–P Bond-Forming Reactions via C–O/P–H Cross-Coupling Catalyzed by Nickel

(2015) Jia Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Nickel-Catalyzed Formal Homocoupling of Methoxyarenes for the Synthesis of Symmetrical Biaryls via C–O Bond Cleavage

(2015) Keisuke Nakamura et al.   ORGANIC LETTERS

Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C–O Bond Cleavage

(2015) Mamoru Tobisu et al.   ORGANIC LETTERS

Direct and selective hydrogenolysis of arenols and aryl methyl ethers

(2015) Shuhei Kusumoto et al.   Nature Communications

Metal-Catalyzed Dealkoxylative CarylC sp 3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile

(2014) Matthias Leiendecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of novel chiral N,N,O-tridentate phenanthroline ligands and their application to enantioselective addition of organozinc reagents to aldehydes

(2014) Yuki Naganawa et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives

(2014) Kentaro Nakanishi et al.   JOURNAL OF ORGANIC CHEMISTRY

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Key Mechanistic Features of Ni-Catalyzed C–H/C–O Biaryl Coupling of Azoles and Naphthalen-2-yl Pivalates

(2014) Huiying Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Direct Reductive Amidation via C–O Bond Cleavage

(2014) Arkaitz Correa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oligonaphthofurans: Fan-Shaped and Three-Dimensional π-Compounds

(2014) Kentaro Nakanishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Selective Reductive Cleavage of Inert Aryl CO Bonds by an Iron Catalyst

(2013) Yunlai Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-crystal Field-effect Transistors with a Furan-containing Organic Semiconductor Having a Twisted π-Electronic System

(2013) Katsumasa Nakahara et al.   CHEMISTRY LETTERS

Synthesis, structure, and catalytic activity of nickel complexes with new chiral binaphthyl-based NHC-ligands

(2013) Haibin Song et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Isolation, Structure, and Reactivity of an Arylnickel(II) Pivalate Complex in Catalytic C–H/C–O Biaryl Coupling

(2013) Kei Muto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Carboxylation of C(sp2)– and C(sp3)–O Bonds with CO2

(2013) Arkaitz Correa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Alkylations of Aryl Sulfamates and Carbamates

(2012) Amanda L. Silberstein et al.   ORGANIC LETTERS

Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams

(2011) Masami Ichinose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mutual Activation: Suzuki-Miyaura Coupling through Direct Cleavage of the sp2 CO Bond of Naphtholate

(2011) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Revealing Atropisomer Axial Chirality in Drug Discovery

(2011) Steven R. LaPlante et al.   ChemMedChem

Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives

(2011) Kei Muto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki−Miyaura Cross-Coupling of Aryl Carbamates and Sulfamates: Experimental and Computational Studies

(2011) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Conjugate Addition of 3-Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Ni(OAc)2-Diamine Complex under Mild Conditions

(2011) Yan-Yan Han et al.   ORGANIC LETTERS

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

(2011) A. G. Sergeev et al.   SCIENCE

Nickel-catalyzed amination of aryl carbamates and sequential site-selective cross-couplings

(2011) Tehetena Mesganaw et al.   Chemical Science

Exploration of New C−O Electrophiles in Cross-Coupling Reactions

(2010) Da-Gang Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents

(2010) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl CO Bonds

(2010) Toshiaki Shimasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed CO Activation

(2010) Kun Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni-Catalyzed Reduction of Inert C−O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups

(2010) Paula Álvarez-Bercedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Ni0-catalyzed Direct Amination of Anisoles Involving the Cleavage of Carbon–Oxygen Bonds

(2009) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Suzuki−Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

(2009) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N,N-DiethylO-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner

(2009) Aurora Antoft-Finch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C−O Bond Activation

(2009) Bi-Jie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Aryl/Alkenyl Pivalates with Organozinc Reagents through Nickel-Catalyzed CO Bond Activation under Mild Reaction Conditions

(2008) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

Cross-Coupling Reactions of Aryl Pivalates with Boronic Acids

(2008) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyticatropo-Enantioselective Reduction of Biaryl Lactones to Axially Chiral Biaryl Compounds

(2008) Tomoko Ashizawa et al.   ORGANIC LETTERS