Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Well-defined organometallic Copper(III) complexes: Preparation, characterization and reactivity

(2021) He Liu et al.   COORDINATION CHEMISTRY REVIEWS

A Five‐Coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III)

(2021) Daniel Joven‐Sancho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Excited state charge distribution and bond expansion of ferrous complexes observed with femtosecond valence-to-core x-ray emission spectroscopy

(2020) Kathryn Ledbetter et al.   JOURNAL OF CHEMICAL PHYSICS

Kβ X‐Ray Emission Spectroscopic Study of a Second‐Row Transition Metal (Mo) and Its Application to Nitrogenase‐Related Model Complexes

(2020) Rebeca G. Castillo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scrutinizing “Ligand Bands” via Polarized Single-Crystal X-ray Absorption Spectra of Copper(I) and Copper(II) Bis-2,2′-bipyridine Species

(2020) Ida M. DiMucci et al.   INORGANIC CHEMISTRY

Probing a Silent Metal: A Combined X-ray Absorption and Emission Spectroscopic Study of Biologically Relevant Zinc Complexes

(2020) Olivia McCubbin Stepanic et al.   INORGANIC CHEMISTRY

Quantification of Ni–N–O Bond Angles and NO Activation by X-ray Emission Spectroscopy

(2020) Phan N. Phu et al.   INORGANIC CHEMISTRY

Experimental X-ray Electron Density Study of Atomic Charges, Oxidation States, and Inverted Ligand Field in Cu(CF3)4–

(2019) Chen Gao et al.   INORGANIC CHEMISTRY

Valence-to-Core X-ray Emission Spectroscopy as a Probe of O−O Bond Activation in Cu2 O2 Complexes

(2019) George E. Cutsail et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper’s rapid ascent in visible-light photoredox catalysis

(2019) Asik Hossain et al.   SCIENCE

An Adaptable N-Heterocyclic Carbene Macrocycle Hosting Copper in three Oxidation States

(2019) Yang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex

(2019) Zachary Mathe et al.   INORGANIC CHEMISTRY

The Myth of d8 Copper(III)

(2019) Ida M. DiMucci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ground-State Copper(III) Stabilized by N-Confused/N-Linked Corroles: Synthesis, Characterization, and Redox Reactivity

(2018) Yogesh Kumar Maurya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

(2018) Chip Le et al.   SCIENCE

A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate

(2018) Zohreh S. Ghavami et al.   Chemical Science

An examination of the nature of localized molecular orbitals and their value in understanding various phenomena that occur in organic chemistry

(2018) James J. P. Stewart   JOURNAL OF MOLECULAR MODELING

High-Energy-Resolution Fluorescence-Detected X-ray Absorption of the Q Intermediate of Soluble Methane Monooxygenase

(2017) Rebeca G. Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields

(2016) Roald Hoffmann et al.   CHEMICAL REVIEWS

X-ray Absorption and Emission Spectroscopic Studies of [L2Fe2S2]n Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron–Sulfur Clusters

(2016) Joanna K. Kowalska et al.   INORGANIC CHEMISTRY

Kβ Valence to Core X-ray Emission Studies of Cu(I) Binding Proteins with Mixed Methionine – Histidine Coordination. Relevance to the Reactivity of the M- and H-sites of Peptidylglycine Monooxygenase

(2016) Vlad Martin-Diaconescu et al.   INORGANIC CHEMISTRY

Charge and Spin-State Characterization of Cobalt Bis(o-dioxolene) Valence Tautomers Using Co Kβ X-ray Emission and L-Edge X-ray Absorption Spectroscopies

(2016) H. Winnie Liang et al.   INORGANIC CHEMISTRY

Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4]1–

(2016) Richard C. Walroth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Insights into the Geometric and Electronic Structure of Transition Metal Centers from Valence-to-Core X-ray Emission Spectroscopy

(2015) Christopher J. Pollock et al.   ACCOUNTS OF CHEMICAL RESEARCH

The divergent effects of strong NHC donation in catalysis

(2015) Justin A. M. Lummiss et al.   Chemical Science

Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions

(2015) Neil C. Tomson et al.   Chemical Science

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

Study of Iron Dimers Reveals Angular Dependence of Valence-to-Core X-ray Emission Spectra

(2014) Christopher J. Pollock et al.   INORGANIC CHEMISTRY

Kβ Mainline X-ray Emission Spectroscopy as an Experimental Probe of Metal–Ligand Covalency

(2014) Christopher J. Pollock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Valence-to-Core X-Ray Emission Spectroscopy of Iron-Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates

(2013) Mario Ulises Delgado-Jaime et al.   CHEMISTRY-A EUROPEAN JOURNAL

Experimental and Computational X-ray Emission Spectroscopy as a Direct Probe of Protonation States in Oxo-Bridged MnIV Dimers Relevant to Redox-Active Metalloproteins

(2013) Benedikt Lassalle-Kaiser et al.   INORGANIC CHEMISTRY

Experimentally Quantifying Small-Molecule Bond Activation Using Valence-to-Core X-ray Emission Spectroscopy

(2013) Christopher J. Pollock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Kβ X-ray Emission Spectroscopy As a Probe of Metal–Ligand Interactions

(2011) Martha A. Beckwith et al.   INORGANIC CHEMISTRY

Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of the Nature of a Bound Ligand

(2011) Christopher J. Pollock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Understanding of the Unexpected Meta Selectivity in Copper-Catalyzed Anilide C–H Bond Arylation

(2011) Bo Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy

(2010) Nicole Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-ray Emission Spectroscopy To Study Ligand Valence Orbitals in Mn Coordination Complexes

(2009) Grigory Smolentsev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE