Review
Chemistry, Physical
Haijun Ruan, Jorge Varela Barreras, Marco Steinhardt, Andreas Jossen, Gregory J. Offer, Billy Wu
Summary: This study reviews the current state-of-the-art self-heating methods and proposes the heating triangle as a new quantitative indicator for comparing self-heating methods. The heating triangle considers three fundamental metrics: specific heating rate, coefficient of performance, and specific temperature difference, enabling a quantitative assessment of self-heating methods. The analysis shows that similar metrics are observed for the same type of self-heating method, supporting the universality of the proposed indicator. The proposed heating triangle provides a standardized approach to compare heating methods and drive innovation.
JOURNAL OF POWER SOURCES
(2023)
Review
Chemistry, Physical
Xiaowan Pang, Baigang An, Shumin Zheng, Bao Wang
Summary: Energy storage devices have made significant advancements in recent years, but their performance is limited in low-temperature environments. Developing new cathode materials is a key strategy to alleviate these limitations, with lithium-ion batteries being the most attractive option. Sodium-ion batteries, magnesium-ion batteries, and zinc-ion batteries are potential substitutes, but they face their own challenges at low temperatures. This review provides an overview of these batteries and their high-energy cathode materials that can operate in low-temperature environments.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Energy & Fuels
Xianjun Liu, Xianhua Hong, Xiaohua Jiang, Yanfei Li, Kw Xu
Summary: This paper proposes an optimization simulation model for charging control strategy, combining thermal model and BPS offline parameters based on a liquid heating thermal management system, to reduce the charging time of batteries at low temperatures. By introducing a pre-heating stage and optimizing the charging strategy, overall charge time is minimized and temperature differences are reduced.
JOURNAL OF ENERGY STORAGE
(2023)
Review
Chemistry, Physical
Yuqiang Zeng, Divya Chalise, Sean D. Lubner, Sumanjeet Kaur, Ravi S. Prasher
Summary: As lithium-ion battery (LIB) research shifts towards high energy density and fast charging batteries, traditional assumptions about battery thermal management around room temperature may not hold true. A comprehensive review of thermal considerations for LIBs targeting high energy density and fast charging is necessary, including optimal thermal conditions, heat transport and generation inside the battery, and thermal management strategies. To maintain temperature uniformity and prevent excessive internal temperature rise, enhancing heat transfer inside the battery and reducing thermal contact resistance between electrodes can significantly improve the effective thermal conductivity of batteries.
ENERGY STORAGE MATERIALS
(2021)
Article
Energy & Fuels
Cheng Lin, Zhenyi Tao, Yu Tian
Summary: This study proposes a variable duty cycle heating strategy based on an online two-dimensional model for self-heating lithium-ion batteries to optimize temperature distribution uniformity. The proposed model can calculate the temperature distribution almost as accurately as the finite element model and the variable duty cycle heating strategy can reduce the temperature difference and limit it to the pre-set boundary according to heating uniformity requirements.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Materials Science, Ceramics
Wei Qin, Yuanbo Chen, Jie An, Xiaogang Wen
Summary: A novel self-supported Li4Ti5O12 nanobelt array with high surface area and excellent performance has been successfully fabricated, showing great potential for high performance flexible energy storage devices, especially at low temperatures.
CERAMICS INTERNATIONAL
(2022)
Article
Thermodynamics
Haijun Ruan, Bingxiang Sun, Andrew Cruden, Tao Zhu, Jiuchun Jiang, Xitian He, Xiaojia Su, Engy Ghoniem
Summary: The research developed a lightweight compound self-heating system involving external aluminum heaters to effectively warm lithium-ion batteries, optimizing heating performance. By considering conflicting metrics such as heating time, efficiency, degradation, and uniformity, a rapid compound self-heating strategy was proposed, significantly improving battery performance.
APPLIED THERMAL ENGINEERING
(2022)
Article
Chemistry, Physical
Fengyang Cai, Huawei Chang, Zhengbo Yang, Chen Duan, Zhengkai Tu
Summary: Polarization is a major issue for lithium-ion batteries at low temperatures. This study proposes a self-heating strategy using bidirectional pulse current to rapidly preheat batteries without external power. By establishing an electrothermal coupling model and a performance evaluation model, the effects of circuit parameters and initial SOC on heating performance were investigated.
JOURNAL OF POWER SOURCES
(2022)
Article
Energy & Fuels
Saeed Alqaed
Summary: This study simulated the cooling of three packs of lithium-ion batteries using airflow in a ventilation channel to provide energy for a residential unit. The results indicate that increasing air velocity can reduce the temperature of the battery cells, but also lower the outlet temperature of the channel.
JOURNAL OF ENERGY STORAGE
(2022)
Review
Energy & Fuels
Bingxiang Sun, Xianjie Qi, Donglin Song, Haijun Ruan
Summary: Lithium-ion batteries (LIBs) experience significant performance decrease at low temperatures, which poses great challenges for the application of electric vehicles in cold weather and the promotion of EVs in high-latitude regions. This review discusses the performance limitations, modeling, and heating methods for addressing the low-temperature challenge of LIBs. Future research directions and limitations are also outlined.
Article
Thermodynamics
Zhizuan Zhou, Xiaodong Zhou, Bei Cao, Lizhong Yang, K. M. Liew
Summary: This research investigates the impact of heating temperature on the thermal runaway (TR) of lithium-ion batteries (LIBs). It is found that TR occurs when the heating temperature exceeds 200 degrees Celsius, while only safety venting is observed at 175 degrees Celsius. As the heating temperature increases, the time interval between safety venting and TR decreases, and the temperature difference within the battery decreases. Additionally, the contribution of self-generated heat to trigger TR at different heating temperatures is identified.
Article
Chemistry, Multidisciplinary
Jaehoon Choi, Omid Zabihi, Mojtaba Ahmadi, Minoo Naebe
Summary: This study presents a promising approach for fabricating high-performance structural batteries with enhanced energy storage and structural capabilities.
Article
Thermodynamics
Haijun Ruan, Bingxiang Sun, Tao Zhu, Xitian He, Xiaojia Su, Andrew Cruden, Wenzhong Gao
Summary: Rapid and effective battery preheating is crucial for electric vehicles to operate efficiently in cold environments. A low-temperature compound self-heating (CSH) strategy integrating inner-battery direct-current heating and outer-battery electric heating has been proposed to enhance heating efficiency. Through systematic discussions and comparisons of different CSH methods, an optimal low-temperature CSH method was proposed, showing significant improvements in heating rate, energy consumption, and battery degradation.
APPLIED THERMAL ENGINEERING
(2021)
Article
Thermodynamics
Zhiyuan Jiang, Zhiguo Qu, Qiong Wang
Summary: This study proposes a new preheating method, inductive heating, to address the challenge of fast preheating of lithium ion batteries (LIBs) in cold climates. Inductive heating offers better battery preheating performance with fast and uniform temperature increment. The performance of inductive heating is highly related to current frequency and battery thickness. This paper provides a preliminary investigation into the feasibility of LIB inductive preheating technology and offers new insights into the thermal management design of LIB application in cold climates.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2023)
Article
Energy & Fuels
Fengyang Cai, Huawei Chang, Zhengbo Yang, Zhengkai Tu
Summary: This study proposes a bidirectional pulse-current preheating strategy for lithium-ion batteries (LIBs) at low temperatures, which effectively improves the battery performance. The effects of ambient temperature, initial state of charge, and preheating strategy on voltage and current evolution, heating rate, and efficiency are experimentally analyzed. Comparative analysis shows that bidirectional pulse-current preheating strategy outperforms the classic pulse heating method in terms of heating rate and thermal efficiency.
Article
Thermodynamics
Li Yiding, Wang Wenwei, Lin Cheng, Yang Xiaoguang, Zuo Fenghao
Summary: Research shows that the battery behavior under dynamic compression is significantly different from that under quasi-static compression, with the dynamic load having a strengthening effect on the battery and the equivalent strength of the battery tending to be consistent under high strain rate.
Article
Energy & Fuels
Xiao-Guang Yang, Teng Liu, Chao-Yang Wang
Summary: The development of thermally modulated LFP battery can provide adequate cruise range and extend the range through short recharges, eliminating range anxiety for electric vehicles. Designed to operate at a working temperature of around 60 degrees Celsius in any ambient condition, it promises to be an ideal powertrain for mass-market EVs. Furthermore, utilizing low surface area graphite presents an opportunity to prolong the lifespan of EVs to over two million miles.
Article
Electrochemistry
Yongjun Leng, Shanhai Ge, Xiao-Guang Yang, Ryan S. Longchamps, Teng Liu, Chao-Yang Wang
Summary: The study found that Li metal anodes can achieve high Coulombic efficiency in highly concentrated electrolytes at elevated temperatures, while LMBs with NMC811 cathodes can achieve stable charge and discharge cycles at 60 degrees Celsius.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Jinpeng Tian, Rui Xiong, Weixiang Shen, Jiahuan Lu, Xiao-Guang Yang
Summary: The study introduces a method to accurately estimate the entire constant-current charging curves using a deep neural network, which can capture the curves accurately in a short amount of time and demonstrate effectiveness through validation, as well as the advantage of transfer learning.
Article
Chemistry, Physical
Teng Liu, Shanhai Ge, Xiao-Guang Yang, Chao-Yang Wang
Summary: This study suggests that allowing Li-ion batteries to charge at higher temperatures can alleviate the issues of increased cost and weight caused by strong cooling systems during fast charging. By using an experimentally validated model, it is shown that a gradually increasing temperature profile can achieve a balance between fast charging and thermal management of the battery.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Ryan S. Longchamps, Xiao-Guang Yang, Chao-Yang Wang
Summary: This article presents a new perspective on battery thermal management and safety for electric vehicles, emphasizing the importance of high-temperature battery operation and heat-resistant materials in future research and development. The application of heat-resistant batteries can enhance battery safety and calendar life, while simplifying thermal management systems.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Physical
Yiding Li, Wenwei Wang, Xiao-Guang Yang, Fenghao Zuo, Shuaibang Liu, Cheng Lin
Summary: This study presents a smart Li-ion battery sensor scheme with an integrated fiber Bragg grating (FBG) optical fiber sensor, enabling simultaneous measurement of temperature, force, and displacement at the cell level. The scheme realizes synchronous monitoring of battery mechanical, electrical, and thermal parameters, and has the potential for enhancing cell life and safety.
JOURNAL OF POWER SOURCES
(2022)
Article
Multidisciplinary Sciences
Chao-Yang Wang, Teng Liu, Xiao-Guang Yang, Shanhai Ge, Nathaniel Stanley, Eric S. Rountree, Yongjun Leng, Brian D. McCarthy
Summary: Researchers have achieved fast charging of high-energy density batteries using an asymmetric temperature modulation and a thermally stable dual-salt electrolyte method, allowing for a 75% state of charge in just 12 minutes. They have also developed a digital twin to assess cooling and safety, demonstrating the feasibility of thermally modulated 4C charging with air convection.
Article
Energy & Fuels
Wenxue Liu, Xiaosong Hu, Xianke Lin, Xiao-Guang Yang, Ziyou Song, Aoife M. Foley, Jonathan Couture
Summary: In this article, a practical and general framework is proposed to investigate the potential error sources in computationally efficient electrothermal modeling of large-format lithium-ion batteries. The results demonstrate that modeling the thermal interplay between two tabs and the cell body and optimizing the temperature sensor placements should be given high priority. Additionally, the overpotential-based method is preferred for calculating the local generation rates of the battery body for accuracy and generalizability.
Article
Mechanics
Yiwei Duan, Duoqi Shi, Changqi Liu, Xiaoguang Yang
Summary: In this paper, a novel aerodynamic-acoustic coupling model is proposed to investigate the influence of aeroelastic effects on the thermo-acoustic response of a three-dimensional, four-directional braided composite panel. The fatigue life under combined aerodynamic load and acoustic load is discussed by using a rainflow cycle counting method. The results show that aeroelastic not only transforms the movement form but also affects the fatigue life of the panel.
COMPOSITE STRUCTURES
(2023)
Article
Chemistry, Multidisciplinary
Ze-Yu Chen, Rui Xiong, Bo Zhang, Rui-Xin Yang, Wei-Xiang Shen, Xiao-Guang Yang, Wan-Zhou Sun, Dai-Wei Yu, Feng-Chun Sun
Summary: This study reports the impact of different ESC durations on battery performance and divides the ESC process into four stages. It reveals a transition from benign to malignant when the ESC duration is close to a critical time. The establishment of the critical time surface and the disclosure of center temperatures of the critical time and battery failure pave the way for fault diagnosis and controlled benign ESC.
CELL REPORTS PHYSICAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Shanhai Ge, Ryan Sheldon Longchamps, Teng Liu, Jie Liao, Yongjun Leng, Chao-Yang Wang
Summary: By adding triallyl phosphate (TAP) to standard electrolytes, high-energy LIBs can become safer with controlled temperatures, reducing the risk of fire at high temperatures. However, this may result in lower battery power, which can be restored through thermal modulation, and the cells stabilized with TAP exhibit good cycling stability at 60 degrees Celsius.
CELL REPORTS PHYSICAL SCIENCE
(2021)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)