In-situ production and activation of H2O2 for enhanced degradation of roxarsone by FeS2 decorated resorcinol-formaldehyde resins

Fenton technology performs well in high-risk roxarsone (ROX) removal, but it is limited by the high H2O2 transportation and storage risks. Herein, FeS2 decorated resorcinol-formaldehyde resins (FeS2-RFR) were successfully prepared to in-situ produce and utilize H2O2 for efficient removal of ROX. Under solar light illumination, resorcinol-formaldehyde resins (RFR) efficiently generated a high concentration of H2O2, with a yield of 500 mu mol g-1 h-1. FeS2 can in-situ decompose H2O2 to generate center dot OH, participating in the oxidation of ROX. As a result, the FeS2-RFR catalyst degraded more than 97% of ROX within 2 h and ROX was selectively degraded into low-toxic As(V), which can be simply removed by traditional adsorption or precipitation processes. During the degradation of ROX, center dot OH played a dominant role. Moreover, the cations (Na+, K+, and Ca2+), anions (SO42-, Cl- ), and humic acid had no noticeable inhibition effect on ROX removal. Furthermore, FeS2-RFR can still remove 70% of ROX even after three cycles, proving that this in-situ photo-Fenton system exhibited stability. This study innovatively proposed a double-active site FeS2-RFR photocatalyst for in-situ production and activation of H2O2 and showed a sustainable and eco-friendly way for organoarsenic compounds degradation.

Automated summary

FeS2-RFR catalyst was successfully prepared for in-situ production of H2O2 and efficient removal of ROX under solar light illumination. This catalyst degraded more than 97% of ROX within 2 hours and selectively transformed ROX into low-toxic As(V) without inhibition effect from cations, anions, or humic acid. FeS2-RFR showed good stability and efficiency in degrading organoarsenic compounds, providing a sustainable and eco-friendly method.