From selective transfer hydrogenation to selective hydrogen auto-transfer process: An efficient method for the synthesis of alkenyl ketones via iridium-catalyzed α-alkylation of ketones with alkenyl alcohols

Selective Catalytic Synthesis of α-Alkylated Ketones and β-Disubstituted Ketones via Acceptorless Dehydrogenative Cross-Coupling of Alcohols

(2021) Dipanjan Bhattacharyya et al.   ORGANIC LETTERS

N-Methylation of Amines with Methanol in the Presence of Carbonate Salt Catalyzed by a Metal–Ligand Bifunctional Ruthenium Catalyst [(p-cymene)Ru(2,2′-bpyO)(H2O)]

(2021) Peng Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Methylation of Amines with Methanol in Aqueous Solution Catalyzed by a Water-Soluble Metal–Ligand Bifunctional Dinuclear Iridium Catalyst

(2020) Chong Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

Proton-responsive Ruthenium(II) Catalysts for the Solvolysis of Ammonia-Borane

(2020) Virginia San Nacianceno et al.   ORGANOMETALLICS

Mechanism and Origin of Chemoselectivity of Ru-Catalyzed Cross-Coupling of Secondary Alcohols to β-Disubstituted Ketones

(2020) Tian-Tian Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed α-Alkylation of Ketones Using Secondary Alcohols to β-Disubstituted Ketones

(2020) Subramanian Thiyagarajan et al.   ORGANIC LETTERS

Highly Productive α-Alkylation of Ketones with Alcohols Mediated by an Ir–Oxalamidato/Solid Base Catalyst System

(2020) Hideo Shimizu et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Hydrogen Production from Methanol‐Water Mixture over Immobilized Iridium Complex Catalysts in Vapor‐Phase Flow Reaction

(2020) Sho Yamaguchi et al.   ChemSusChem

Ruthenium-catalyzed acceptorless dehydrogenative coupling of o-aminobenzyl alcohols with ketones to quinolines in the presence of carbonate salt

(2020) Xiangchao Xu et al.   JOURNAL OF CATALYSIS

Ruthenium-Catalyzed β-Alkylation of Secondary Alcohols and α-Alkylation of Ketones via Borrowing Hydrogen: Dramatic Influence of the Pendant N-Heterocycle

(2019) Chong Zhang et al.   ORGANOMETALLICS

Nonbifunctional Outer-Sphere Strategy Achieved Highly Active α-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)

(2019) Xiao-Bing Lan et al.   ORGANIC LETTERS

Direct Synthesis of Cycloalkanes from Diols and Secondary Alcohols or Ketones Using a Homogeneous Manganese Catalyst

(2019) Akash Kaithal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(I)-Catalyzed Alkylation Reactions To Form α-Alkylated Ketones

(2018) Sertaç Genç et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine-Free NNN-Manganese Complex Catalyzed α-Alkylation of Ketones with Primary Alcohols and Friedländer Quinoline Synthesis

(2018) Milan K. Barman et al.   ADVANCED SYNTHESIS & CATALYSIS

Nickel-Catalyzed Hydrogen-Borrowing Strategy for α-Alkylation of Ketones with Alcohols: A New Route to Branched gem-Bis(alkyl) Ketones

(2018) Jagadish Das et al.   ORGANIC LETTERS

Synergistic Bimetallic Ni/Ag and Ni/Cu Catalysis for Regioselective γ,δ-Diarylation of Alkenyl Ketimines: Addressing β-H Elimination by in Situ Generation of Cationic Ni(II) Catalysts

(2018) Prakash Basnet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols

(2018) Subrata Chakraborty et al.   ACS Catalysis

Visible-Light-Promoted Synthesis of Dibenzofuran Derivatives

(2017) Ji Young Cho et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Utilization of MeOH as a C1 Building Block in Tandem Three-Component Coupling Reaction

(2017) Kaushik Chakrabarti et al.   ORGANIC LETTERS

Cobalt-Catalyzed α-Alkylation of Ketones with Primary Alcohols

(2017) Guoqi Zhang et al.   ORGANIC LETTERS

Dehydrogenative Oxidation of Alcohols in Aqueous Media Catalyzed by a Water-Soluble Dicationic Iridium Complex Bearing a Functional N-Heterocyclic Carbene Ligand without Using Base

(2017) Ken-ichi Fujita et al.   ACS Catalysis

Supported Palladium Nanoparticle Catalyzed α-Alkylation of Ketones Using Alcohols as Alkylating Agents

(2017) C. Bal Reddy et al.   ACS Sustainable Chemistry & Engineering

Manganese-Catalyzed Hydrogen-Autotransfer C−C Bond Formation: α-Alkylation of Ketones with Primary Alcohols

(2016) Miguel Peña-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and Mild Cobalt-Catalyzed C-Alkylation of Unactivated Amides and Esters with Alcohols

(2016) Nicklas Deibl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acceptorless Dehydrogenative Coupling of o-Aminobenzamides with the Activation of Methanol as a C1 Source for the Construction of Quinazolinones

(2016) Feng Li et al.   ORGANIC LETTERS

Acceptorless Dehydrogenative Cyclization of o-Aminobenzyl Alcohols with Ketones to Quinolines in Water Catalyzed by Water-Soluble Metal–Ligand Bifunctional Catalyst [Cp*(6,6′-(OH)2bpy)(H2O)][OTf]2

(2016) Rongzhou Wang et al.   ORGANIC LETTERS

Iron-Catalyzed α-Alkylation of Ketones with Alcohols

(2015) Saravanakumar Elangovan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Production from a Methanol-Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions

(2015) Ken-ichi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TheN-Alkylation of Sulfonamides with Alcohols in Water Catalyzed by the Water-Soluble Iridium Complex {Cp*Ir[6,6′-(OH)2bpy](H2O)}[OTf]2

(2014) Panpan Qu et al.   ADVANCED SYNTHESIS & CATALYSIS

α-Alkylation of Ketones with Primary Alcohols Catalyzed by a Cp*Ir Complex Bearing a Functional Bipyridonate Ligand

(2014) Feng Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Alkenylation of Ketone Enolates under Mild Conditions

(2014) Michael Grigalunas et al.   ORGANIC LETTERS

Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect

(2014) Cheng Hou et al.   ACS Catalysis

Efficient Catalyst for Acceptorless Alcohol Dehydrogenation: Interplay of Theoretical and Experimental Studies

(2014) Guixiang Zeng et al.   ACS Catalysis

Additional Vinyl Ketones and Their Pyranyl Ketones in Gonyleptid Harvestmen (Arachnida: Opiliones) Suggest These Metabolites Are Widespread in This Family

(2013) Felipe C. Wouters et al.   JOURNAL OF NATURAL PRODUCTS

Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium

(2013) Timothy P. Brewster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Reactions of Trimethylsilyldiazomethane with 4-Alkenyl Ketones and Aldehydes Catalyzed by Lewis Bases

(2013) Huaqing Liu et al.   ORGANIC LETTERS

Osmium Catalyst for the Borrowing Hydrogen Methodology: α-Alkylation of Arylacetonitriles and Methyl Ketones

(2013) María L. Buil et al.   ACS Catalysis

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium catalysed chemoselective alkylation of 2′-aminoacetophenone with primary benzyl type alcohols under microwave conditions

(2012) Shailen Bhat et al.   CHEMICAL COMMUNICATIONS

Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure

(2012) Wan-Hui Wang et al.   Energy & Environmental Science

Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system

(2011) Nicolas R. Vautravers et al.   CHEMICAL COMMUNICATIONS

Effective synthesis of 2,5-disubstituted tetrahydrofurans from glycerol by catalytic alkylation of ketones

(2011) Magnus Rueping et al.   GREEN CHEMISTRY

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multialkylation of Aqueous Ammonia with Alcohols Catalyzed by Water-Soluble Cp*Ir−Ammine Complexes

(2010) Ryoko Kawahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Nickel-Catalyzed Three-Component Coupling of Alkynes with Enones and Alkenyl Boronic Acids: A Novel Route to Substituted 1,3-Dienes

(2010) Chun-Ming Yang et al.   ORGANIC LETTERS

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones

(2009) Miguel Paradas et al.   JOURNAL OF ORGANIC CHEMISTRY

Design, Synthesis, and Biological Evaluation of New-Generation Taxoids

(2008) Iwao Ojima et al.   JOURNAL OF MEDICINAL CHEMISTRY