期刊
JOURNAL OF CARBOHYDRATE CHEMISTRY
卷 40, 期 7-9, 页码 361-400出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/07328303.2022.2031207
关键词
Carbohydrate mimetics; glycosyl precursors; glycosylation; radical reactions
资金
- Shanghai Sailing Program [21YF1420600]
- Natural Science Foundation of Shanghai [21ZR1435600]
- Shanghai Jiao Tong University [AF1100077/008, WH220432508]
Radical glycosylation has emerged as a powerful method for synthesizing carbohydrate mimetics, with novel glycosyl radical precursors being identified for the synthesis of various glycosides. This review highlights recent advances in radical glycosylation and provides insights for future research directions.
Radical glycosylation has gradually become a powerful and effective method to synthesize carbohydrate mimetics as reactions via radical intermediates usually provide excellent functional group compatibility and good anomeric selectivity. Novel glycosyl radical precursors have been identified as glycosyl donors in radical glycosylation to access C-, S- and Seglycosides. This review aims at summarizing the remarkable advances in radical glycosylation reactions to illuminate potential future research directions. Herein, the most recent literature concerning radical glycosylation is covered with a specific emphasis on radical precursor design along with discussions of consequential mechanisms.
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