Article
Materials Science, Multidisciplinary
Dong Wu, Yaxin Xu, Wenya Li, Ningsong Fan, Yang Yang, Shuo Yin
Summary: In this study, an equimolar FeCoNiCrMn high-entropy alloy (HEA) was fabricated using solid-state cold spray additive manufacturing (CSAM) technique and post-annealing. The microstructure evolution and mechanical properties were evaluated. Tensile test results showed that the deposited sample annealed at 1000 degrees C for 2 h exhibited improved tensile strength and ductility compared to the as-sprayed sample. The combination of CSAM and post-annealing strategy achieved a strength-ductility synergy in HEA deposits.
MATERIALS CHARACTERIZATION
(2023)
Article
Nanoscience & Nanotechnology
Ningsong Fan, Aran Rafferty, Rocco Lupoi, Wenya Li, Yingchun Xie, Shuo Yin
Summary: In this study, equiatomic CoCrFeNi high-entropy alloy was manufactured using solid-state cold spray additive manufacturing technology and then post-spray annealed at temperatures ranging from 500 to 1000 degrees C. Different types of deposits were obtained by adjusting the annealing temperature, and their microstructure and mechanical properties were examined. The as-sprayed deposit showed high compressive yield strength but fractured in the tensile test, indicating tension-compression asymmetry. Recrystallization annealing improved the deposit density and reduced interparticle interfaces, leading to enhanced compressive strength and ductility. Fully recrystallized deposit exhibited weakened tension-compression asymmetry and the best recovery of tensile ductility.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Review
Materials Science, Multidisciplinary
Wei Zhang, Ali Chabok, Bart J. Kooi, Yutao Pei
Summary: This article summarizes the microstructure characteristics, mechanical properties, and functional properties of additive manufactured high entropy alloys (HEAs), providing a fundamental understanding of this research field. The article also discusses the current challenges and future work in this area.
MATERIALS & DESIGN
(2022)
Article
Engineering, Manufacturing
Davoud M. Jafarlou, Bryer C. Sousa, Matthew A. Gleason, Gehn Ferguson, Aaron T. Nardi, Danielle L. Cote, Ian R. Grosse
Summary: The research introduces the cold spray process as a method for additive manufacturing of tantalum and extensively evaluates the material's mechanical properties. While anisotropy in the mechanical properties was observed, the material exhibited high strength and excellent isotropy. The study reveals that the cold spray process is suitable for producing tantalum components.
ADDITIVE MANUFACTURING
(2021)
Review
Materials Science, Multidisciplinary
Ahmad Ostovari Moghaddam, Nataliya A. Shaburova, Marina N. Samodurova, Amin Abdollahzadeh, Evgeny A. Trofimov
Summary: The novel concept of high entropy alloys (HEAs) has led to the discovery of several promising materials with outstanding properties. Additive manufacturing (AM) provides new opportunities for fabricating complex HEAs and tailoring their microstructure. Future developments in HEAs are expected as the interest in AM of HEAs continues to grow.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Nanoscience & Nanotechnology
Di Ouyang, Pengcheng Zhang, Cheng Zhang, Ning Li, K. C. Chan, Lin Liu
Summary: A high-strength lamellar high-entropy alloy (HEA) of Zr45Ti31.5Nb13.5Al10 with excellent ductility was fabricated by in-situ alloying of blended elemental powders via laser directed energy deposition (DED). Microstructure characterizations suggest that the molten pools with body-centred cubic (BCC) structure and heat affected zones with mixed structure of BCC + ordered BCC (B2) nanoprecipitates, are alternately distributed in the DEDprocessed HEA with a lamellar structure. This research provides new options for the design and manufacturing of HEAs with outstanding mechanical properties for structural applications.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Chemistry, Physical
Zhiyu Zhang, Pan Ma, Yacheng Fang, Zhilu Yang, Nan Zhang, Konda Gokuldoss Prashanth, Yandong Jia
Summary: The particle size of the reinforcement plays a significant role in the microstructure and mechanical properties of composites fabricated by selective laser melting. The characteristics of the powder bed are greatly influenced by the size of the powder particles. In this study, two different reinforcement sizes were used to reinforce CoCrFeMnNi high entropy alloys (HEAs) with NiCoFeAlTi high entropy intermetallics (HEI). The microstructure and mechanical properties of the composites with varying particle sizes were systematically investigated. Composites with fine particle size exhibited intergranular cracking, element segregation, and poor mechanical properties, while composites with coarser particle size showed crack and pore-free microstructure with uniform compositional distribution and relatively outstanding mechanical properties. This research contributes to a better understanding of the effect of reinforcement particle size on crack-sensitive composites fabricated by selective laser melting.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Engineering, Manufacturing
Bo Xiao, Rong Chen, Jianyang Zhang, Jixun Zhang, Yinghao Zhou, Jiang Ju, Yilu Zhao, Lianyong Xu, Tao Yang
Summary: A cellular-structured high-entropy alloy was successfully fabricated using additive manufacturing technology, and subsequent thermal treatment led to a distinct microstructure. The material exhibited both high strength and large ductility, which were attributed to the presence of high-density precipitates in the wall and improved plastic deformation stability.
ADDITIVE MANUFACTURING
(2023)
Article
Nanoscience & Nanotechnology
Bosheng Dong, Zhiyang Wang, Zengxi Pan, Ondrej Muransky, Chen Shen, Mark Reid, Bintao Wu, Xizhang Chen, Huijun Li
Summary: The study investigated the effects of layer-remelting on high entropy alloys, revealing that it significantly degrades the tensile strength and ductility of prepared alloys. Repeated remelting of deposited material leads to thermally induced plasticity, increasing the amount of stored dislocations in the microstructure and limiting interfacial strengthening. Despite the potential strain hardening effects, the constrained dendritic morphology of BCC grains dominates and results in the loss of tensile strength.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Coatings & Films
Hongjian Wu, Chunjie Huang, Xinliang Xie, Shaowu Liu, Tao Wu, Thomas Niendorf, Yingchun Xie, Chunming Deng, Min Liu, Hanlin Liao, Sihao Deng
Summary: This article introduces four typical spray trajectories used in industrial robots during cold spray process and their effects on Cu deposits. The study found that spray trajectories have a significant impact on thermal history and residual stress distribution, but no significant differences were found in microstructures and mechanical properties. The Cu coating presented anisotropic characteristics that influenced performances in different directions, and post-heat treatment improved mechanical performances to some extent.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Engineering, Manufacturing
Yansong Zhang, Huaming Wang, Yanyan Zhu, Shuquan Zhang, Fang Cheng, Junwei Yang, Bing Su, Chen Yang
Summary: Lightweight refractory high-entropy alloys (LRHEAs) have lower density and better ductility compared to other refractory high-entropy alloys. Laser directed energy deposition additive manufacturing (LDED) technology is an ideal process for preparing LRHEAs. This study investigated the microstructure evolution and the plastic deformation mechanisms of a new LRHEA Al0.3NbTi3VZr1.5 fabricated by LDED.
ADDITIVE MANUFACTURING
(2023)
Article
Chemistry, Physical
Xinliang Xie, Chaoyue Chen, Zhe Chen, Ahmed Addad, Yingchun Xie, Hongjian Wu, Christophe Verdy, Yan Wang, Jiang Wang, Zhongming Ren, Gang Ji, Hanlin Liao
Summary: Cold spray technology can be used to fabricate metal matrix composites or repair damaged components, but poorly bonded interfaces and pores can affect mechanical performance. This study used a special designed composite powder to produce TiB2/AlSi10Mg composites, and post-annealing treatment was shown to improve mechanical properties.
SURFACES AND INTERFACES
(2021)
Article
Engineering, Manufacturing
Bharat K. Jasthi, Terrence S. Kuca, Marius D. Ellingsen, David L. Ellis, Venkata A. S. Kandadai, Todd R. Curtis
Summary: The aim of this study was to analyze the microstructure and mechanical properties of Cu-Cr-Nb (GRCop-42) and Fe-Ni-Cr (HR-1) alloy deposits produced using high-pressure cold spray. GRCop-42 powder blended with varying amounts of HR-1 powder underwent cold spray deposition, and the resulting deposits were evaluated. The use of He process gas resulted in lower porosity and better mechanical properties compared to N2 process gas. Post-deposition heat treatment improved ductility and tensile strength for both GRCop-42 and HR-1 deposits, but also caused certain undesired phase formations.
ADDITIVE MANUFACTURING
(2023)
Article
Materials Science, Coatings & Films
Yongming Zou, Zhaoguo Qiu, Chunjie Huang, Dechang Zeng, Rocco Lupoi, Nannan Zhang, Shuo Yin
Summary: In this study, high entropy alloy composite coatings were successfully fabricated using cold spray technique, showing higher hardness and improved wear-resistance properties compared to pure alloy coatings. The reinforcing effect of Al2O3 particles and the formation of a tribo-layer were the main reasons for the improvements in the composite coatings.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Chemistry, Physical
Qingkai Shen, Jiaxiang Xue, Xiaoyan Yu, Zehong Zheng, Ning Ou
Summary: Powder plasma arc additive manufacturing (PPA-AM) is a promising method for preparing high-entropy alloys (HEAs) with the advantages of low cost, high efficiency, and high quality. In this study, CoCrFeNiWx (x = 0, 0.2, 0.5, 0.7, and 1.0) HEAs were successfully prepared via PPA-AM, and the effects of W content on the microstructure and mechanical properties were investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Manufacturing
Chenwei Shao, Haoyang Li, Yankun Zhu, Peng Li, Haoyang Yu, Zhefeng Zhang, Herbert Gleiter, Andre McDonald, James Hogan
Summary: This study proposes an industrial approach to rapidly fabricate high-strength large-size nanostructured metal matrix composites. By controlling different strengthening mechanisms, the researchers were able to achieve higher hardness in the nanocrystalline aluminum matrix composites compared to bulk aluminum.
INTERNATIONAL JOURNAL OF EXTREME MANUFACTURING
(2023)
Article
Materials Science, Multidisciplinary
Okan K. Orhan, Mohamed Hendy, Mauricio Ponga
Summary: High-entropy alloys (HEAs) are promising radiation-resistant materials because of their complex local chemical environment and slow defect migration. In this study, we investigate the electronic properties and their impact on defect formation and recombination in random-solid solutions (RSS) of four and five principal elements HEAs. By performing first-principles calculations and two-temperature molecular dynamics simulations, we find that the electron-phonon coupling factor and electronic specific heat play a crucial role in Frenkel pairs formation. Furthermore, we show that including lighter elements can enhance the electron-phonon coupling, suggesting a potential approach to improve the radiation resistance of HEAs.
Article
Materials Science, Ceramics
Alex Yang, Dan Romanyk, James D. Hogan
Summary: A numerical approach combining finite element modeling and machine learning is used to predict the material performance of alumina ceramic tiles under high-velocity impact. The study simulates the tiles using a user-defined material model within the framework of smoothed particle hydrodynamics (SPH) in LS-DYNA finite element software. By matching the results from plate impact experiments and ballistic testing, the computational model is verified and used to generate training data for an artificial neural network (ANN) to predict the residual velocity and projectile erosion. This study demonstrates the capability of the FEM-ANN approach in studying high-velocity impact on ceramic tiles, providing valuable insights for the design of ceramic-based protection systems.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Zahra Zaiemyekeh, Haoyang Li, Saman Sayahlatifi, Min Ji, Jie Zheng, Dan L. Romanyk, James D. Hogan
Summary: This study uses finite element modeling to investigate the stress-state- and strain-rate-dependent behavior of CeramTec ALOTEC 98% alumina ceramic. The validated model reveals the effects of different parameters on the material response under various stress conditions. The study provides insights for the computational design and development of ceramic-based structures in higher-scale applications.
CERAMICS INTERNATIONAL
(2023)
Article
Engineering, Multidisciplinary
Benhour Amirian, Bilen Emek Abali, James David Hogan
Summary: This study models and investigates crack initiation, growth, propagation, and branching in two-dimensional single crystalline boron carbide at the nanometer length-scale and picosecond time-scale. A phase-field approach is used to capture the mechanics and damage coupling, and the FEniCS computing platform is utilized for numerical simulations. The results are important for modeling anisotropic fracture and designing advanced ceramics with desired dynamic failure characteristics.
COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING
(2023)
Article
Biophysics
Kevin Adanty, Kapil B. B. Bhagavathula, Olivia Tronchin, David X. X. Li, Karyne N. N. Rabey, Michael R. R. Doschak, Samer Adeeb, James Hogan, Simon Ouellet, Thomas A. A. Plaisted, Sikhanda S. S. Satapathy, Dan L. L. Romanyk, Christopher R. R. Dennison
Summary: This study reports on the mechanical response of 23 human calvarium specimens subjected to dynamic four-point bending impacts. The study found comparable effective bending moduli to previous research, but relatively lower fracture bending stress. Additionally, no significant differences in mechanical response were observed between male and female calvaria.
JOURNAL OF BIOMECHANICAL ENGINEERING-TRANSACTIONS OF THE ASME
(2023)
Article
Chemistry, Physical
Musanna Galib, Okan K. Orhan, Mauricio Ponga
Summary: Aqueous zinc-ion batteries (AZIB) show great potential as next-generation energy storage systems due to their high capacity and low cost. However, the dendrite and fracture formation on Zn anodes lead to capacity loss and cycling failure. Coating the Zn surface with an alucone layer can effectively improve the chemo-mechanical stability without compromising performance.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Materials Science, Ceramics
Jie Zheng, Min Ji, Zahra Zaiemyekeh, Haoyang Li, James D. Hogan
Summary: This study assessed the microstructure and properties of CeramTec ALOTEC 98 SB alumina ceramic and found it to have better mechanical properties than other commercial alumina ceramics. They used an ultra-high-speed camera and digital image correlation (DIC) to visualize crack initiation and propagation processes, and proposed a new data processing method to calculate shear components for compression-shear tests. New observations and understandings of failure mechanisms were obtained, including the importance of shear behavior and the influence of directional cracks.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Mohamed Hendy, Mauricio Ponga
Summary: This study presents a framework combining molecular dynamics simulations and atomistic diffusion simulations to investigate radiation-induced damage in nano-crystalline materials. It was found that nano-crystals exhibited self-healing behavior with a reduction in the number and size of defects over time. However, the self-healing behavior was limited, with about 50% of vacancies surviving. The collective behavior of vacancy clusters contributed to this effect.
JOURNAL OF NUCLEAR MATERIALS
(2023)
Article
Chemistry, Physical
Hannaneh Manafi Farid, Andre McDonald, James David Hogan
Summary: This study investigates the impact of porosity on the deposition of a ceramic-reinforced metal-matrix composite coating. The study utilizes constitutive models and finite element analysis to examine the effects of particle size, velocity, and pore characteristics on particle retention. The results highlight the importance of porosity in improving coating quality by enhancing particle retention.
Article
Multidisciplinary Sciences
Nathaniel J. M. Haven, Matthew T. Martell, Haoyang Li, James D. Hogan, Roger J. Zemp
Summary: Photoacoustic remote sensing is an all-optical imaging modality that can image various contrast agents without labeling. Using a high-speed camera, we further investigated the predicted reflectivity modulations caused by laser pulses and explored other potential mechanisms. We observed laser-induced motion in different samples and also non-motion-based intensity modulations, which are important for understanding the laser-pulse interactions.
SCIENTIFIC REPORTS
(2023)
Article
Engineering, Mechanical
Saman Sayahlatifi, Zahra Zaiemyekeh, Chenwei Shao, Andre McDonald, James D. Hogan
Summary: 3D micro-scale finite element models were developed to analyze the failure mechanisms and behavior of CSAM Al-Al2O3 composites under different stress states. The models quantified the matrix ductile failure, particle cracking, and matrix/particle debonding mechanisms based on crack volume fraction, fraction of cracked particles, and fraction of debonded interfacial nodes. The models were validated and used to study the effects of particle content and size on material behavior. The results showed that the failure mechanisms are activated in a specific order and that particle size minimally affects the material strength and flow stress under shear. This work provides a better understanding of the stress-state-dependent evolution of failure mechanisms and has implications for the design of improved Al-Al2O3 composites.
INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES
(2023)
Article
Engineering, Mechanical
Kyle Mao, Genevieve Toussaint, Alexandra Komrakova, James D. Hogan
Summary: In this study, the Generalized Incremental Stress State dependent damage MOdel (GISSMO) is used to simulate the high-velocity impact failure of Armox 500T steel. The GISSMO is calibrated and validated using experimental data from the literature, and is then applied to investigate the impact failure behaviors of bi-layered steel systems. The results provide new capabilities and insights for the design of armor structures and evaluation of impact failure behaviors in Armox 500T/RHA bi-layered systems.
INTERNATIONAL JOURNAL OF IMPACT ENGINEERING
(2024)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)