Sintering Temperature Effect on the Structural Phase, Microstructure and Electrical Properties of 0.92BNKLT-0.08BST Ceramics Prepared via the Solid State Combustion Method

Binary system ceramics of 0.92Bi(0.5)(Na0.68K0.22Li0.10)(0.5)TiO3-0.08Ba(0.5)Sr(0.5)TiO(3) (abbreviation as 0.92BNKLT-0.08BST) were prepared by the solid-state combustion method. Different sintering temperatures (between 1050 and 1150 degrees C for 2 h) were investigated for their effects on the structural phase, microstructure and electrical properties. 0.92BNKLT-0.08BST ceramics showed a pure perovskite structure with coexisting phases of rhombohedral and tetragonal, in all samples. The tetragonality and the lattice parameters increased with increasing sintering temperatures. The ceramics' grains showed polygonal shapes with anisotropic growth. The average grain size increased from approximately 0.35 to 0.83 mu m when the sintering temperature increased from 1050 to 1150 degrees C. The highest density of 5.83 g/cm(3) and the maximum dielectric constant at T-m (epsilon(m)) 5006 were obtained by the sample sintered at 1100 degrees C for 2 h. With higher sintering temperatures, the P-E hysteresis curves exhibited more pinched loops which indicated higher relaxor behavior. A large strain of 0.21% and a high normalized strain piezoelectric coefficient (d(33)*), around 420 pm/V, were achieved at the sintering temperature of 1125 degrees C for 2 h.

Automated summary

Binary system ceramics of 0.92BNKLT-0.08BST were prepared by solid-state combustion method and the effects of different sintering temperatures on their structural phase, microstructure, and electrical properties were investigated. The ceramics exhibited a pure perovskite structure with coexisting phases of rhombohedral and tetragonal. The tetragonality and lattice parameters increased with increasing sintering temperatures. Higher sintering temperatures resulted in larger grain size and higher relaxor behavior. The sample sintered at 1125 degrees C for 2 hours showed the highest strain and a high piezoelectric coefficient.