期刊
GREEN CHEMISTRY
卷 24, 期 1, 页码 136-141出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc03465k
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资金
- National Natural Science Foundation of China [21603089]
- Natural Science Foundation of Jiangsu Province [BK20160209]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [16KJB150014]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX20_2354]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
Pyridinium-based ionic porous organic polymers (Py-iPOPs) were constructed from newly designed acetonitrile-functionalized ionic liquids and multi-carbaldehyde monomers by base-catalyzed Knoevenagel condensation. The obtained Py-iPOPs are regarded as efficient metal-free and halogen-free heterogeneous catalysts for atmospheric CO2 fixation under mild conditions.
Pyridinium-based ionic porous organic polymers (Py-iPOPs) were constructed from newly designed acetonitrile-functionalized ionic liquids and multi-carbaldehyde monomers by base-catalyzed Knoevenagel condensation. The obtained Py-iPOPs having in situ formed hydroxide anions and pyridinyl radicals were regarded as efficient metal-free and halogen-free heterogeneous catalysts for atmospheric CO2 fixation under mild conditions.
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