A novel cooperative design with optimized flow field on bipolar plates and hybrid wettability gas diffusion layer for proton exchange membrane unitized regenerative fuel cell

Proton exchange membrane unitized regenerative fuel cell (PEM-URFC), as a novel electrochemical device which combines fuel cell (FC) and water electrolyzer (WE), is gradually being recognized as promising power source with reduction of size and cost. Unsatisfying mass transfer ability under the two adverse modes is the main factor hindering the commercialization of URFC, which calls for a bifunctional cell structure. In this study, a novel cooperative design with interdigitated flow field on bipolar plate (BPP) and a hydrophilic-hydrophobic alternative gas diffusion layer (GDL) is proposed to compose a new means of mass transfer under both working modes. Cells made up with different combinations of BPPs and GDLs are tested to confirm the usefulness of the new design. The cell with the optimized structure shows great progress in performance. The current density increases by 11.5% under FC mode and 4.8% under WE mode. EIS test and GDL's structure measurement are also carried out to further explain the working principle of the positive effect made by the new system on the cell. It is also found that the novel design of the URFC in this study has great adaptability to various operating conditions based on the stability test. (c) 2021 Elsevier Ltd. All rights reserved.

Automated summary

This study proposes a novel cooperative design for the proton exchange membrane unitized regenerative fuel cell, which combines an interdigitated flow field on bipolar plate and a hydrophilic-hydrophobic alternative gas diffusion layer to improve mass transfer under both working modes. The optimized structure shows significant progress in performance, with an increase in current density by 11.5% under FC mode and 4.8% under WE mode.