4.7 Article

Construction of interface-engineered two-dimensional nanohybrids towards superb fire resistance of epoxy composites

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2021.106707

关键词

Nano-structures; Polymer-matrix composites (PMCs); Flame retardancy; Interface-engineered strategy

资金

  1. National Natural Science Foundation of China [22005277, 52074247]
  2. Opening Fund of State Key Laboratory of Fire Science [BTBUFR21-4]
  3. Petroleum and Chemical Industry Engineering Laboratory of Non-halogen Flame Retardants for Polymers, Beijing Technology and Business University, China [BTBUFR21-4]
  4. Fundamental Research Funds of the National University, China University of Geosciences (Wuhan) [CUGGC09]

向作者/读者索取更多资源

The interface-engineered strategy used in this study, involving the introduction of polyaniline coating, established a strong interfacial linkage between phosphorus-doped cerium oxide and epoxy resin, resulting in superb fire resistance of the epoxy composites.
Interfacial interaction played a crucial role in the performance of nanofiller-reinforced polymer composites. Here, an interface-engineered strategy was adopted to establish the strong interfacial linkage between phosphorus-doped cerium oxide (P-CeO2) and EP via introducing polyaniline (PANI) coating, and then endow EP composites with superb fire resistance. The as-prepared P-CeO2@PANI nanohybrids were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetry analysis (TGA) and scanning electron microscopy (SEM), respectively. Subsequently, P-CeO2@PANI nanohybrids were incorporated into EP matrix to probe their influences on the thermal properties, flame retardancy and mechanical properties of EP composites. The coated PANI could strengthen the interfacial adhesion between PCeO2 and EP by covalent bonding, achieving a good dispersion state in EP matrix. Moreover, the introduction of P-CeO2@PANI nanohybrids led to the decreasing peak heat release rate (PHRR), total heat release (THR), peak CO production rate (PCO) and peak CO2 production rate (PCO2), with the reduction of 21%, 26%, 40% and 31%, respectively. Additionally, the introduction of P-CeO2@PANI enhanced cross-linking density and dynamic mechanical properties of EP composites. In conclusion, the reinforced interfacial interactions promoted the dispersion of interface-engineered nanofiller, which together with the lamellar barrier effect and catalytic effect of P-CeO2@PANI hybrids, contributed to the enhancements of the thermal properties, fire safety and mechanical properties of EP composites.

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