4.6 Article

S-defected In2S3/ZnS nanospheres for enhancing solar-light photocatalytic capacity

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ELSEVIER
DOI: 10.1016/j.colsurfa.2021.127126

关键词

In2S3/ZnS; Microwave-assisted hydrothermal; Solar-light photocatalysis; Junction interface

资金

  1. Natural Science Foundations of Qinghai Province [2021-ZJ-718]
  2. Key Research and Development Plan of Qinghai Province [2021-GX-103]
  3. Guangdong-Dongguan Joint Fund for Basic Research and Applied Basic Research [2020A1515110835]
  4. Chinese Academy of Sciences and Youth Innovation Promotion Association, CAS [2019423]
  5. National Innovation and Entrepre-neurship Training Program for Undergraduate [X2019118]
  6. Research Team Project of Neijiang Normal University [2020TD01]

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S-defected In2S3/ZnS nanospheres were synthesized via a microwave-assisted hydrothermal method for enhancing the solar-light induced photodegradation of TCH. The removal efficiency of TCH by In2S3/ZnS was higher compared to pure ZnS and In2S3, with the main active species being ·O-2(-) and h(+) in the photocatalytic system. The enhanced performance was attributed to the tight interface between In2S3 and ZnS for efficient transfer and utilization of photo-induced carriers.
S-defected In2S3/ZnS nanospheres were synthesized via a microwave-assisted hydrothermal mute for facilitating the solar-light induced photodegradation of tetracycline hydrochloride (TCH). The removal efficiency of TCH over In2S3/ZnS was higher in comparison to pure ZnS and In2S3. The adsorption-photocatalytic capacity of S-defected In2S3/ZnS was affected by In2S3 content, TCH concentration, inorganic salts, pH, and quenchers. The removal efficiency of optimal 3-In2S3/ZnS for TCH solution of 50 mg L-1 was 100% within 90 min, and decreased to 93.26% after five cycle times. The main active species were center dot O-2(-) and h(+) in solar-light driven photocatalytic system. The enhanced photocatalytic performance of S-defected In2S3/ZnS was due to the tight interface between In2S3 and ZnS for the efficient transfer and utilization of photo-induced carriers.

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