期刊
CHEMSUSCHEM
卷 15, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202102557
关键词
electrosynthesis; fluoroalkylation; sulfonyl compounds; sulfonylation
资金
- National Natural Science Foundation of China [22071269, 22171187]
- Pearl River Recruitment Program of Talent [2019QN01 L149]
- Project of Department of Education of Guangdong Province [2020KTSCX116]
- Shenzhen Science and Technology Foundation [20200812202943001, KQJSCX20180328100401788]
- Principal Foundation of Shenzhen University [8570700000307]
Electrosynthesis has gained more attention recently for its potential in replacing chemical oxidants or reductants in molecule-electrode electron transfer. Sulfonyl compounds have been found as practical precursors of several radicals, and electrochemical redox reactions offer green and efficient pathways for activating these compounds.
Electrosynthesis has recently attracted more and more attention due to its great potential to replace chemical oxidants or reductants in molecule-electrode electron transfer. Sulfonyl compounds such as sulfonyl hydrazides, sulfinic acids (and their salts), sulfonyl halides have been discovered as practical precursors of several radicals. As electrochemical redox reactions can provide green and efficient pathways for the activation of sulfonyl compounds, studies for electrosynthesis have rapidly increased. Several types of radicals can be generated from anodic oxidation or cathodic reduction of sulfonyl compounds and can initiate fluoroalkylation, benzenesulfonylation, cyclization or rearrangement. In this Review, we summarize the electrosynthesis developments involving sulfonyl compounds mainly in the last decade.
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