Qualification of operating conditions to extend oxygen carrier utilization in the scaling up of chemical looping processes

Chemical looping combustion (CLC) is a technology allowing CO2 capture at low cost. The development of durable oxygen carrier materials is a key factor for the scale-up of CLC. Once a promising oxygen carrier has been identified dedicated studies into the effects of reaction conditions on the durability of these kinds of materials are required in order to improve their reliability before use at industrial scale. This method requires several longterm tests in CLC units each one of them to fixed conditions, which is time consuming and expensive. In this work, a low-effort method using thermogravimetric analysis was developed and validated against a high-effort method requiring the use of an oxygen carrier material for hundreds of hours in a CLC unit. The reaction pathways and variation in physico-chemical properties of a material with 14 wt% CuO impregnated on Delta-Al2O3 during the course of 300 redox cycles were evaluated as a function of reaction temperature, variation in oxygen carrier conversion (Delta X-s) and degree of oxidation/reduction in every redox cycle. As a result, preferred conditions to be used in a CLC unit were identified. In general, reactivity and mechanical integrity were not affected when the reaction temperature was 800 degrees C. However, a temperature of 900 degrees C was found to be potentially suitable when the material was highly reduced in each redox cycle and.Xs was low. The use of this method for promising oxygen carriers can boost the identification of long lasting materials for the scale-up of chemical looping processes.

Automated summary

Chemical looping combustion (CLC) is a cost-effective technology for CO2 capture, and the development of reliable oxygen carrier materials is essential for its scale-up. A low-cost method using thermogravimetric analysis has been developed to accelerate the identification of long-lasting materials.