4.7 Article

Unlocking the role of pores in chloride permeability of recycled concrete: A multiscale and a statistical investigation

期刊

CEMENT & CONCRETE COMPOSITES
卷 125, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.cemconcomp.2021.104320

关键词

Recycled concrete; Pore structure analysis; Chloride penetration; X-ray computed tomography; Correlation analysis

资金

  1. Zhejiang Provincial Key Laboratory of Marine Geotechnical Engineering and Materials
  2. State Key Laboratory of Solid Waste Reuse for Building Materials [SWR-2021-004]
  3. State Key Laboratory of Clean Energy Utilization, Zhejiang University [109203*A62103/027]

向作者/读者索取更多资源

This study analyzed the impact of pore structures in recycled concrete on chloride permeability, proposed key pore parameters, and constructed a model for the chloride permeability of recycled concrete.
Chloride ingress is strongly associated with the properties of pores in recycled concrete. To unlock its role in chloride permeability, the pore structures of concrete containing various quantities of recycled coarse (fine) aggregates were analyzed from multi-scales, and the outcomes were further verified by the statistical investigation. The results show that different roles that recycled coarse (fine) played in terms of the pore structures of recycled concrete, as reflected by their volume and diameter of mesopores and micropores, respectively. Meanwhile, Unlike the previous studies, two key pore parameters (i.e., PV < 1 and PT) were put forward, revealing their strong interconnections with chloride diffusion of recycled concrete, as confirmed by the statistical analysis. Further, a model concerning chloride permeability of recycled concrete was proposed on a basis of the probability theory, and the newly proposed factor Rp (relied on the previous two pore parameters) has a great relevance to effective chloride diffusion. Therefore, this work enhances accuracy of prediction for chloride diffusivity and durability associated with recycled concrete.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Construction & Building Technology

Development of a functionally graded bacteria capsule for self-healing concrete

Xi Xiao, Ashley C. Y. Tan, Cise Unluer, En-Hua Yang

Summary: This paper presents the development of a new type of functionally graded reactive magnesia cement-based bacteria spores (RMC-B) capsule for self-healing concrete. The capsule is designed with a gradient structure consisting of a dense shell and a porous and low alkaline core to protect and enhance the viability of bacteria spores. The addition of the RMC-B capsules maintains the strength of the matrix and enables self-healing of cracks. The inclusion of these capsules does not negatively affect hydration and fresh properties of the paste, while improving the compressive strength and crack healing performance.

CEMENT & CONCRETE COMPOSITES (2023)

Article Construction & Building Technology

Development of nanofiber reinforced reactive magnesia-based composites for 3D printing

S. H. Chu, E. H. Yang, C. Unluer

Summary: Nanofiber reinforced reactive magnesia-based composites (nano-FRMC) with varying nanofiber contents and water to binder ratios were studied for their fresh properties and mechanical performance. The inclusion of nanofibers improved the shape stability and acceleration of leveling. An optimum nanofiber content was found to enhance the compression strength through fiber bridging and networking effects. Thermogravimetric analysis and scanning electron microscopy revealed the enhanced formation of hydrate and carbonate phases and microstructural evolution. A thixotropy index successfully modeled the variation of slump and flow diameter. The study deepened the understanding of nano-FRMC for 3D printing applications.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Materials Science, Ceramics

Understanding the role of seeds in reactive magnesia cement (RMC) formulations

Yufeng Song, Xiaoqian Qian, Dongming Yan, Cise Unluer, Yu Peng, Deyu Kong, Chuanlin Hu, Su Wang, Shaoqin Ruan

Summary: In this study, different types and contents of seeds were introduced in reactive magnesia cement (RMC) systems. The results showed that seeded RMC samples exhibited accelerated hydration/carbonation, resulting in faster strength development. Among the seeds, magnesite performed the best due to its more homogenous microstructures. Further experiments confirmed the nucleation effects of seeds in RMC formulations, and it was found that seeds had a higher affinity for Mg2+ ions, making them effective accelerators for curing RMC-based concrete products on a large scale.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Article Construction & Building Technology

Investigation of the properties of reactive MgO-based cements and their effect on performance

Tangwei Mi, En-Hua Yang, Cise Unluer

Summary: This study characterizes and investigates the effects of MgO properties on the performance of Reactive MgO cement (RMC) powders. The results show that hydration progress is highly dependent on the reactivity of RMC, while the purity influences the early stages of the reaction. Additionally, the agglomeration ratio is strongly correlated with strength after 7 days of carbonation curing and 28 days of hydration. A regression analysis is used to propose a model for predicting strength based on the initial properties of RMC powder. The findings can serve as a guideline for selecting suitable RMC-based binders for different building applications.

CEMENT & CONCRETE COMPOSITES (2023)

Article Construction & Building Technology

Unlocking the role of recycled aggregates in the performance enhancement and CO2 capture of reactive magnesia cement formulations

Chenyu Pan, Yufeng Song, Jiaze Wang, Shulin Zhan, Cise Unluer, Shaoqin Ruan

Summary: In this study, the strength development of CO2-cured RMC-RCA was explored for the first time, and the strength variation among groups was interpreted by microstructural analyses. The initial results show that the strength of RMC-RCA is higher compared to samples with natural aggregates, which could be attributed to its refined microstructures and larger carbonation depths. The presence of porous ITZs in RCA contributes to better CO2 diffusion, as described in the proposed revised CO2 diffusion model. Overall, this preliminary study could pave the path for the upcycling of RCAs in RMC concrete on a large scale while enabling a pronounced CO2 capture potential.

CEMENT AND CONCRETE RESEARCH (2023)

Review Engineering, Multidisciplinary

Development of alternative cementitious binders for 3D printing applications: A critical review of progress, advantages and challenges

Yiming Peng, Cise Unluer

Summary: This paper systematically reviews the recent advances in the use of key alternative binders in the context of 3D printing, including geopolymers/alkali-activated systems, aluminate cements, MgO-based cements, gypsum-based materials, and limestone-calcined clay-based cementitious materials. The paper provides a detailed discussion on the progress, challenges, and potential solutions in the development of 3D-printed components using these alternative binders. It also includes a comprehensive evaluation of the key properties controlling the performance of 3D-printed components prepared with different mixture proportions and curing conditions.

COMPOSITES PART B-ENGINEERING (2023)

Article Engineering, Environmental

Modeling the mechanical properties of recycled aggregate concrete using hybrid machine learning algorithms

Yiming Peng, Cise Unluer

Summary: By building a comprehensive database with 607 records, the complex functional relationship between key parameters of recycled aggregate concrete (RAC), such as recycled aggregate properties, mix proportion, and compressive strength, was explored. Two standard algorithms (artificial neural network and support vector regression) and two optimized hybrid models (Particle Swarm Optimization based support vector regression and grey Wolf optimizer based support vector regression) were used. Additionally, two interpretable algorithms (Partial Dependence Plot and SHapley Additive exPlanations) were applied to assess the global and local approaches independent of machine learning models. Results showed that the hybrid models outperformed the conventional models, with the coefficient of determination (R2) of the optimized hybrid models reaching above 0.89.

RESOURCES CONSERVATION AND RECYCLING (2023)

Article Construction & Building Technology

Performance buildup of reactive magnesia cement (RMC) formulation via using CO2-strengthened recycled concrete aggregates (RCA)

Chenyu Pan, Yufeng Song, Yuxi Zhao, Tao Meng, Yanlin Zhang, Ruohong Chen, Xiangming Zhou, Shaoqin Ruan

Summary: This study investigates the impact of recycled concrete aggregates (RCA) on the performances of reactive magnesia cement (RMC) formulations. The results suggest that RMC samples with carbonated RCA show the best 28-day strength and a faster strength gain, which is attributed to the refined microstructure.

JOURNAL OF BUILDING ENGINEERING (2023)

Article Engineering, Civil

Experimental and theoretical analyses of chloride transport in recycled concrete subjected to a cyclic drying-wetting environment

Songsong Lian, Tao Meng, Yuxi Zhao, Zhicheng Liu, Xiangming Zhou, Shaoqin Ruan

Summary: The diffusion behavior of chloride in recycled concrete was found to be different from that in normal concrete due to the high porosity of recycled aggregates. The maximum chloride concentration in the drying-wetting environment increased rapidly, but the decrease in the chloride diffusion coefficient was slower. The relationship between several parameters related to chloride diffusion was established, and a more sophisticated model considering key indexes was proposed.

STRUCTURES (2023)

Article Construction & Building Technology

Investigation of the viscoelastic evolution of reactive magnesia cement pastes with accelerated hydration mechanisms

Yiming Peng, Cise Unluer

Summary: The viscoelasticity of reactive magnesia cement (RMC) pastes with different hydration agents (HCl, Mg(CH3COO)2, and MgCl2) was studied. Various measurements were conducted to analyze the hydration reaction and products. The addition of hydration agents accelerated the growth rate of storage modulus/loss modulus over time. MgCl2 showed the strongest acceleration effect and had applications in 3D printing.

CEMENT & CONCRETE COMPOSITES (2023)

Article Construction & Building Technology

Single bacteria spore encapsulation through layer-by-layer self-assembly of poly(dimethyldiallyl ammonium chloride) and silica nanoparticles for self-healing concrete

Xi Xiao, Cise Unluer, Shaohua Chu, En-Hua Yang

Summary: Self-healing of cracks in concrete can be achieved through microbial induced calcite precipitation. A new approach using single bacteria spore capsule, formed by layer-by-layer self-assembly of poly(dimethyldiallyl ammonium chloride) and silica nanoparticles, is proposed to enhance the consistency of healing and minimize the negative impact on mechanical properties of concrete. The inclusion of the capsules, with a size of 1 μm, does not compromise the compressive strength of the matrix. Cement paste incorporating the capsules shows complete closure of large cracks and recovery of transport property along the entire crack.

CEMENT & CONCRETE COMPOSITES (2023)

Article Construction & Building Technology

A comparative study of ethylenediamine tetraacetic acid induced gas-solid and liquid-solid accelerated carbonation for enhancement of steel slag aggregates

Ning Li, Cise Unluer

Summary: In this study, ethylenediamine tetraacetic acid (EDTA)-induced dry and wet carbonation processes were proposed to accelerate the carbonation of steel slag aggregates (SSA). It was found that spraying EDTA on SSA before dry carbonation resulted in a denser carbonated layer and higher specific gravity. Wet carbonation of SSA in EDTA solution promoted both carbonation and hydration, reducing expansion of SSA.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Construction & Building Technology

Pore structures and interfacial properties between hydrated magnesia carbonates-modified recycled aggregate and reactive magnesia paste

Liyun Pu, Shaoqin Ruan, Chenyu Pan, Yufeng Song, Fangjun Zhou, Junying Lai, Kuangliang Qian, Qiang Li

Summary: This study investigates the impact of carbonation degree on the strength and pore structures of reactive magnesia cement (RMC) concrete by pretreating recycled aggregates using the carbonation technique. The results show that a higher carbonation degree contributes to strength improvement by forming well-developed carbonates and reducing porosity. However, a lower water-to-cement ratio improves mechanical performance by refining pore structures. The correlation between carbonation degree and strength is weaker due to different types of hydrated magnesium carbonates formed. The study also demonstrates that CO2 diffusion in RMC samples occurs through interfacial transition zones (ITZs) rather than capillary pores.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Construction & Building Technology

Properties and microstructures of 3D printable sulphoaluminate cement concrete containing industrial by-products and nano clay

Guangcheng Sun, Zhiguang Wang, Chengkun Yu, Xiaoqian Qian, Ruohong Chen, Xiangming Zhou, Yiwei Weng, Yufeng Song, Shaoqin Ruan

Summary: The producibility of calcium sulphoaluminate cement-based foam concrete (CSA-FC) with nano-clay and industrial by-products through concrete extrusion was confirmed. The use of appropriate amounts of nano-clay and desulfurized gypsum improved the hydration acceleration and extrudability of samples. A suitable mix design of CSA-FC with satisfactory performance, low carbon footprint, and cost was proposed through the extrusion technology.

JOURNAL OF BUILDING ENGINEERING (2023)

Article Construction & Building Technology

Unveiling the role of reactive magnesia and red mud in CO2-cured aerated concrete

Zhiguang Wang, Liyun Pu, Yuchen Yao, Jie Yang, Liping Li, Jinrong Luo, Shengquan Zhu, Qiang Zeng, Shaoqin Ruan

Summary: This study investigated the use of hydrated magnesia carbonates as the binding material for the production of aerated concrete, and studied the impacts of material design on the properties of aerated concrete. The results showed that the selection of Ca/Mg ratio and water/binder ratio in raw materials directly determined the properties of the aerated concrete.

JOURNAL OF BUILDING ENGINEERING (2023)

Article Construction & Building Technology

Development of a durability indicator to forecast the efficiency of preventive measures against external sulphate attack

Diego J. De Souza, Leandro F. M. Sanchez, Juarez Hoppe Filho, Marcelo H. F. Medeiros

Summary: This paper evaluates the physical and chemical properties of mortar mixtures with different binders and exposed to different sulphate solutions. A theoretical approach to describe the susceptibility of cementitious mixtures against sulphate attack is proposed. The results show that the amount of portlandite and the potential of ettringite formation are well correlated with the expansion and damage caused by sulphate attack.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

An approach to develop set-on-demand 3D printable limestone-calcined clay-based cementitious materials using calcium nitrate

Yu Chen, Hossein Rahmani, Erik Schlangen, Og uzhan Copurog

Summary: This study presents a method to accelerate the production of limestone-calcined clay-based cementitious materials using Ca(NO3)2 solution in 3D printing, and investigates the effects of adding Ca(NO3)2 solution on the material's properties. The results show that adding Ca(NO3)2 solution can improve buildability, accelerate initial setting, and increase compressive strength.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Understanding the formation and structure of bio-mineralization for self-healing of marine concrete: An experimental and thermodynamic approach

Jing Xu, Xianzhi Wang, Wu Yao, Qing Chen, Hehua Zhu, Surendra P. Shah

Summary: Concrete cracks in marine engineering are caused by the hostile seawater environment, leading to serious deterioration of infrastructures. Microbial induced carbonate precipitation (MICP) is an effective and environmentally friendly approach for self-healing of concrete cracks. However, the formation and structure of MICP products for crack healing in seawater are still unclear, which hinders the application of MICP in marine structures.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Self-healing and rebar corrosion performance of cracked engineered cementitious composites exposed to wet coral sand environment

Zhenbo Wang, Peng Sun, Yurun Fan, Yudong Han, Yudong Hu

Summary: This study investigates the potential use of engineered cementitious composites (ECCs) with strain-hardening and self-healing characteristics as a cover material in wet coral sand exposure. The results show that ECCs can effectively close cracks, reduce water permeability, and restore the load-carrying capacity of structures. Additionally, lower strain levels are associated with decreased rebar corrosion.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Long-term volume stability of ECC containing high-volume steel slag

Zhengxian Yang, Xiaoli Xiong, Kang Li, Bruno Briseghella, Giuseppe Carlo Marano, Shanghong Chen

Summary: This study investigates the long-term volume stability and strength development of engineered cementitious composites (ECC) containing high-volume steel slag (SS). It is found that the strength of ECC with SS starts to decline after 90 days, while the decline is more significant compared to the matrix. The expansion of SS reduces the fracture toughness of the matrix, leading to an increase in toughness and ductility of the ECC. The introduction of ground granulated blast furnace slag (GGBFS) and PVA fibers can reduce the volume expansion and strength loss caused by SS expansion.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Healing capacity of Ultra High Performance Concrete under sustained through crack tensile stresses and aggressive environments

Bin Xi, Zhewen Huang, Salam Al-Obaidi, Liberato Ferrara

Summary: This study investigates the self-healing capabilities of Ultra-High Performance Concrete (UHPC) under the combined influence of mechanical and environmental factors. The results reveal that UHPC with narrow cracks exhibits a higher degree of self-healing, especially when exposed to tap water. Furthermore, prolonged exposure mitigates the inhibitory effect of aggressive ions on self-healing.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Ti3C2Tx MXene modified polyethylene fibers for enhancing interface properties of strain-hardening cementitious composites

Zhichao Xu, Huayang Sun, Yanlin Huo, Minjie Jia, Zhitao Chen, Yingzi Yang

Summary: In this study, MXene was used to modify the surface of polyethylene fiber, improving the interfacial properties and tensile properties of strain hardening cementitious composites. The MXene-coated fiber showed increased tensile stress and strain, reduced crack width and spacing, and enhanced frictional bond strength between the fiber and matrix.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

High-purity vaterite CaCO3 recovery through wet carbonation of magnesium slag and leaching residue utilization in cement

Bao Lu, Yeqiang Zhou, Lei Jiang, Zhensen Liu, Guihua Hou

Summary: This study investigated the leaching rate of Ca2+ from magnesium slag (MS) and developed a leaching-carbonation method to convert MS into high-purity vaterite and supplementary cementitious materials. The wet carbonation process with glycine as a crystal modifier successfully produced spherical vaterite with high purity and surface area. The leachate solid residue (LSR) obtained from the leaching process of MS showed a smaller size destruction and higher surface area compared to Portland cement, leading to accelerated hydration process and improved compressive strength and pore structure development. This work provides a novel treatment method for MS and enables its high value-added utilization.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Smart laying mortars for masonry structures: effects of lime/cement ratio and carbon nanomaterials content on self-sensing behavior

Gustavo Henrique Nalon, Jose Carlos Lopes Ribeiro, Leonardo Goncalves Pedroti, Roberto Marcio da Silva, Eduardo Nery Duarte de Araujo, Gustavo Emilio Soares de Lima

Summary: The mechanical behavior of mortar joints is crucial for masonry's structural performance. This study investigated the effects of different lime/cement ratios and carbon black nanoparticles content on the properties of mortars. The results showed that increasing lime content decreased mortar strength but increased self-sensing properties at the end of the percolation zone.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Effect of diethanolisopropanolamine and ethyldiisopropylamine on hydration and strength development of cement-fly ash-limestone ternary blend

Yifei Wang, Lei Lei, Caijun Shi

Summary: The effects of DEIPA and EDIPA at dosages of 0.02% and 0.05% on the hydration and strength development of cement-fly ash-limestone ternary blend were investigated. It was found that both dosages of DEIPA and EDIPA promote the chemical effect of limestone and the hydration of aluminates from cement and fly ash. The hydration of silicates was accelerated by 0.02% of DEIPA or EDIPA but delayed by 0.05% due to excessive aluminates hydration. DEIPA and EDIPA also refine the pore structure and increase compressive strength of the blend mortar.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Cracking time and prediction model of low-alloy steel reinforced seawater sea-sand concrete based on DIC technology

Du Pan, Ditao Niu, Zongjin Li

Summary: A thick-walled cylinder model was developed in this study to analyze the cracking behavior of seawater sea-sand concrete (SSC) cover. Damage variables were introduced to determine the extent of damage for each cracked ring, and a predictive model for the cracking time of SSC cover was established. The accuracy of the model was verified using the Digital Image Correlation (DIC) technique.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Improvement of cemented rockfill by premixing low-alkalinity activator and fly ash for recycling gangue and partially replacing cement

Jiangyu Wu, Hong S. Wong, Hao Zhang, Qian Yin, Hongwen Jing, Dan Ma

Summary: This study explores a method of strengthening cemented rockfill by using well-graded gangue and partially replacing Portland cement with fly ash and a premixed low-alkalinity activator. The research investigated the effects of activator dosage and curing time on the mechanical properties, composition, and microstructure of cemented rockfill. Results show improved performance with low cement content and the use of a low-cost activator. The addition of premixed activator to fly ash enhanced the formation of specific minerals and caused densification of the microstructure. The study reveals an effective and low-cost method for recycling mining wastes and reducing cement.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Influence of alkaline activator and precursor on the foam characterization and alkali-activated foamed concrete properties

Juntao Dang, Xiaosong Tang, Jianzhuang Xiao, Aihong Han

Summary: This study proposes a solution to improve the fresh stability and thermal insulation of alkali-activated foamed concrete by adding recycled brick powder. The study investigates the effects of activator modulus and Na2O concentration on the properties of alkali-activated foamed concrete with different bases. The presence of alkaline activator negatively affects the foamability and foam stability, but adjusting the activator concentration can achieve shorter initial setting time and higher fluidity loss. In addition, the increased activator concentration resulted in changes in the pore structure of the foamed concrete.

CEMENT & CONCRETE COMPOSITES (2024)

Article Construction & Building Technology

Effects of nitrite ion intercalated CaAl and MgAl layered double hydroxides on the properties of concrete mortar

Jiandong Zuo, Bo Wu, Biqin Dong, Feng Xing, Jun Ma, Guanqi Wei

Summary: Nitrite ion intercalated Ca-Al and Mg-Al layered double hydroxides (LDHs) were successfully synthesized using two modified methods. The Ca-Al LDH synthesized by hydrothermal method (H-C-LDH) exhibited the best properties. The intercalated LDHs improved the mechanical properties, chloride penetration resistance, and permeability resistance of cement mortars without affecting the fluidity. Additionally, the intercalated LDHs provided better corrosion resistance.

CEMENT & CONCRETE COMPOSITES (2024)

Review Construction & Building Technology

Internal curing and its application to alkali-activated materials: A literature review

Jingbin Yang, Zhenping Sun, Nele De Belie, Didier Snoeck

Summary: This review paper provides an overview of internal curing mechanism, common internal curing agents, and the most promising agent-superabsorbent polymers in alkali-activated materials (AAM) systems. The introduction of voids by internal curing agents typically has a negative impact on mechanical properties, but continuous water release during internal curing counteracts this effect by promoting hydration. While the effect of internal curing in reducing autogenous shrinkage of AAM systems has been well-established, the impact on drying shrinkage varies widely in different studies.

CEMENT & CONCRETE COMPOSITES (2024)