4.8 Article

SWCNT-bridged laser-induced graphene fibers decorated with MnO2 nanoparticles for high-performance flexible micro-supercapacitors

期刊

CARBON
卷 183, 期 -, 页码 128-137

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2021.07.014

关键词

Single-walled carbon nanotubes; Laser-induced graphene fibers; MnO2 nanoparticles; Hybrid electrodes; Flexible micro-supercapacitors

资金

  1. National Natural Science Foundation of China [62071073]
  2. National Key Research and Development Program [2018YFB2100100]
  3. Fundamental Research Funds for Central Universities [2019CDJGFGD007]
  4. Key Science and Technology Program of Chongqing [CSTC2017SHMS-ZDYFX0028]
  5. Technology Innovation and Application Project of Chongqing [cstc2018jszx-cyzdX0111]
  6. China Postdoctoral Science Foundation [2019M663433]
  7. Guangxi Key Laboratory of Manufacturing Systems and Advanced Manufacturing Technology [19-050-44-002K]

向作者/读者索取更多资源

Hybrid nanocomposites of metal oxide nanoparticles and 3D graphene, particularly in the form of flexible micro-supercapacitors, show superior performance due to the synergistic effect between conductive SWCNT-bridged LIGF network and high theoretical capacitance of MnO2 nanoparticles. These hybrid electrodes offer a facile and novel method to develop flexible energy storage devices with high performance, indicating great potential for various wearable electronics applications in the future.
Hybrid nanocomposites comprised of metal oxide nanoparticles and three-dimensional (3D) graphene possess the advantages of metal oxide and graphene, which have generated extensive attention. Here, we fabricate flexible micro-supercapacitors (MSCs) based on hybrid materials of single-walled carbon nanotubes (SWCNT)-bridged laser-induced graphene fibers (LIGF) decorated with manganese dioxide (MnO2) nanoparticles. SWCNT is deposited on the LIGF surface and the space between LIGF, which can bridge LIGF to form more conductive paths and provide more active areas to grow with MnO2 nanoparticles. Profiting from the synergistic effect between conductive SWCNT-bridged LIGF network and the MnO2 nanoparticles with high theoretical capacitance, the obtained flexible MSCs based on LIGF-C4/ MnO2 hybrid electrodes deliver an outstanding areal capacitance of 156.94 mF cm(-2), which is about 8 times higher than that of LIGF-MnO2 based MSC (20 mF cm(-2)). Additionally, the LIGF-C4/MnO2 MSCs also exhibit considerable areal energy density of 21.8 mWh cm(-2), long-term cycling stability, remarkable modular integration capability, and exceptional mechanical flexibility (with 90.5% capacitance retention after 1200 bending cycles). Therefore, the design of hybrid electrode materials proposed in this work offers a facile and novel method to develop flexible energy storage devices with high performance, suggesting great prospects for applications in future various wearable electronics. (C) 2021 Published by Elsevier Ltd.

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