From Esters to Ketones via a Photoredox‐Assisted Reductive Acyl Cross‐Coupling Strategy

Diastereoselective Synthesis of Aryl C‐Glycosides from Glycosyl Esters via C‐O Bond Homolysis

(2021) Yongliang Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

(2021) Purui Zheng et al.   Nature Communications

Mechanism and Selectivity Control in Ni- and Pd-Catalyzed Cross-Couplings Involving Carbon–Oxygen Bond Activation

(2021) Shuo-Qing Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Synthesis of Ketones from Methyl Esters by Nickel‐Catalyzed Suzuki–Miyaura Coupling

(2021) Yan‐Long Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel/Photoredox-Catalyzed Asymmetric Reductive Cross-Coupling of Racemic α-Chloro Esters with Aryl Iodides

(2020) Haixing Guan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Deaminative Acylation of Activated Aliphatic Amines with Aromatic Amides via C–N Bond Activation

(2020) Chu-Guo Yu et al.   ORGANIC LETTERS

Photoredox/Nickel Dual-Catalyzed Reductive Cross Coupling of Aryl Halides Using an Organic Reducing Agent

(2020) Abhishek Dewanji et al.   ORGANIC LETTERS

Nickel‐Catalyzed Synthesis of Dialkyl Ketones from the Coupling of N‐Alkyl Pyridinium Salts with Activated Carboxylic Acids

(2020) Jiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

(2020) Xiao-Ye Yu et al.   CHEMICAL REVIEWS

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silyl Radical Mediated Cross-Electrophile Coupling of N-Acyl-imides with Alkyl Bromides under Photoredox/Nickel Dual Catalysis

(2020) Taline Kerackian et al.   ORGANIC LETTERS

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis

(2020) Marvin Parasram et al.   ACS Catalysis

Nickel-Catalyzed Direct Acylation of Aryl and Alkyl Bromides with Acylimidazoles

(2020) Junming Zhuo et al.   ACS Catalysis

Synergistic Activation of Amides and Hydrocarbons for Direct C(sp 3 )–H Acylation Enabled by Metallaphotoredox Catalysis

(2020) Geun Seok Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives

(2020) Jiandong Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Visible-Light-Driven Catalytic Reductive Carboxylation with CO2

(2020) Zhen Zhang et al.   ACS Catalysis

Dual Catalytic Strategy for Forging sp2–sp3 and sp3–sp3 Architectures via β-Scission of Aliphatic Alcohol Derivatives

(2020) Fei Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Engineering Electronic Structure of Single-Atom Pd Site on Ti 0.87 O 2 Nanosheet via Charge Transfer Enables C–Br Cleavage for Room-Temperature Suzuki Coupling

(2020) Yangxin Jin et al.   CCS Chemistry

Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents

(2019) Phil S. Baran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Acyl Suzuki Cross-Coupling

(2019) Jonathan Buchspies et al.   Catalysts

Migratory Reductive Acylation between Alkyl Halides or Alkenes and Alkyl Carboxylic Acids by Nickel Catalysis

(2019) Jun He et al.   ACS Catalysis

Direct Transformation of Aryl 2-Pyridyl Esters to Secondary Benzylic Alcohols by Nickel Relay Catalysis

(2019) Xianqing Wu et al.   ORGANIC LETTERS

A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines

(2019) Shengyang Ni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis

(2019) Jun Yi et al.   ORGANIC LETTERS

Ketones from Nickel-Catalyzed Decarboxylative, Non-Symmetric Cross-Electrophile Coupling of Carboxylic Acid Esters

(2019) Jiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling

(2019) Eugenio Gandolfo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-mediated external-reductant-free reductive cross coupling of benzylammonium salts with (hetero)aryl nitriles

(2019) Meng Miao et al.   Science China-Chemistry

Synthesis of Reversed C -Acyl Glycosides through Ni/Photoredox Dual Catalysis

(2018) Shorouk O. Badir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-noble metal-catalysed carbonylative transformations

(2018) Yahui Li et al.   CHEMICAL SOCIETY REVIEWS

Metal-Catalyzed Synthesis and Use of Thioesters: Recent Developments

(2018) Vera Hirschbeck et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)–C(sp3) Cross-Couplings

(2018) Adisak Chatupheeraphat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Method for the Synthesis of C–N-Linked Bi(heteroaryl)s Using Heteroaryl Ethers and N-Benzoyl Heteroarenes

(2018) Saori Tanii et al.   ORGANIC LETTERS

Photochemical Nickel-Catalyzed Reductive Migratory Cross-Coupling of Alkyl Bromides with Aryl Bromides

(2018) Long Peng et al.   ORGANIC LETTERS

Recent Advances in the Metal-Catalyzed Activation of Amide Bonds

(2018) Moreshwar B. Chaudhari et al.   Chemistry-An Asian Journal

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3–Csp3 Coupling of Aliphatic Bromides

(2018) Russell T. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Reductive Coupling of Electron-Rich Aryl Iodides with Tertiary Alkyl Halides

(2018) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C–C Bond Formation from Alkanes Using Ni-Photoredox Catalysis

(2018) Laura K. G. Ackerman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl–Alkyl Cross-Couplings

(2017) Avishek Paul et al.   JOURNAL OF ORGANIC CHEMISTRY

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Esters

(2017) Taoufik Ben Halima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe/Cu-Mediated One-Pot Ketone Synthesis

(2017) Vemula Praveen Kumar et al.   ORGANIC LETTERS

Photocatalytic α-Acylation of Ethers

(2017) Zhongdong Sun et al.   ORGANIC LETTERS

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides

(2017) Javad Amani et al.   ORGANIC LETTERS

General Method for the Suzuki–Miyaura Cross-Coupling of Amides Using Commercially Available, Air- and Moisture-Stable Palladium/NHC (NHC = N-Heterocyclic Carbene) Complexes

(2017) Peng Lei et al.   ACS Catalysis

Breaking Amides using Nickel Catalysis

(2017) Jacob E. Dander et al.   ACS Catalysis

Recent advances in visible-light-driven organic reactions

(2017) Qiang Liu et al.   National Science Review

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling

(2016) John C. Tellis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photoredox Catalysis for the Generation of Carbon Centered Radicals

(2016) Jean-Philippe Goddard et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Acylation of C(sp3 )−H Bonds Enabled by Nickel and Photoredox Catalysis

(2016) Candice L. Joe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Cooperative photoredox catalysis

(2016) Xianjun Lang et al.   CHEMICAL SOCIETY REVIEWS

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Alkyl Bromides: Et3N as the Terminal Reductant

(2016) Zhengli Duan et al.   ORGANIC LETTERS

Nickel-Catalyzed Diaryl Ketone Synthesis by N–C Cleavage: Direct Negishi Cross-Coupling of Primary Amides by Site-Selective N,N-Di-Boc Activation

(2016) Shicheng Shi et al.   ORGANIC LETTERS

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

(2016) Javad Amani et al.   ORGANIC LETTERS

Nickel-Catalyzed Alkylation of Amide Derivatives

(2016) Bryan J. Simmons et al.   ACS Catalysis

Radical Decarboxylative Functionalizations Enabled by Dual Photoredox Catalysis

(2016) Hanchu Huang et al.   ACS Catalysis

Photoredox sheds new light on nickel catalysis: from carbon–carbon to carbon–heteroatom bond formation

(2016) Yong-Yuan Gui et al.   Organic Chemistry Frontiers

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkyl–aryl ketone synthesis via nickel-catalyzed reductive coupling of alkyl halides with aryl acids and anhydrides

(2015) Xiao Jia et al.   CHEMICAL COMMUNICATIONS

Fragment Couplings via CO2 Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

(2015) Chi “Chip” Le et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

(2015) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalysed Suzuki–Miyaura coupling of amides

(2015) Nicholas A. Weires et al.   Nature Chemistry

Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations

(2015) Jun Gu et al.   Organic Chemistry Frontiers

Reductive Cross-Coupling Reactions between Two Electrophiles

(2014) Christiane E. I. Knappke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

(2014) Toni Moragas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides

(2014) Chenglong Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organic Electron Donors as Powerful Single-Electron Reducing Agents in Organic Synthesis

(2013) Julie Broggi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

(2013) Susan L. Zultanski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones

(2013) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild ketone formation via Ni-catalyzed reductive coupling of unactivated alkyl halides with acid anhydrides

(2012) Hongyu Yin et al.   CHEMICAL COMMUNICATIONS

Structure–Activity Relationships, Ligand Efficiency, and Lipophilic Efficiency Profiles of Benzophenone-Type Inhibitors of the Multidrug Transporter P-Glycoprotein

(2012) Ishrat Jabeen et al.   JOURNAL OF MEDICINAL CHEMISTRY

Chemoselective synthesis of ketones and ketimines by addition of organometallic reagents to secondary amides

(2012) William S. Bechara et al.   Nature Chemistry

Ketone Formation via Mild Nickel-Catalyzed Reductive Coupling of Alkyl Halides with Aryl Acid Chlorides

(2012) Fan Wu et al.   ORGANIC LETTERS

Synthesis of Functionalized Dialkyl Ketones from Carboxylic Acid Derivatives and Alkyl Halides

(2012) Alexander C. Wotal et al.   ORGANIC LETTERS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

(2011) Xiao-Feng Wu et al.   CHEMICAL SOCIETY REVIEWS

Bioorthogonal Chemistry: Fishing for Selectivity in a Sea of Functionality

(2009) Ellen M. Sletten et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Cross-Coupling of Anhydrides with Organozinc Reagents: The Controlled Formation of Carbon−Carbon Bonds through the Nucleophilic Interception of Metalacycles

(2008) Jeffrey B. Johnson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION