4.8 Article

Cephalopod-Inspired Design of Photomechanically Modulated Display Systems for On-Demand Fluorescent Patterning

期刊

ADVANCED MATERIALS
卷 34, 期 4, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202107452

关键词

bioinspired materials; fluorescent patterning; photomechanically; single-input multiple-output; soft actuators

资金

  1. National Natural Science Foundation of China [52073297, 21774138, 51773215]
  2. Sino-German Mobility Program [M-0424]
  3. Key Research Program of Frontier Sciences, Chinese Academy of Sciences [QYZDB-SSW-SLH036]
  4. National Key Research and Development Program of China [2019YFC1606603]
  5. Youth Innovation Promotion Association of Chinese Academy of Sciences [2019297]
  6. K.C. Wong Education Foundation [GJTD-2019-13]

向作者/读者索取更多资源

Inspired by cephalopods, a new photomechanically modulated fluorescent system has been developed, enabling dynamic and reversible display of fluorescent patterns through control of NIR light signals. This bioinspired strategy shows promise for on-demand fluorescent display platforms with single-input multiple-output features.
Cephalopods can display variable body color/patterns upon environmental stimulation via bioelectricity-controlled muscle contraction/expansion of skin chromatophores. However, it remains challenging to produce artificial display analogs that exhibit reversible and rapid switching between multiple expected luminescent patterns, although such systems are very appealing for many practical uses (e.g., data encryption). Inspired by the bioelectromechanical display tactic of cephalopods, in this work, a conceptually new photomechanically modulated fluorescent system that enables on-demand display of fluorescent patterns via a cascading stimulation-mechanical movement-optical output conduction mechanism is presented. Specifically, this biomimetic system comprises a customizable hollow display panel and a bottom-tethered photothermally responsive fluorescent actuator. Under NIR light, the photomechanically bending movements of the fluorescent actuator will immediately cover the hollow window of the display panel and synchronously manifest as the display of fluorescent patterns. Owing to its desirable time- and light-power-dependent actuating behaviors, diverse fluorescent patterns/information can be dynamically and reversibly displayed by facilely controlling this single remote NIR signal. This bioinspired strategy is universal and promising for fabricating on-demand fluorescent display platforms that combine a wide choice of fluorophores, remote control with high spatial/temporal precision, and especially single-input multiple-output features.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Aggregation-Induced Emissive Carbon Dots Gels for Octopus-Inspired Shape/Color Synergistically Adjustable Actuators

Shuangshuang Wu, Huihui Shi, Wei Lu, Shuxin Wei, Hui Shang, Hao Liu, Muqing Si, Xiaoxia Le, Guangqiang Yin, Patrick Theato, Tao Chen

Summary: The study proposes the use of hydrophobic carbon dots to construct an aggregation-induced emission active glycol CDs polymer gel, which can be used for anisotropic bilayer soft actuators that undergo shape and color changes on water surfaces, leading to autonomous locomotion.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Supramolecular Hydrogel with Orthogonally Responsive R/G/B Fluorophores Enables Multi-Color Switchable Biomimetic Soft Skins

Hao Liu, Shuxin Wei, Huiyu Qiu, Muqing Si, Guoqing Lin, Zhenkuang Lei, Wei Lu, Lei Zhou, Tao Chen

Summary: Many living creatures have evolved to exhibit diverse appearance color changes in response to various environmental stimuli. Constructing artificial soft polymer hydrogels with similar multi-responsive multicolor tunable behaviors is challenging, but can enhance the function of certain machines. A novel class of supramolecular fluorescent polymeric hydrogels with wide multi-color tunability, multi-responsiveness, self-healing, and remolding capacities has been proposed, which can be used to create soft biomimetic color-changing skins for robots.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Engineering, Environmental

Biomimetic organohydrogel actuator with high response speed and synergistic fluorescent variation

Hui Shang, Xiaoxia Le, Muqing Si, Shuangshuang Wu, Yu Peng, Fuqing Shan, Si Wu, Tao Chen

Summary: This study presents an organohydrogel actuator with simultaneous shape and fluorescence color variation capability, offering insights for designing and fabricating novel soft robots.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Materials Science, Multidisciplinary

Dual-Channel Flexible Strain Sensors Based on Mechanofluorescent and Conductive Hydrogel Laminates

Guoqing Lin, Muqing Si, Longgang Wang, Shuxin Wei, Wei Lu, Hao Liu, Yi Zhang, Danyang Li, Tao Chen

Summary: Flexible strain sensors are important for various applications, and a dual-channel sensing system that can provide both strain-dependent electronic and visually optical signal responses is of interest. Researchers have developed mechanofluorescent and conductive hydrogel laminates inspired by squid skin color changes, which can be used for real-time human motion monitoring.

ADVANCED OPTICAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Mechanochemical transformation of fluorescent hydrogel based on dynamic lanthanide-terpyridine coordination

Guangqiang Yin, Jianxiang Huang, Depeng Liu, Rui Li, Shuxin Wei, Muqing Si, Feng Ni, Yinfei Zheng, Qiu Yang, Ruhong Zhou, Xiaoxia Le, Wei Lu, Tao Chen

Summary: As a burgeoning research field, ultrasound-responsive materials have attracted intense interest in health-care research. In this study, mechanochemical transformations of europium(III) complexes in a supramolecular hydrogel matrix were demonstrated. The hydrogel showed a noticeable fluorescence change in response to ultrasound, and the mechanochemical transformation was elucidated by molecular dynamics (MD) simulations and fully probed and evidenced by electrochemical experiments, X-ray photoelectron spectroscopy (XPS), and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy.

CHINESE CHEMICAL LETTERS (2023)

Article Materials Science, Multidisciplinary

Integrating Photorewritable Fluorescent Information in Shape-Memory Organohydrogel Toward Dual Encryption

Hui Shang, Xiaoxia Le, Yu Sun, Fuqing Shan, Shuangshuang Wu, Yinfei Zheng, Danyang Li, Dong Guo, Qingquan Liu, Tao Chen

Summary: Counterfeiting information is a serious global problem, and using organic hydrogels for information security protection is of great significance.

ADVANCED OPTICAL MATERIALS (2022)

Review Chemistry, Multidisciplinary

Mimicking Color-Changing Organisms to Enable the Multicolors and Multifunctions of Smart Fluorescent Polymeric Hydrogels

Wei Lu, Muqing Si, Xiaoxia Le, Tao Chen

Summary: Fluorescent polymer hydrogels (FPHs) have attracted significant interest due to their potential applications in visualized sensing, smart display, and soft actuators/robots. By learning from chameleons and cephalopods, researchers have made significant advances in preparing FPHs with multicolor tunability and multifunctional synergy. These FPHs have a wide range of applications and can be used in bioinspired actuators/robots, smart systems with fluorescent patterning capacities, and robust chemosensors.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Article Engineering, Environmental

Self-healing, tough, red-to-near-infrared (NIR) luminescent organohydrogels derived from supramolecular assemblies of common aggregation-induced emissive luminogens

Shuhui An, Xiaoyi Zhang, Muqing Si, Huihui Shi, Peng Wei, Jianwei Shen, Wei Lu, Tao Chen

Summary: In this study, red-to-NIR luminescent polymeric gels based on supramolecular co-assemblies of cationic terpyridine platinum (II) luminogen and anionic alginate were reported. The large red-shifted emission and good preservation of luminescence after incorporation into crosslinked poly(vinyl alcohol) networks were observed. These organohydrogels exhibited high stress-bearing capacity, pH-responsive emission, self-healing and remolding abilities, as well as biocompatibility.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Multidisciplinary

Bio-Inspired Electro-Thermal-Hygro Responsive Rewritable Systems with Temporal/Spatial Control for Environment-Interactive Information Display

Shuangshuang Wu, Huihui Shi, Shuxin Wei, Hui Shang, Weiping Xie, Xipao Chen, Wei Lu, Tao Chen

Summary: This study presents an ideal rewritable system inspired by the bioelectricity-triggered skin pattern switching in cephalopods. It consists of a conductive graphene film and carbon dots gel that undergo blue-to-red fluorescence-color changes through water-triggered aggregation and re-dispersion of carbon dots. The rewritability is achieved by using water ink to write on the carbon dots gel and utilizing the Joule heat of the graphene film to evaporate water. With highly controlled electrical stimulus, temporally/spatially controlled display is achieved, enabling on-demand delivery and regulation of the written information's duration time. Furthermore, a new-concept environment-interactive rewritable system is obtained by integrating sensitive acoustic/optical sensors and multichannel electronic time-delay devices. This work opens unprecedented avenues for rewritable systems and expands potential uses for information encryption/delivery.
Article Chemistry, Multidisciplinary

Synergistic fluorescent hydrogel actuators with selective spatial shape/color-changing behaviors via interfacial supramolecular assembly

Wei Lu, Ruijia Wang, Muqing Si, Yi Zhang, Shuangshuang Wu, Ning Zhu, Wenqin Wang, Tao Chen

Summary: In this study, robust fluorescent polymeric hydrogel actuators with spatially anisotropic structures were constructed using an interfacial supramolecular assembly (ISA) approach, enabling control over synergistic shape/color-changing behaviors. The proposed ISA approach is universal and expected to open new avenues for developing bioinspired intelligent soft actuators/robotics with selective spatial shape/color-changing behaviors.

SMARTMAT (2023)

Article Chemistry, Multidisciplinary

A panther chameleon skin-inspired core@shell supramolecular hydrogel with spatially organized multi-luminogens enables programmable color change

Wei Lu, Muqing Si, Hao Liu, Huiyu Qiu, Shuxin Wei, Baoyi Wu, Ruijia Wang, Guangqiang Yin, Jiawei Zhang, Patrick Theato, Yen Wei, Tao Chen

Summary: Inspired by the core@shell structure in panther chameleons, a responsive multi-luminogen supramolecular hydrogel system was designed to achieve programmable multi-color fluorescent changes. Independent control over different luminogens enables easy adjustment of emission color, covering the full visible spectrum. Potential applications of this system include anti-counterfeiting materials.

CELL REPORTS PHYSICAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Optimizing supramolecular fluorescent materials with responsive multi-color tunability toward soft biomimetic skins

Muqing Si, Huihui Shi, Hao Liu, Hui Shang, Guangqiang Yin, Shuxin Wei, Shuangshuang Wu, Wei Lu, Tao Chen

Summary: Many natural organisms have evolved to display responsive biofluorescence color changes for various purposes, inspiring the development of artificial fluorescence-color changeable materials. Replicating the dynamic fluorescence color camouflage capacities of living organisms using soft synthetic materials is challenging, but such systems can enhance the function of machines like robots or prosthetics. The reported supramolecular fluorescent soft material with multi-color tunability and self-healing features has potential applications in soft biomimetic camouflage and display skins for machines, offering new possibilities for powerful fluorescent materials.

MATERIALS CHEMISTRY FRONTIERS (2021)

暂无数据