Article
Chemistry, Multidisciplinary
Yu-Ting Xu, Xiao-Feng Wang, Xin Qi, Qing-Yuan Zhao, Sheng-Jia Dai, Yi-Song Zheng, Sheng-Han Wang, Xiong-Wei Wu, Xian-Xiang Zeng
Summary: Reactive copper phthalocyanine (CuPc) is used to rebuild a zinc (Zn) anode, resulting in uniform zinc ion flux and smooth Zn deposition, while suppressing Zn corrosion. The CuPc@Zn battery exhibits low polarization voltages and high cumulative areal capacity under high current density, as well as excellent cycling stability. Furthermore, when paired with different cathode materials, the CuPc@Zn battery demonstrates superior performance.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Electrochemistry
Xiaomin Zeng, Xiangjuan Meng, Wei Jiang, Min Ling, Lijing Yan, Chengdu Liang
Summary: The study focuses on improving the performance of zinc anodes by constructing a polyacrylamide interphase, which enables homogeneous nucleation and high coulombic efficiency, leading to an extended lifespan of the battery.
ELECTROCHIMICA ACTA
(2021)
Article
Engineering, Environmental
Yifeng Li, Danyang Zhao, Jiajun Cheng, Yu Lei, Zisheng Zhang, Wenming Zhang, Qiancheng Zhu
Summary: This study reports a bifunctional nitrogen-doped carbon network as an interlayer in zinc-ion batteries to suppress dendrite growth. The interlayer exhibits both physical and chemical effects, balancing the electrostatic field and promoting the desolvation process, leading to the inhibition of dendrite growth and side-reactions. The symmetric cell with the interlayer demonstrates a long cycle life and stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Wenhao Liu, Yu Li, Haoyi Yang, Bo Long, Ying Li, Ying Bai, Chuan Wu, Feng Wu
Summary: This article summarizes the basic advantages, mechanisms and challenges of aluminum-based dual-ion batteries (ADIBs), and outlines various strategies for advanced cathode, electrolyte and aluminum anode in ADIBs. Finally, the key perspectives for the future development of ADIBs are discussed in detail.
ENERGY STORAGE MATERIALS
(2023)
Article
Engineering, Environmental
Huiqin Zhou, Wang Zhang, Long Wang, Xulei Sui, Panpan Wang, Zhenbo Wang
Summary: Uniform zinc deposition was achieved in aqueous zinc-ion batteries by constructing an interface film, resulting in improved cycling life and stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yuan Tian, Yongling An, Chengkai Liu, Shenglin Xiong, Jinkui Feng, Yitai Qian
Summary: By designing and growing multifunctional uniform antimony nanoarrays on Ti3C2Tx MXene paper, this study demonstrates the feasibility of antimony as an alloying-type Zn storage anode and provides an effective approach to suppress Zn dendrites.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Sijun Wang, Ze Yang, Botan Chen, Hang Zhou, Shuangfeng Wan, Lingzi Hu, Ming Qiu, Long Qie, Ying Yu
Summary: In this study, an organic-inorganic dual protection layer was built to address the issues of zinc dendrite growth and side reactions in AZIBs, resulting in improved cycling stability and lifespan of the batteries. This work paves the way for future development of AZIBs.
ENERGY STORAGE MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Zichen Qi, Ting Xiong, Tao Chen, Chao Yu, Mingchang Zhang, Yi Yang, Zejun Deng, Hong Xiao, Wee Siang Vincent Lee, Junmin Xue
Summary: This study reveals a dendrite-free ZIB anode through the hybridization of a eutectic ZnAl alloy with a copper mesh. The unique structure of the anode effectively reduces dendrite formation and side reactions, leading to improved performance stability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
Xin Qi, Fuli Xie, Yu-Ting Xu, Hai Xu, Cheng-Lin Sun, Sheng-Han Wang, Jian-Yong Hu, Xiao-Feng Wang
Summary: This study designs an organic molecule as an artificial layer to address the issues of dendrite growth and uneven zinc deposition in aqueous zinc ion batteries, which demonstrates promising prospects with long-term cycling stability and excellent rate performance. The sulfur-containing functional groups in the organic materials also successfully resolve the problems of zinc anodes.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Nanoscience & Nanotechnology
Neng Yu, Yanpeng Li, Wenhao She, Hanbin Li, Haoxiong Chen, Wenchong Cheng, Jinxue Chen, Haiyuan Liu, Yunliang Tu, Zhengkai Huang, Yinpeng Wan, Lixia Zou, Xing Zhong, Junming Luo, Kai Guo
Summary: The research successfully developed a robust sodium zinc phosphate layer (Zn@NZP) on zinc metal foil anode via facile electrodeposition, which effectively alleviates dendrite formation and corrosion issues on the anode of aqueous zinc batteries, leading to improved cycle life and battery performance.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Minghe Luo, Caiyun Wang, Haotian Lu, Yunhao Lu, Ben Bin Xu, Wenping Sun, Hongge Pan, Mi Yan, Yinzhu Jiang
Summary: This study utilized a chelating agent, BIS-TRIS, to regulate the solvation sheath structure of Zn2+ in aqueous Zn-ion batteries, restricting Zn2+ 2D diffusion and inhibiting dendrite growth. Partial substitution of water with chelator also suppressed the hydrogen evolution reaction. This strategy led to the achievement of a stable Zn cell and aqueous Zn/MnO2 battery.
ENERGY STORAGE MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Chenbei Zhang, Xiaohu Qian, Dong Wang, Chengtao Chen, Yingdong Chen, Tao Chen, Jiajun Fu
Summary: In this study, an ion-conductive supramolecular elastomer was developed based on the strategy of dynamic hard domains to improve the stability of zinc metal anode and enhance ion transport. The elastomer can adapt to the volume changes of zinc anodes and effectively inhibit water-induced corrosion, showing excellent cycling stability and electrochemical performance.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Xudong Huyan, Zhehan Yi, Zhiyuan Sang, Shandong Tan, Jiaxin Liu, Rui Chen, Wenping Si, Ji Liang, Feng Hou
Summary: In order to address the issues in the application of zinc powder anodes in industrial production, researchers introduced a polyethylene glycol (PEG) coating onto the surface of zinc powder to achieve corrosion-resistant, dendrite-free, and high utilized zinc anodes. This coating effectively suppressed hydrogen evolution reaction and induced ordered plating/stripping of Zn2+ on Zn (002) planes. This study provides new prospects for the modification of zinc powder anodes.
APPLIED SURFACE SCIENCE
(2023)
Article
Engineering, Environmental
Zhenglin Li, Lei Ye, Guoqiang Zhou, Wangwang Xu, Kangning Zhao, Xiaoman Zhang, Shu Hong, Tongtong Ma, Mei-Chun Li, Chaozheng Liu, Changtong Mei
Summary: A lignocellulose nanofiber (LCNF) separator with dual-function of water-gating and zinc-sieving is developed for dendrite-free zinc anodes in rechargeable aqueous zinc-ion batteries. The LCNF separator offers a hydrophobic surface, uniform nanopores, excellent mechanical performance, and high ionic conductivity. It enables increased zinc deposition kinetics, reduced desolvation barrier of hydrated zinc ions, and effectively suppresses zinc dendrite growth, promoting uniform zinc plating/stripping.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Applied
Ning Wang, Zhitan Wu, Yu Long, Derong Chen, Chuannan Geng, Xiaochen Liu, Daliang Han, Jing Zhang, Ying Tao, Quan-Hong Yang
Summary: Coating polymer on the surface is an effective way to enhance the stability of metal anodes in batteries. This study proposes a Ti3C2Tx MXene-assisted approach to construct polymer coating on zinc metal surfaces directly from the aqueous solution of monomers. By combining a doctor-blading method with spontaneous polymerization of monomers on the substrates at room temperature, a uniform, adhesive, and versatile coating layer assisted by a small amount of MXene is produced in one step. The coated zinc anode exhibits a long cycling lifespan and the assembled full cells show excellent cycling stability.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Electrochemistry
Bin Sun, MingHao Fang, ZhaoHui Huang, Hui Wu
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2018)
Article
Electrochemistry
Bin Sun, Kai Liu, Jialiang Lang, Minghao Fang, Yang Jin, Hui Wu
ELECTROCHIMICA ACTA
(2018)
Article
Chemistry, Multidisciplinary
Jing Xu, Kai Liu, Yang Jin, Bin Sun, Zili Zhang, Yi Chen, Dawei Su, Guoxiu Wang, Hui Wu, Yi Cui
ADVANCED MATERIALS
(2020)
Article
Nanoscience & Nanotechnology
Zili Zhang, Yu Zhao, Bin Sun, Jing Xu, Qianzheng Jin, Hongfei Lu, Nawei Lyu, Zhi-Min Dang, Yang Jin
Summary: The new method operates at atmospheric pressure, reducing equipment requirements and increasing safety; using water instead of fossil fuels as a hydrogen source reduces fuel consumption and CO2 emissions; low equipment requirements facilitate ready miniaturization and decentralization of the NH3 synthesizing process, promoting the possible use of renewable sources of electricity.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Kai Liu, Jialiang Lang, Minzheng Yang, Jing Xu, Bin Sun, Yulong Wu, Kuangyu Wang, Zhikun Zheng, Zeya Huang, Chang-an Wang, Hui Wu, Yang Jin, Yi Cui
Article
Chemistry, Multidisciplinary
Bin Sun, Yang Jin, Jialiang Lang, Kai Liu, Minghao Fang, Hui Wu
CHEMICAL COMMUNICATIONS
(2019)
Article
Chemistry, Multidisciplinary
Bin Sun, Jialiang Lang, Kai Liu, Naveed Hussain, Minghao Fang, Hui Wu
CHEMICAL COMMUNICATIONS
(2019)