期刊
HOLZFORSCHUNG
卷 70, 期 5, 页码 475-483出版社
WALTER DE GRUYTER GMBH
DOI: 10.1515/hf-2015-0119
关键词
cork Douglas fir; lipophilic extracts; phloem; suberin
资金
- FEDER funds through the Operational Programme for Competitiveness Factors - COMPETE under the project NewCork [38363]
- Centro de Estudos Florestais, a research unit - national funding of FCT - Fundacao para a Ciencia e a Tecnologia [UID/AGR/00239/2013]
Cork and phloem from Pseudotsuga menziesii outer bark were separated, fractionated and the 40- to 60-mesh fractions chemically analyzed. Cork and phloem showed a different grinding behavior with the highest yields for cork and phloem, respectively, for the 40- to 60-mesh fraction (31.4%) and the <0.180-mm fraction (49.2%). Cork chemical composition was (% o.d. mass): ash 0.9%; extractives 29.2% (mostly polar, 23.5%); lignin 16.8%, and suberin 36.2%. Polysaccharides (16.9%) contained glucose (55.4% of total neutral carbohydrates), xylose (13.3%), mannose, arabinose, and galactose as minor components. Lipophilic and suberin extracts from cork and phloem were analyzed by GC-MS, directly and after alkaline hydrolysis. In cork, catechin was the major compound identified in the lipophilic extract, accompanied by ferulic acid and acylglycerols. In phloem, beta-sitosterol was the major compound. The content of fatty alcohols and fatty acids increased after hydrolysis confirming their esterification in both extracts. Suberin from P. menziesii cork is rich in saturated omega-hydroxyacids (omega-hydroxyacids 36.2%, alpha,omega-diacids 18.6%, alkanoic acids 6.2%, and alkanols 8.7%), being different from suberin of Quercus suber where alpha,omega-diacids are dominant.
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