Review
Chemistry, Inorganic & Nuclear
Lan Sun, Qiaomei Luo, Zhengfei Dai, Fei Ma
Summary: Water electrolysis is crucial for hydrogen generation, requiring efficient electrocatalysts; Recent advancements include strategies like nanoarchitecturing and heteroatomic doping to enhance electrocatalyst performance; Challenges and opportunities lie ahead for improving water splitting performance.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Physical
Dongdong Wang, Yue Liu, Lili Liu, Dongfan Shan, Guixin Shen, Shanlong Peng, Heng Zhang, Xindong Wang
Summary: A three-dimensional multilevel nanoarray electrode with superaerophobicity was designed and fabricated, inspired by the underwater superaerophobicity of fish scales, to solve the bubble shielding effect in electrochemical reactions. The electrode exhibited outstanding electrocatalytic activity and durability, making it a promising catalyst for electrochemical water splitting.
Article
Engineering, Environmental
Hailin Liu, Zihao Li, Jie Hu, Zhaoling Qiu, Wei Liu, Jiangang Lu, Jiangang Yin
Summary: This study proposes a novel strategy for constructing self-supported cobalt oxide electrocatalysts with hierarchical nanostructures on a copper substrate using spatially shaped femtosecond laser ablation pretreatment. The self-supported electrocatalysts demonstrated favorable electrocatalytic properties in alkaline solutions, showcasing high activity and stability for water electrolysis.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Mingzhu You, Shasha Yi, Guanxing Zhang, Weimin Long, Deliang Chen
Summary: In this study, a stable catalyst based on Co2P/NiMoO4 heterojunction arrays supported on nickel foam was reported for water splitting and urea oxidation. The catalyst exhibited lower overpotential and higher catalytic performance at a large current density compared to a commercial catalyst RuO2/NF. The addition of Co2P was found to significantly affect the chemical environment and electron structure of NiMoO4, increasing the number of active sites and promoting charge transfer across the Co2P/NiMoO4 interface.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Green & Sustainable Science & Technology
Hengfei Qin, Shipeng Luo, Yan Li, Yifan Zhang, Ruoyu Dong, Yang Zhou, Jing Luo, Yeling Zhu, Feng Jiang
Summary: This study presents a low-cost nitrogen and sulfur co-doped carbon-supported cobalt sulfide dual-functional electrocatalyst derived from imidazole modified lignin for overall water splitting. It demonstrates the good performance of the catalyst in the overall water splitting process.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Engineering, Environmental
Taotao Gao, Xiaoqin Li, Xiaojuan Chen, Caixia Zhou, Qu Yue, Hongyan Yuan, Dan Xiao
Summary: The study successfully prepared a unique Fe/C@CNT carrier with an improved heterostructure, enhancing the stability and efficiency of catalysts. The Ni-Ru@Fe/C@CNT exhibited superior bifunctional activity and enduring stability, outperforming traditional catalysts significantly.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Linghui Zhang, Zheng Hu, Hui Li, Qianqian Ren, Yishu Qiu, Jianqiang Qu, Shi Hu
Summary: NiO@Ru nanosheets were fabricated on Ni foam surface through a two-step method, showing a thin layer of NiRuO3 sandwiched between NiO and Ru at the interface. The electrode exhibited high activity and durability for overall water splitting in 1 M KOH, delivering a current density of 10 mA cm(-2).
Article
Chemistry, Physical
Meng-Ting Chen, Jiao-Jiao Duan, Jiu-Ju Feng, Li-Ping Mei, Yang Jiao, Lu Zhang, Ai-Jun Wang
Summary: In order to enhance the overall water splitting efficiency, low-cost, abundant, and efficient bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are highly attractive yet challenging. The Fe,Rh-codoped Ni2P nanosheets arrays exhibited excellent catalytic performance for both OER and HER, with a small voltage of 1.62 V to drive a current density of 10 mA cm(-2) for overall water splitting. This work provides an alternative option for fabricating advanced catalysts in electrocatalysis and energy devices.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Yuanting Lei, Lili Zhang, Wenjing Xu, Chengli Xiong, Wenxing Chen, Xu Xiang, Bing Zhang, Huishan Shang
Summary: This study successfully synthesized a novel carbon fiber-supported multi-metal sulfide nanoarray using a mild cation exchange strategy. The resulting nanoarray exhibited excellent catalytic activity and stability in alkaline medium, providing a viable synthesis route for water electrolysis.
Article
Energy & Fuels
Ziyi Xu, Sinan Li, Weizhao Lu, Xiaoyi Dou, Yong Wu, Julan Zeng, Yuhai Dou, Jian Zhang, Jinchao Wei, Linping Yu
Summary: Constructing self-supported electrocatalysts is important for enhancing the performance of water splitting. In this study, a bimetallic phosphide CoNiP grown on a micro-sized porous nickel substrate showed low overpotentials for hydrogen and oxygen evolution reactions. The micro-sized porous nickel substrate provided a large surface area for active material loading, and the hierarchically porous structure facilitated mass transfer in the electrocatalytic reaction. The CoNiP/MP Ni electrocatalyst achieved ultra-low overpotentials and stable operation, making it a promising candidate for water splitting.
Article
Chemistry, Physical
Jiaxing Zhang, Aixiang Wei, Jun Liu, Jiali Zhu, Yuding He, Zhen Liu
Summary: In this study, a high-efficiency and low-cost bifunctional catalyst was prepared by depositing 2D CoFeLDH nanosheets on a self-supporting nickel sponge. The catalyst showed excellent electrocatalytic performances, including low overpotentials and high current densities, in alkaline solution.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Shuangshuang Jiang, Li Zhu, Zhanzhan Yang, Yingang Wang
Summary: A self-supported FeNiCo-based amorphous catalyst with hierarchical micro/nanoporous structure was successfully designed, showing fast reaction kinetics, abundant active sites, and significant catalytic activity under alkaline conditions, enabling stable electrolysis apparatus for overall water splitting.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Boru Xiong, Qiaoling Kang, Mengfei Su, Feng Gao, Qingyi Lu
Summary: In this study, a low Pt loading uniformly dispersed Pt nanoclusters on self-supported nickel foam (NF@Pt-1) was fabricated using dual surface guiding agents NaI and PVP. NF@Pt-1 exhibited excellent performance in hydrogen evolution reaction (HER), oxygen evolution reaction (OER), overall water splitting, and rechargeable zinc-air battery. This work explores an effective route for fabricating multifunctional electrocatalysts with relatively high performance-cost ratio.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Multidisciplinary
Min Jiang, Huanhuan Zhai, Libao Chen, Lin Mei, Pengfei Tan, Ke Yang, Jun Pan
Summary: A highly active bi-functional electrocatalyst of Ni2P/FeP heterostructures is constructed and demonstrates the synergistic catalytic mechanism of Ni and Fe species for overall water splitting. Ni enhances the oxygen evolution reaction (OER) performance by promoting the formation of high-valence FeOOH phase, while Ni2P/Ni(OH)2 heterojunction is identified as the high active phase for hydrogen evolution reaction (HER). This study not only develops a near-commercial bifunctional electrocatalyst, but also provides insights into the catalytic mechanism of Ni and Fe.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Ping Li, Wenjie Wei, Jin Li, Yanru Liu, Kaicai Fan, Lingbo Zong, Lei Wang
Summary: A bifunctional electrocatalyst Ru-Cu@CM/CC is prepared by a facile flash joule heating technology, showing remarkable performance for HER and OER in both alkaline and acid solution, outperforming Pt/C and RuO2, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Shuwen Cheng, Zhehao Sun, Kang Hui Lim, Ary Anggara Wibowo, Tianxi Zhang, Tao Du, Liying Liu, Hieu T. T. Nguyen, Gang Kevin Li, Zongyou Yin, Sibudjing Kawi
Summary: By stacking/constructing an ultrathin dual-defective two-dimensional (2D)/2D Z-scheme heterojunction with growing functional anionic vacancies onto both reductive and oxidative components of the Z-scheme, this work successfully overcomes the challenges of charge separation and redox capacities, achieving excellent photoactivity in CO2 reduction. The N-vacancy-rich g-C3N4 exhibits active and selective photoreduction ability, accompanied with oxidation reactions from O-vacancy-rich BiOCl. This work provides an effective adaptable dual-defect engineering on 2D/2D heterojunctions to enhance CO2 photoreduction.
Review
Nanoscience & Nanotechnology
Yuejiao Wang, Mukhtar Lawan Adam, Yunlong Zhao, Weihao Zheng, Libo Gao, Zongyou Yin, Haitao Zhao
Summary: To achieve a highly connected and productive smart society, advanced flexible sensing technology is essential. Recent advances in flexible sensing technology have improved the hardware performance of sensor devices and the data processing capabilities of their software. Significant research efforts have been dedicated to enhancing materials, sensing mechanisms, and configurations of flexible sensing systems to meet future technological requirements. Additionally, machine learning (ML) has emerged as a powerful tool for interpreting complex data collected by sensors and addressing challenges associated with multi-dimensional and multi-faceted information. This review presents the working mechanisms and common types of flexible mechanical sensors, explores how ML-assisted data interpretation enhances the applications of these sensors in various areas, and discusses the advantages, challenges, and future prospects of integrating flexible mechanical sensing technology with ML algorithms, ultimately contributing to the advancement of next-generation flexible mechanical sensing.
NANO-MICRO LETTERS
(2023)
Article
Chemistry, Applied
Qiang Zhang, Jianlin Wang, Fang Guo, Ge He, Xiaohui Yang, Wei Li, Junqiang Xu, Zongyou Yin
Summary: By treating Cu-based materials with N2 cold plasma, the activation of Cu0/Cu+-onAg interface was stabilized, resulting in improved Faradaic efficiency (FE) of CO2RR into C2 products.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Physics, Applied
Boqing Liu, Tanju Yildirim, Elena Blundo, Domenico de Ceglia, Ahmed Raza Khan, Zongyou Yin, Hieu T. Nguyen, Giorgio Pettinari, Marco Felici, Antonio Polimeni, Yuerui Lu
Summary: In this study, large pressurized monolayer TMD domes were fabricated using proton irradiation, and their SHG performance was comprehensively investigated. The results showed that the intensity of SHG was effectively enhanced by around two orders of magnitude at room temperature. This giant enhancement was attributed to the distinct separation distance induced by capped pressurized gas and the hemi-spherical morphology, which enabled constructive optical interference. Moreover, the unique divergent strain field in TMD domes promoted the first experimental study on the anisotropic nonlinear optical behavior based on biaxial strain conditions.
APPLIED PHYSICS REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Guodong Meng, Linghan Xia, Yonghong Cheng, Zongyou Yin
Summary: Gap distance and discharge power significantly influence the morphology and characteristics of glow plasma, but their influence on CO2 splitting by glow plasma has been rarely studied. By designing a plasma reactor, conducting numerical simulations and experimental investigations, the unique influence laws and mechanisms of CO2 splitting behavior are revealed. Key parameters such as gap distance, discharge power, and gas flow rate can synergistically improve the conversion and energy efficiency of the reactor.
JOURNAL OF CO2 UTILIZATION
(2023)
Review
Chemistry, Multidisciplinary
Fan Yang, Ping Hu, Fairy Fan Yang, Bo Chen, Fei Yin, Ruiyan Sun, Ke Hao, Fei Zhu, Kuaishe Wang, Zongyou Yin
Summary: Two-dimensional transition metal dichalcogenides (2D TMDs) have promising applications in various fields, such as electronics, optoelectronics, memory devices, batteries, superconductors, and hydrogen evolution reactions. This paper reviews recent enhancement approaches to induce magnetism in 2D TMDs, including doping, vacancy defects, heterostructure composites, phase modulation, adsorption, electron irradiation, and O plasma treatment. The effects of these methods on introducing magnetism into 2D TMDs are summarized and discussed. For future research, more reliable and efficient techniques, such as exploring advanced design strategies and advancing experimentation strategies, should be directed towards magnetic doping in 2D TMDs materials.
Article
Crystallography
Yanlin Zhang, Honglong Qu, Cheng Gang, Hongtao Guan, Chengjun Dong, Zongyou Yin
Summary: As a typical spinel ferrite, porous, tremella-like NiFe2O4 was fabricated using porous, ultrathin nanosheets via the coordination of Ni2+ and Fe2+ with 1,4-phenylenediboronic acid. The NiFe2O4 sensor exhibited a low detection limit of 50 ppb, a fast response/recovery time, good reproducibility, and long-term stability at 220°C, attributed to its good catalytic activity and the presence of porous ultrathin nanosheets. This work provides a new insight into the fabrication of NiFe2O4 using 1,4-phenylenediboronic acid and shows promising potential for ppb-level toluene detection.
Article
Crystallography
Ruonan Tian, Huai Tan, Gang Chen, Hongtao Guan, Chengjun Dong, Zongyou Yin
Summary: In this study, Fe-alkoxide was fabricated using a solvothermal method and converted into α-Fe2O3, γ-Fe2O3, and their mixed-phase α/γ-Fe2O3 with a flower-like nanosheets-assembled structure through thermal treatment. The influence of calcination temperature on the phase and sensing properties of acetone detection was investigated. It was found that the α/γ-Fe2O3 annealed at 400 ℃ contained 18% α-Fe2O3 and exhibited excellent sensing performance towards acetone. It showed a high response of 353 to acetone with a concentration of 200 ppm, a low limit of detection of 0.5 ppm at 160 ℃, and demonstrated good linearity, reproducibility, selectivity, as well as fast response and recovery times.
Article
Chemistry, Physical
Haijiao Lu, Nasir Uddin, Zhehao Sun, Zibin Chen, Zackaria Mahfoud, Yilan Wu, Ary Anggara Wibowo, Zhicheng Su, Xinmao Yin, Chi Sin Tang, Xiaozhou Liao, Simon P. Ringer, Xiu Song Zhao, Andrew T. S. Wee, Michel Bosman, Zongyou Yin
Summary: By integrating plasmonic bismuth nanoparticles and non-plasmonic redox heterojunctions, we have successfully achieved high activity and selectivity in the transformation of CO2 into methanol. This is achieved through the use of localized surface plasmon resonances (LSPRs) to direct the reaction pathways and optimize product selectivity.
Article
Chemistry, Multidisciplinary
Yuxuan Ji, Jian Wei, Di Liang, Bing Chen, Xueting Li, Hao Zhang, Zongyou Yin
Summary: Researchers adopt a higher operating voltage to expand the application scope and market share of LCO, but this causes capacity decay and safety issues. Coating Li3PO4 onto an LCO cathode increases the energy density of lithium-ion batteries. Enhancing the conductivity of cathode materials is crucial for raising their operating voltage. A direct coprecipitation method was used to coat Li3PO4 onto an LCO surface, balancing ionic conductivity and chemical stability. The optimized LP-3 cathode delivers a high initial discharge capacity of 181 mA h g(-1) at 0.5C, with a capacity retention of 75% after 200 cycles. This study introduces a competitive strategy for producing a high-voltage LCO cathode.
Correction
Chemistry, Multidisciplinary
Bing Bai, Chengxi Zhang, Yongjiang Dou, Lingmei Kong, Lin Wang, Sheng Wang, Jun Li, Yi Zhou, Long Liu, Baiquan Liu, Xiaoyu Zhang, Ido Hadar, Yehonadav Bekenstein, Aixiang Wang, Zongyou Yin, Lyudmila Turyanska, Jochen Feldmann, Xuyong Yang, Guohua Jia
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Mengdie Jin, Zhichao Zeng, Hao Fu, Siyuan Wang, Zongyou Yin, Xinyun Zhai, Qian Zhang, Yaping Du
Summary: In this study, highly stable perovskite nanocrystals were developed by doping Eu2+ into CsPbBr3. The Eu2+-doped CsPbBr3 nanocrystals exhibit tunable green-to-cyan emissions, high photoluminescence quantum yield, and good resistance to adverse conditions. The thermal stability of CsPbBr3 nanocrystals after Eu2+ doping is greatly enhanced, and they also show emissions of Eu2+. A cyan light emitting diode based on Eu2+-doped CsPbBr3 nanocrystals was fabricated, which displays narrow exciton emission under different current densities. This work provides a new approach to advancing perovskite nanomaterials for practical applications.
Article
Chemistry, Multidisciplinary
Guodong Meng, Fuzhi Zhan, Junyi She, Jinan Xie, Qinren Zheng, Yonghong Cheng, Zongyou Yin
Summary: In this study, the effect of nitrogen doping on the field emission properties of graphene was investigated. Experimental results showed that nitrogen doping could lower the turn-on field and increase the current density. Theoretical calculations revealed that nitrogen doping introduced additional charge and decreased the work function, thereby enhancing the field emission. Moreover, the study demonstrated the specific tunable effect of different nitrogen doping configurations and ratios on the field emission properties of graphene.
Article
Electrochemistry
Zhuo Wang, Zhehao Sun, Hang Yin, Honghe Wei, Zicong Peng, Yoong Xin Pang, Guohua Jiac, Haitao Zhao, Cheng Heng Pang, Zongyou Yin
Summary: Researchers have made significant progress in the field of CO2RR by utilizing machine learning techniques, including accelerated catalyst property prediction, activity and selectivity prediction, guided catalyst and electrode design, and assisted experimental synthesis. These advancements contribute to a better understanding of CO2RR and play a role in achieving carbon neutrality.
Article
Chemistry, Multidisciplinary
Doudou Zhang, Haobo Li, Haijiao Lu, Zongyou Yin, Zelio Fusco, Asim Riaz, Karsten Reuter, Kylie Catchpole, Siva Karuturi
Summary: This study fabricates a highly active ternary metal (hydro)oxide OER catalyst and uses machine learning methods to analyze its activity mechanism, demonstrating that adding Fe and Co can reduce overpotential and enhance activity. This study provides new insights into the activity mechanism of ternary metal (hydro)oxide amorphous catalysts.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)