Article
Chemistry, Multidisciplinary
Xiaoqi Wang, Xiaoning Liu, Richard Lee Smith, Yining Liang, Xinhua Qi
Summary: A method for the direct synthesis of ordered mesoporous carbons (OMCs) using lignin as a carbon precursor has been developed, with wide applications expected in catalysis, adsorption, sensor, drug delivery, and energy storage fields.
Article
Chemistry, Multidisciplinary
Mohammed Abdelhameed, Mahmoud Elbeh, Navajit S. Baban, Leticia Pereira, Julie Matula, Yong-Ak Song, Khalil B. Ramadi
Summary: The COVID-19 pandemic has caused a surge in the use of single-use plastics, posing serious environmental and health hazards. Converting plastic waste into valuable materials is crucial in mitigating these effects. A hydrothermal process has been developed to efficiently convert plastic bags and surgical masks into carbon dots, offering a sustainable solution to address plastic pollution.
Article
Green & Sustainable Science & Technology
Marta Lara-Serrano, Silvia Morales-delaRosa, Jose M. Campos-Martin, Victor K. Abdelkader-Fernandez, Luis Cunha-Silva, Salete S. Balula
Summary: The direct conversion of glucose to HMF was studied using MOF as catalysts and POM as a co-catalyst. Two routes were investigated and it was found that the reactions with MIL-53(Al) and MIL-101(Cr) catalysts produced the highest yield of HMF. Stability tests on the POM@MOF catalysts showed that MIL-53(Al) and Hsiw@ MIL-101(Cr) can be reused but with a progressive loss in HMF yield.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Chemistry, Physical
Gurmeet Singh, Jyotishman Kaishyop, Gaje Singh, Md. Jahiruddin Gazi, Arijit Bag, Chanchal Samanta, Ankur Bordoloi
Summary: This study aims to develop a new method for the production of N-substituted furfuryl amines using bio-based environmentally friendly chemicals. The results show that the PdCNTs catalyst, under optimized conditions, can convert furfural and aniline almost completely to N-(furan-2-ylmethyl) aniline in methanol, with a yield of over 99%. The catalyst also exhibits good recyclability.
MOLECULAR CATALYSIS
(2023)
Article
Chemistry, Multidisciplinary
Ning Shi, Tianlang Zhu, Hongyan Zhang, Hongsheng Huang, Liang Zhou, Ying Liu, Riyang Shu
Summary: Catalytic conversion of cellulose into 2,5-hexanedione (HXD) is an efficient method for high-value utilization of biomass resources. This study developed a one-pot conversion of cellulose into HXD with high yield using Al2(SO4)3 and Pd/C as catalysts. Al2(SO4)3 catalyzed the conversion of cellulose into intermediate HMF, while Pd/C and Al2(SO4)3 catalyzed the hydrogenolysis of HMF into furanic intermediates, which were further transformed into HXD by Al2(SO4)3. The catalytic system also showed excellent performance in converting glucose and sucrose into HXD.
Article
Chemistry, Multidisciplinary
Olatunji S. Ojo, Alejandro Bugarin
Summary: The study presents a new one-pot synthesis method for styrene derivatives using readily available natural products, achieving regioselectivity without transition metals. The methodology has broad nucleophile scope, even accommodating sterically hindered nucleophiles.
Article
Chemistry, Multidisciplinary
Seiji Ogo, Takeshi Yatabe, Tamon Tome, Riko Takenaka, Yoshihito Shiota, Kenji Kato
Summary: This paper reports a method for the synthesis of H2O2 using a homogeneous catalyst in water, using only H2 and O2 without flammable mixtures or cocatalysts. The catalyst can remove electrons from H2, store them for the reduction of O2, and allow the protonation of the reduced oxygen to form H2O2. The turnover number (TON) is 910 under an H2/O2 (95/5) atmosphere (1.9 MPa) for 12 hours at 23 degrees C, which is the highest among any homogeneous catalysts. Furthermore, a reaction mechanism based on two crystal structures is proposed.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Seiji Ogo, Takeshi Yatabe, Tamon Tome, Riko Takenaka, Yoshihito Shiota, Kenji Kato
Summary: In this study, a homogeneous catalyst is used to synthesize hydrogen peroxide using H2 and O2 in water, eliminating the need for flammable H2/O2 mixtures and cocatalysts. The catalyst is capable of extracting electrons from H2, storing them for the reduction of O2, and then converting the reduced oxygen to H2O2. The catalyst exhibits the highest turnover number (TON) among all homogeneous catalysts.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Green & Sustainable Science & Technology
Reena Goyal, B. Moses Abraham, Omvir Singh, Siddharth Sameer, Rajaram Bal, Prasenjit Mondal
Summary: A high surface acidic ZrO2 nanoparticle was prepared with glucose as a reducing agent, and Pd nanoparticles were successfully embedded. The particle size and nature of acidic sites were found to have a significant impact on the conversion rate and selectivity. The activation energy and TOF of the catalyst were also calculated, and a linear relationship between Pd loading and selectivity was observed. Characterization of the spent catalysts showed that smaller nanoparticles were prone to agglomeration, resulting in decreased stability and activity. Therefore, high catalytic performance can be achieved by balancing Bronsted and Lewis acid sites, combined with the intrinsic activity of Pd species.
Article
Chemistry, Organic
Akihiro Sugawara, Hirokazu Takada, Tomoyasu Hirose, Aoi Kimishima, Takeshi Yamada, Masaki Toda, Toru Kojima, Takanori Matsumaru, Toshiaki Sunazuka
Summary: A highly efficient Pd-catalyzed hydrostannylation method for alkyl ethynyl ethers has been developed, allowing for the generation of alkenyl ethers with high regio- and stereoselectivity. This method also enables scalable synthesis and construction of the core framework of luminamicin, containing all functional groups and stereocenters.
Article
Energy & Fuels
Xiaoli Yang, Zelin Li, Mingyu Guo, Tao Zhao, Xiong Su, Wei Jiang, Guangting Han, Haoxi Ben
Summary: A series of multifunctional NiCu/WO3 catalysts were prepared and applied for the one-pot catalytic conversion of cellulose to ethylene glycol (EG). By tuning the metal ratio and WO3 content, a high EG selectivity of 58.9% and a total diols selectivity of 83.9% were achieved. The catalyst exhibited excellent performance in the conversion of raw biomass, attributed to the unique catalyst structure and the formation of NiCu-WOx-1-O(H) interfacial sites.
Review
Agricultural Engineering
Dibyajyoti Haldar, Pinaki Dey, Jibu Thomas, Reeta Rani Singhania, Anil Kumar Patel
Summary: This article critically reviews the advancements in one-pot reaction systems for the production of value-added products from lignocellulosic biomass. It highlights the novelty of one-pot reactions in the fractionation of biomass into individual constituents and discusses the importance of direct conversion of cellulose and lignin into valuable products. The article also explores the opportunities, challenges, and possible solutions in lignocellulosic biorefinery.
BIORESOURCE TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Yanling Liu, Yaoyao Zhou, Yuxuan Lin, Guozhi Jia
Summary: In this study, broad-spectrum light-harvesting silver-selenium nanoparticles with good photothermal conversion properties were synthesized, and their characteristics and performance were characterized using various testing methods.
RESULTS IN PHYSICS
(2022)
Article
Engineering, Chemical
Natalia Sobus, Izabela Czekaj
Summary: This article presents the results of converting biomass-based glucose to levulinic acid using Na-BEA commercial zeolite catalyst. The study shows that the highest yield of levulinic acid is obtained at appropriate temperature and catalyst dosage.
Article
Chemistry, Organic
Anze Zupanc, Marjan Jereb
Summary: This study presents the synthesis and characterization of N-iodo sulfoximines, with a one-pot cascade reaction yielding high isolated yields and demonstrating the iodination of aryls, oxidation, and conversion to N-SCF3 congeners.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Biotechnology & Applied Microbiology
A. Taleb, J. Legrand, H. Takache, S. Taha, J. Pruvost
JOURNAL OF APPLIED PHYCOLOGY
(2018)
Article
Environmental Sciences
Arwa Aboudalle, Florence Fourcade, Aymen Amin Assadi, Lionel Domergue, Hayet Djelal, Thomas Lendormi, Samir Taha, Abdeltif Amrane
Article
Engineering, Environmental
Arwa Aboudalle, Hayet Djelal, Florence Fourcade, Lionel Domergue, Aymen Amin Assadi, Thomas Lendormi, Samir Taha, Abdeltif Amrane
JOURNAL OF HAZARDOUS MATERIALS
(2018)
Article
Biochemistry & Molecular Biology
Josiane Alhage, Hoda Elbitar, Samir Taha, Jean-Paul Guegan, Zeina Dassouki, Thomas Vives, Thierry Benvegnu
Article
Environmental Sciences
Lisa Zaouk, Anthony Masse, Patrick Bourseau, Samir Taha, Murielle Rabiller-Baudry, Sebastien Jubeau, Benoit Teychene, Jeremy Pruvost, Pascal Jaouen
ENVIRONMENTAL TECHNOLOGY
(2020)
Article
Environmental Sciences
H. Al Jawad, M. Rabiller-Baudry, P. Loulergue, C. Bejjani, A. Lejeune, H. Mawlawi, G. Nasser, S. Taha
ENVIRONMENTAL TECHNOLOGY
(2020)
Article
Biotechnology & Applied Microbiology
N. E. Ramia, S. M. El Kheir, S. Taha, C. Mangavel, A. M. Revol-Junelles, F. Borges
JOURNAL OF APPLIED MICROBIOLOGY
(2019)
Article
Biotechnology & Applied Microbiology
Nouha Sari-Chmayssem, Samir Taha, Hiba Mawlawi, Jean-Paul Guegan, Jelena Jeftic, Thierry Benvegnu
JOURNAL OF APPLIED PHYCOLOGY
(2019)
Article
Chemistry, Multidisciplinary
Katia Sayyed, Abdel-Karim Aljebeai, Mariam Al-Nachar, Hala Chamieh, Samir Taha, Ziad Abdel-Razzak
Summary: This study found an interaction between cigarette smoke and the antipsychotic drug chlorpromazine, with the smoke potentially inducing cross-resistance to the drug. Variants in different genes may be involved in this process.
DRUG AND CHEMICAL TOXICOLOGY
(2022)
Article
Energy & Fuels
Hajar Bahry, Rawa Abdallah, Benoit Chezeau, Agnes Pons, Samir Taha, Christophe Vial
Summary: The present study investigated the possibility of using carob waste for second-generation biohydrogen production through dark fermentation. The results showed that dark fermentation of carob waste led to higher hydrogen yields compared to glucose, and the selection of nitrogen source and particle size reduction further improved the hydrogen productivity.
Article
Biotechnology & Applied Microbiology
Hajar Bahry, Rawa Abdalla, Agnes Pons, Samir Taha, Christophe Vial
JOURNAL OF BIOTECHNOLOGY
(2019)
Article
Multidisciplinary Sciences
Nancy E. Ramia, Cecile Mangavel, Claire Gaiani, Aurelie Muller-Gueudin, Samir Taha, Anne-Marie Revol-Junelles, Frederic Borges
SCIENTIFIC REPORTS
(2020)
Article
Environmental Sciences
Samer Semrany, Samir Taha, Hayet Djelal, Lidia Favier, Abdeltif Amrane
ENVIRONMENTAL ENGINEERING AND MANAGEMENT JOURNAL
(2018)
Article
Pharmacology & Pharmacy
Josiane Alhage, Hoda Elbitar, Samir Taha, Thierry Benvegnu
PHARMACOGNOSY RESEARCH
(2018)
Article
Chemistry, Multidisciplinary
Houssein Al-Attrache, Hala Chamieh, Monzer Hamze, Isabelle Morel, Samir Taha, Ziad Abdel-Razzak
DRUG AND CHEMICAL TOXICOLOGY
(2018)
Article
Chemistry, Multidisciplinary
Xuemei Liu, Chaonan Cui, Shuoshuo Wei, Jinyu Han, Xinli Zhu, Qingfeng Ge, Hua Wang
Summary: This study presents a new strategy for designing efficient photocatalysts that can convert CO2 into hydrocarbons by utilizing synergistic catalytic sites. The findings provide a solution for the selective photocatalytic reduction of CO2 to CH4.
Article
Chemistry, Multidisciplinary
Chengxian Hu, Dan Wang, Lu Wang, Ying Fu, Zhengyin Du
Summary: A novel one-pot, three-component reaction conducted under electrochemical conditions was studied. The reaction involved 2-aminothiophenols, aldehydes, and malononitrile, using TBABF4 as an electrolyte and CuI as a catalyst. The proposed reaction mechanism suggested that CuI served as an electron relay. This method offers simplified operation, high atom economy, and mild reaction conditions.
Article
Chemistry, Multidisciplinary
Zhi Yang, Yu Chen, Linxi Wan, Yuxiao Li, Dan Chen, Jianlin Tao, Pei Tang, Fen-Er Chen
Summary: A highly enantioselective method for the complete hydrogenation of pyrimidinium salts using Ir/(S,S)-f-Binaphane complex as the catalyst was developed. This method provides easy access to fully saturated chiral hexahydropyrimidines, which are prevalent in many bioactive molecules. The reactions exhibit high yields and enantioselectivities under mild reaction conditions without additives. Successful application of this methodology in a continuous flow fashion further extends its practical utility.
Article
Chemistry, Multidisciplinary
Tina Jeoh, Jennifer Danger Nill, Wujun Zhao, Sankar Raju Narayanasamy, Liang Chen, Hoi-Ying N. Holman
Summary: In this study, the enzymatic hydrolysis of cellulose was investigated using real-time infrared spectromicroscopy. The spatial heterogeneity of cellulose was found to impact the hydrolysis kinetics. Hydration affected cellulose ordering, and Cel7A preferentially removed less extensively hydrogen bonded cellulose.
Article
Chemistry, Multidisciplinary
Tiphaine Richard, Walid Abdallah, Xavier Trivelli, Mathieu Sauthier, Clement Dumont
Summary: An effective method of grafting functionalities onto lignin based on glycerol carbonate has been developed using an efficient nickel-catalysed telomerisation reaction. This method allows lignin to have new reactive functions and reduces the glass transition temperatures of modified lignins, thereby expanding the application range of lignin-based resins.
Article
Chemistry, Multidisciplinary
Jing Qi, Xiyan Wang, Gan Wang, Srinivas Reddy Dubbaka, Patrick ONeill, Hwee Ting Ang, Jie Wu
Summary: This study presents a green and environmentally friendly approach for the synthesis of imides using electrocatalytic oxidation with H2O as the oxygen source. The method eliminates the need for toxic or expensive oxidants and achieves high yields under mild reaction conditions. It shows broad substrate compatibility and potential for industrial applications.
Article
Chemistry, Multidisciplinary
Babasaheb Sopan Gore, Lin-Wei Pan, Jun-Hao Lin, Yi-Chi Luo, Jeh-Jeng Wang
Summary: Here, we report a visible light-promoted intramolecular radical cascade reaction for the construction of fluorenol and naphthalene-fused cyclopropyl carbaldehyde derivatives. This method offers mild reaction conditions, a broad substrate scope, excellent step efficiency, and scalability, without the need for external chemical oxidants. The novelty of this protocol was demonstrated by synthesizing chrysene analogs and performing late-stage functionalizations.
Article
Chemistry, Multidisciplinary
Juho Antti Sirvio, Idamaria Romakkaniemi, Juha Ahola, Svitlana Filonenko, Juha P. Heiskanen, Ari Ammala
Summary: This article discusses the method of using supramolecular interaction between an aromatic hydrogen bond donor and lignin to achieve rapid delignification of softwood at low temperatures.
Article
Chemistry, Multidisciplinary
Yunyan Meng, Chunxiang Pan, Na Liu, Hongjiang Li, Zixiu Liu, Yao Deng, Zixiang Wei, Jianbin Xu, Baomin Fan
Summary: A novel visible light-driven synthesis method for 2,3-diamines has been developed, which has mild conditions, avoids the use of metal reagents, and can synthesize diamines and diols in one pot.
Article
Chemistry, Multidisciplinary
Mingqing Huang, Haiyang Huang, Mengyao You, Xinxin Zhang, Longgen Sun, Chao Chen, Zhichao Mei, Ruchun Yang, Qiang Xiao
Summary: A direct air-oxidized strategy for the synthesis of benzo[b]phosphole oxides was developed in this study. Arylphosphine oxides were transformed into phosphinoyl radicals, which were further combined with various alkynes to achieve the desired products. DFT calculations revealed the mechanism of phosphinoyl radical formation.
Article
Chemistry, Multidisciplinary
Anwei Wang, Jiayin Huang, Chunsheng Zhao, Yu Fan, Junfeng Qian, Qun Chen, Mingyang He, Weiyou Zhou
Summary: This study demonstrates an innovative strategy for the aerobic oxidation of C(sp(3))-H bonds using gamma-valerolactone. By optimizing the reaction conditions and utilizing specific catalysts, efficient oxidation of C(sp(3))-H bonds is achieved with good chemoselectivity in certain cases.
Article
Chemistry, Multidisciplinary
Shun Li, Likai Tong, Zhijian Peng, Bo Zhang, Xiuli Fu
Summary: Sulfide compounds show promise as electrocatalysts for water splitting, but their performance is limited by factors such as limited active sites and hindered substance transport. This study successfully prepared a high-entropy sulfide (ZnCoMnFeAlMg)(9)S-8, which reduced grain size and increased specific surface area, enabling the realization of a dual-functional catalyst with multiple catalytic sites. High entropy also modulated the electronic properties of sulfides, reducing the potential energy barrier for hydrolysis. This research introduces a new approach for functionalizing high entropy nanomaterials and improves the performance of water splitting catalysts.