期刊
GREEN CHEMISTRY
卷 18, 期 5, 页码 1206-1211出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc02513c
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资金
- CSIR, New Delhi as part of the XIIth Five Year Plan programme [CSC-0108]
- UGC
- CSIR, New Delhi
A very unusual role of polystyrene stabilized rhodium (Rh@PS) nanoparticles as a supported catalyst is described for reverse-esterification of ethanol with benzyl/alkyl alcohols or aldehydes. Faster and selective oxidation of ethanol to acetaldehyde and H-2 under Rh@PS catalyzed conditions which restricted further oxidation of benzyl/alkyl alcohols and their in situ reaction gave the corresponding acetate esters following the dehydrogenative-coupling approach. A hitherto redox dehydrogenative-coupling of ethanol and aldehydes has also been explored for the same acetate ester synthesis under Rh@PS catalyzed conditions.
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