期刊
JOURNAL OF ENERGY CHEMISTRY
卷 60, 期 -, 页码 241-248出版社
ELSEVIER
DOI: 10.1016/j.jechem.2021.01.022
关键词
Ultrafine SnSSe; Multilayer graphene nanosheet; Potassium-ion batteries; Anode; Full cell
资金
- National Natural Science Foundation of China [22075147]
- Natural Science Foundation of Jiangsu Province of China [BK20180086]
The study successfully synthesized SnSSe/MGS nanocomposite with excellent potassium ion storage performance. The strong synergistic effect between the components leads to high reversible capacity, excellent rate capability, and stable cycling performance, making it promising for battery applications. The full cell assembled with this composite material also demonstrates excellent electrochemical performance.
Layer-structured SnSSe attracts much attention as an anode material for potassium storage due to its large theoretical capacity. Unfortunately, their practical application is severely restrained by the dramatic volumetric variation of SnSSe. Herein, we synthesize ultrafine SnSSe/multilayer graphene nanosheet (SnSSe/MGS) by a vacuum solid-phase reaction and subsequent ball milling. Owing to the strong synergistic effect between the two components, the obtained SnSSe/MGS nanocomposite exhibits a high reversible capacity (423 mAh g(-1) at 100 mA g(-1)), excellent rate property (218 mAh g(-1) at 5 A g(-1)), and stable cycling performance (271 mAh g(-1) after 500 cycles at 100 mA g(-1)) in potassium-ion half batteries. Moreover, the full cell assembled by the SnSSe/MGS anode and the potassiated 3,4,9,10-perylene-tetracar boxylic aciddianhydride cathode shows excellent electrochemical performance between 0.2 and 3.3 V (209 mAh g(-1) at 50 mA g(-1) after 100 cycles). The presented two-step synthesis strategy of SnSSe/MGS may also provide ideas to craft other alloy-type anode materials. (C) 2021 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
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