期刊
MATERIALS
卷 14, 期 11, 页码 -出版社
MDPI
DOI: 10.3390/ma14112722
关键词
copper corrosion; localized corrosion; BTA inhibitor; inhibition; carbonaceous residue
类别
资金
- program for fostering next-generation researchers in engineering of National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2017H1D8A2031628]
- NRF - Korean Government [NRF-2020R1I1A1A01074866]
This study investigated the inhibiting effect of benzotriazole (BTA) on pitting corrosion of copper pipes, showing that BTA forms Cu-BTA complexes to prevent corrosion mechanisms from taking place.
Carbonaceous residues on copper pipes during the manufacturing process are known to be one of the main causes of pitting corrosion on copper pipes. This study examined the corrosion-inhibiting effect of benzotriazole (BTA) on C12200 copper pipes with carbonaceous film in synthetic tap water. In the absence of BTA, localized corrosion mechanisms due to galvanic corrosion, crevice corrosion, and oxygen-concentration cell were proposed in the boundary part of the carbonaceous film on the copper through X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive spectrometer (EDS) analyses. Electrochemical tests showed that BTA inhibits corrosion by forming Cu-BTA complexes on all over the copper surface where carbonaceous film is present. BTA mitigates galvanic corrosion and crevice corrosion at the boundary of the carbonaceous film and suppresses the formation of oxygen-concentration cells through the formation of a Cu-BTA complex.
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