期刊
ACS CATALYSIS
卷 11, 期 16, 页码 10377-10382出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.1c02956
关键词
alcohol; borrowing hydrogen; molybdenum; alkylation; nitro compound
资金
- NSFC [21973113, 21977019, 21773312]
- Fundamental Research Funds for the Central Universities
This study demonstrates the effective N-alkylation of anilines or challenging nitroarenes with alcohols through homogeneous Mo-catalysis, utilizing a strong hydride-donating ability of the easily accessible bis-NHC-Mo(0) complex. The enhanced hydride-donating strategy is valuable for designing highly active systems for borrowing hydrogen transformations.
An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with alcohols is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo(0) complex features a strong hydride-donating ability, achieving effective N-alkylation of anilines or challenging nitroarenes with alcohols. The enhanced hydride-donating strategy should be useful in designing highly active systems for borrowing hydrogen transformations.
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