4.2 Article

Experimental Study of the High-Temperature Region of the Ca3(PO4)2-CaKPO4-CaNaPO4 System

期刊

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 95, 期 7, 页码 1302-1306

出版社

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024421070190

关键词

mixed phosphates of calcium; sodium and potassium; phase transformations; phase diagrams of ternary systems

资金

  1. Russian Foundation for Basic Research [19-38-90199, 19-3860063]

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An experimental study was conducted on the high-temperature region of the phase diagram for the Ca-3(PO4)(2)-CaNaPO4-CaKPO4 system. The study determined the compositions of phase fields at 1200 degrees C and identified the existence of two single-phase regions at that temperature. Additionally, the upper temperatures of the phase triangle section at 1200 degrees C were determined.
An experimental study is performed of the high-temperature region of the phase diagram of the Ca-3(PO4)(2)-CaNaPO4-CaKPO4 system. The compositions of the phase fields at 1200 degrees C are determined. It is shown that the region of tricalcium composition at the given temperature consists of two single-phase regions: high-temperature alpha-Ca-3(PO4)(2) and low-temperature beta-Ca-3(PO4)(2). The upper temperatures of the existence of fields of the phase triangle section at 1200 degrees C are determined.

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