Using biopolymers to strengthen the historical printed paper: mechanical and optical characters

Purpose This study aims to restore the lost mechanical properties of the prints with carrageenan, methyl hydroxyethyl cellulose (Tylose) and hydroxypropyl methylcellulose (Methocel). Design/methodology/approach The effect of these materials on the properties of the printed paper (modern and historical samples) has been evaluated under the influence of accelerated aging using pH measurement, the mechanical properties (tensile and elongation), FTIR and color changes. Findings The three consolidates reduced the acidity of treated samples significantly, but after ageing, it was observed that the pH of aged treated samples decreased slightly as compared to the untreated samples. The results of the mechanical properties showed the superiority of hydroxypropyl methylcellulose (Methocel) in improving the tensile and elongation forces of the samples compared to carrageenan and methyl hydroxyethyl cellulose even during the accelerated aging. Consolidation materials succeeded in reducing Delta E of the paper samples under accelerated aging, especially carrageenan. The IR spectra confirmed that no dramatic difference was observed in topically function vibrations of samples after treatment beside that the O-H stretching band intensity increased observably after treatment with the three consolidates, after ageing the treatment, and it protected the treated paper from oxidation processes as the infrared spectrum analysis showed a decrease in intensities of carbonyl and carboxyl groups as compared to aged untreated samples. Originality/value The research provides new biopolymers in strengthening the historical printed paper, where printed papers lack studies related to their conservation. This makes the current study a promising step for treating historical printed paper.

Automated summary

The three consolidates significantly reduced the acidity of treated samples, with the superiority of hydroxypropyl methylcellulose (Methocel) in improving tensile and elongation forces. Accelerated aging showed a decrease in pH and protected the paper from oxidation processes. This study provides new biopolymers for strengthening historical printed paper.