1,3-Aza-Brook Rearrangement of Aniline Derivatives: In Situ Generation of 3-Aminoaryne via 1,3-C-(sp2)-to-N Silyl Migration

Aryne 1,2,3,5-Tetrasubstitution Enabled by 3-Silylaryne and Allyl Sulfoxide via an Aromatic 1,3-Silyl Migration

(2021) Jiarong Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of Anion Relay Chemistry: Construction of Architecturally Complex Natural Products

(2020) Yifan Deng et al.   ACCOUNTS OF CHEMICAL RESEARCH

One-Pot, Three-Aryne Cascade Strategy for Naphthalene Formation from 1,3-Diynes and 1,2-Benzdiyne Equivalents

(2019) Xiao Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

3-Thioaryne Intermediates for the Synthesis of Diverse Thioarenes

(2019) Yu Nakamura et al.   ORGANIC LETTERS

Arynes and Cyclic Alkynes as Synthetic Building Blocks for Stereodefined Quaternary Centers

(2018) Elias Picazo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of 3,4-Polyfused Oxindoles with Quaternary All-Carbon Stereocenters: A Rh-Catalyzed C–C Activation Approach

(2018) Bo Qiu et al.   ORGANIC LETTERS

Ergot alkaloids: synthetic approaches to lysergic acid and clavine alkaloids

(2017) Haichao Liu et al.   NATURAL PRODUCT REPORTS

3-Hydroxy-2-(trialkylsilyl)phenyl Triflate: A Benzyne Precursor Triggered via 1,3-C-sp2-to-O Silyl Migration

(2017) Yong-Ju Kwon et al.   ORGANIC LETTERS

Three New Ergot Alkaloids from the Fruiting Bodies of Xylaria nigripes (Kl .) Sacc .

(2016) Dongbao Hu et al.   CHEMISTRY & BIODIVERSITY

Aryne Relay Chemistry en Route to Aminoarenes: Synthesis of 3-Aminoaryne Precursors via Regioselective Silylamination of 3-(Triflyloxy)arynes

(2016) Suguru Yoshida et al.   ORGANIC LETTERS

Silylaryl Halides Can Replace Triflates as Aryne Precursors

(2016) Milad Mesgar et al.   ORGANIC LETTERS

Synthesis of Aryl anti-Vicinal Diamines via Aza-Brook Rearrangement-Initiated Nucleophilic Addition of α-Silylamines to Imines

(2015) Chao-Yang Lin et al.   JOURNAL OF ORGANIC CHEMISTRY

[1,4]-Aza-Brook Rearrangement for Efficient Formation of Benzynes and Their Cycloaddition

(2015) Chong-Dao Lu et al.   SYNLETT

The Role of Aryne Distortions, Steric Effects, and Charges in Regioselectivities of Aryne Reactions

(2014) Jose M. Medina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Steric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-Silylarynes

(2012) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly efficient chemoselective N-TBS protection of anilines under exceptional mild conditions in the eco-friendly solvent 2-methyltetrahydrofuran

(2011) Vittorio Pace et al.   GREEN CHEMISTRY

Diversity-oriented synthesis leads to an effective class of bifunctional linchpins uniting anion relay chemistry (ARC) with benzyne reactivity

(2011) A. B. Smith et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Regioselective Reactions of Highly Substituted Arynes

(2010) Pamela M. Tadross et al.   ORGANIC LETTERS