Inductively coupled nonthermal plasma synthesis of aluminum nanoparticles

Metallic nanoparticles of aluminum (Al), a nontoxic and earth-abundant element, are relevant to plasmonic and energetic applications. However, monodisperse Al nanoparticles are difficult to synthesize using all gas-phase approaches, especially in the 10 to 20 nm size range; yet, many applications require particles of this size due to their enhanced properties. Here, an inductive nonthermal plasma reactor fed with aluminum trichloride (AlCl3) and Ar is used to synthesize single-crystal aluminum nanoparticles. The particles can be produced with or without hydrogen. Several reactor conditions such as AlCl3 vapor concentration, flow rates, and power are found to strongly influence particle properties such as the oxide shell thickness, particle mono-dispersity, and particle size. Significant quantities of Ar relative to AlCl3, short residence times of 10 s of ms, and pressures in excess of 4.7 Torr are required to form Al particles with geometric mean sizes of 10-20 nm and geometric standard deviations as low as 1.3. While the Al nanoparticles are covered with 2-4 nm thick oxide shells, the best synthesis conditions yield particle sizes determined by electron microscopy that are comparable to crystallite sizes determined from x-ray diffraction.

Automated summary

By using an inductive nonthermal plasma reactor fed with aluminum trichloride and Ar, single-crystal aluminum nanoparticles were synthesized with different reactor conditions affecting properties like oxide shell thickness, particle mono-dispersity, and particle size. Large quantities of Ar relative to AlCl3, short residence times, and high pressures are needed to form 10-20 nm Al particles with low geometric standard deviations.