期刊
FUEL
卷 173, 期 -, 页码 1-7出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2015.12.077
关键词
Mercury; Regeneration; Copper chloride; Magnetospheres
资金
- National Key Basic Research Program (973) of China [2014CB238904]
- National Natural Science Foundation of China (NSFC) [51176060, 51376074, 51206192]
The regeneration performance of spent catalyst after mercury removal as well as the involved reaction mechanism was investigated. The effects of restoration with or without O-2 and/or HCl, O-2 and HCl concentration, regeneration temperature, and heating rate on regeneration performance were studied, respectively. The results suggested that two steps were essential in the regeneration process: (1) releasing the sulfur and mercury species adsorbed on the catalyst; (2) restoring the surface chemistry of catalyst by O-2 and HCl. Optimal regeneration performance of spent catalyst was attained after thermal desorption at 400 degrees C and following by the restoration of O-2 and HCl. The changes in surface chemistry of catalyst revealed that the sulfur and mercury species could be fully released by heating at 400 degrees C, and the deactivated adsorption sites was exposed. With the assistance of O-2 and HCl, the surface chemistry of Cu and Cl was restored close to original CuCl2. Four cycles of mercury adsorption-catalyst regeneration showed that the mercury removal capacity did not vary appreciably with respect to fresh catalyst after multiple regeneration. (C) 2016 Elsevier Ltd. All rights reserved.
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