4.7 Article

Additive manufacturing of SiOC scaffolds with tunable structure-performance relationship

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 41, 期 15, 页码 7552-7559

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ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.08.043

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Additive manufacturing; SiOC; Mechanical properties; Permeability; Preceramic polymers

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This study investigated the properties variation in porous ceramics by designing different patterns in SiOC log-pile structures. Results confirmed that mechanical performance could be tuned by adjusting the architectural features of the structures, such as filament spacing and layer deflection angle, to optimize strength and permeability without reducing porosity.
Aiming at optimizing the performance of porous ceramics through structural optimization, this work explored the properties variation achieved by designing different patterns in SiOC log-pile structures fabricated by direct ink writing. Specifically, we investigated the effect of filament diameter, spacing between filaments and angle of deflection between adjacent layers on the compression strength and gas permeability of these structures. Results confirm that mechanical performance could be tuned by designing the structures' architectural features, such as the spacing between filaments and the angle of deflection between layers, leading to changes in the contact area of filaments belonging to adjacent layers. Permeability decreased with varying angle of deflection from 90 degrees to 15 degrees, due to the higher tortuosity of the flow paths. This enables to optimize the strength and permeability of the structure without reducing the porosity of the component.

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