4.8 Article

Thermal characteristics of ultrahigh power density lithium-ion battery

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JOURNAL OF POWER SOURCES
卷 506, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.jpowsour.2021.230205

关键词

Ultrahigh power density lithium-ion battery; LTO anode-based battery; HPPC; EIS; Thermal characteristics

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The study investigated the thermal characteristics of a commercial lithium-ion battery under high discharge rates, revealing that heat generation power and temperature rise ratio increased with discharge rate. Irreversible heat accounted for 83% under 40C discharge. Different methods were used to predict heat generation, with the HPPC method found to be more accurate than the EIS method.
Ultrahigh power density lithium-ion batteries (LIBs) are widely applied in transportation and energy storage systems. However, the thermal characteristics of power lithium-ion batteries under high discharge rates remain unclear. In this work, a commercial lithium-ion battery with lithium titanate oxide (LTO) as the anode material is investigated under discharge rates up to 40C. The heat generation power and temperature rise ratio increase with the discharge rate. A maximum heat generation rate of 358 W is obtained under 40C discharge. Due to the limited discharge capacity with high discharge rates, the highest temperature rise appears under 25C discharge, which is 38.9 degrees C. The percentage of irreversible heat increases with the discharge rate, but it only accounts for 83% under 40C discharge. Furthermore, different internal resistance estimation methods are used to predict the heat generation of lithium-ion batteries. It is found that hybrid pulse power characteristic (HPPC) method is more accurate than electrochemical impedance spectroscopy (EIS) method, and heat generation in higher discharge rate can be estimated by HPPC with a shorter time scale.

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