Effect of aging treatment on microstructure and corrosion behavior of a Fe-18Cr-15Mn-0.66N stainless steel

The effect of aging treatment on the microstructure and corrosion behavior of a Fe-18Cr-15Mn-0.66N high-nitrogen stainless steel (HNSS) in 3.5 wt.% NaCl solution was investigated using a series of electrochemical tests, scanning electronic microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results showed that the aging treatment led to the precipitation of Cr2N particles along the grain boundaries and their morphologies changed from dispersive particles to continuous network as the aging time increased up to 60 min. Aging time had minor effects on the corrosion potential and corrosion current density, but resulted in the sharp decrease in the pitting corrosion potential. The passive film behaved as a n-type semiconductor, and the donor density of the passive film increased with the aging time. Meanwhile, the fraction of stable oxide (Cr2O3) in the passive film decreased with the aging time. It demonstrates that the aging treatment deteriorated the protectiveness of the passive film, hence weakened the corrosion resistance of HNSS. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

The effect of aging treatment on the microstructure and corrosion behavior of a high-nitrogen stainless steel (HNSS) was investigated. The aging treatment led to the precipitation of Cr2N particles along the grain boundaries, and the morphology changed from dispersive particles to a continuous network. Aging time had minor effects on corrosion potential and corrosion current density, but resulted in a sharp decrease in the pitting corrosion potential. The passive film behaved as a n-type semiconductor, and the donor density of the passive film increased with aging time. However, the fraction of stable oxide (Cr2O3) in the passive film decreased with aging time. The aging treatment weakened the corrosion resistance of HNSS by deteriorating the protectiveness of the passive film.