4.4 Article

Synthesis and properties of phosphorus-containing cardanol-based acrylates for flame-retardant UV/EB-cured coatings

期刊

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH
卷 18, 期 5, 页码 1353-1364

出版社

SPRINGER
DOI: 10.1007/s11998-021-00500-1

关键词

Cardanol; UV; EB cured; Flame retardant; Coatings

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In this study, two phosphorus-containing cardanol-based acrylates were designed and successfully synthesized, leading to the production of photosensitive resins used in flame-retardant UV/EB curing coatings. The coatings exhibited excellent flame-retardant properties, with cured films achieving a V-0 flammability rating in UL-94 testing.
In this article, two kinds of phosphorus-containing cardanol-based acrylates were designed and synthesized. Firstly, a pre-polymer (PT-HCE) with three arms was synthesized using hydroxyethyl cardanol ether (HCE) and phosphorus oxychloride (POCl3) as raw materials. Then, the PT-HCE was acrylated to synthesize phosphate tris-hydroxyethyl cardanol epoxy acrylate resin (AEPT-HCE) and phosphate tris-hydroxyethyl cardanol photosensitive resin (APT-HCE). The structures of PT-HCE, AEPT-HCE and APT-HCE were characterized and the results showed that the photosensitive resins were successfully synthesized. In addition, AEPT-HCE and APT-HCE were used to prepare the flame-retardant UV/EB curing coatings. The properties of the coatings were tested, and the results revealed that different structures have a certain effect on T-g and tensile properties of the coatings. The cured films demonstrated excellent flame-retardant properties, showing flammability rating of V-0 in UL-94 test.

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