4.7 Article

Conversion of poultry-fat waste to a sustainable feedstock for biodiesel production via microbubble injection of reagent vapor

期刊

JOURNAL OF CLEANER PRODUCTION
卷 311, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.127525

关键词

Biodiesel; Acid catalysis; Esterification; Chicken fat oil; Mass transfer

资金

  1. Higher Education Commission Pakistan (HEC)
  2. National Research Program for Universities (NRPU) [20-7924/17, 20-3982/14]
  3. EPSRC [EP/S031421/1]

向作者/读者索取更多资源

The economics of biodiesel production are influenced by sustainability and feedstock prices, with high biodiesel prices being a major obstacle to commercialization. Chicken fats, as waste products, are being increasingly used as feedstock for biodiesel production due to their low cost and widespread availability. Innovative methods such as vapor-liquid contacting and the use of cost-effective catalysts have been proposed to increase efficiency and reduce costs in biodiesel production, particularly when using chicken fat as a base material.
Sustainability and the price of feedstock are the key parameters governing the economics of biodiesel production. Higher price of biodiesel is the major obstacle in its commercialization. Chicken fats, otherwise a waste and environmental nuisance, are an attractive feedstock for cleaner biodiesel production because of low cost and worldwide availability. Moreover, Establishment of thermodynamic equilibrium in esterification reaction limits the overall conversion and reduces the rate of reaction. A new vapor (methanol bubble)-liquid contacting method has been proposed to analyze the hypothesis that bubble reactor can push the biodiesel production near completion. Simultaneous removal of water from the system would pull the equilibrium in the forward direction. Kinetic investigation shows that the reaction occurs, indeed, at the vapor-liquid interface and consequently yielding a higher conversion of 89.90% in 30 min-significantly higher than any previously reported studies for chicken fat based biodiesel. Furthermore, the use of, an economical and already used at commercial grade catalyst, p-Toluene sulfonic acid eliminates the need to produce a catalyst at commercial scale before it could be used in an industrial process. These factors make microbubble mediated biodiesel production from chicken fat oil using p-Toluene sulfonic acid a lucrative option.

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