4.7 Article

Cellulose nanocrystals from agricultural resources: Extraction and functionalisation

期刊

EUROPEAN POLYMER JOURNAL
卷 160, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2021.110789

关键词

Cellulose nanocrystals (CNC); Pretreatment methods; Extraction techniques; Functionalization

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The article highlights the extraction process, properties, and applications of cellulose nanocrystal composites from agricultural resources, as well as the importance of functionalization. This bio-based material is characterized by high strength, large surface area, and versatility for various fields, contributing positively to agricultural and industrial development.
During the early nineteens, enhanced concern towards biodegradable materials and green chemistry, along with the significant advancements in nanotechnology, coerce scientists and scholars to ferret out an alternative biomaterial. Prolonged rummage to the alternate biomaterial leads to the discovery of nanoparticles from cellulose as cellulose nanocrystal composites. Various cellulosic sources yield nano cellulosic derivatives after various pretreatment and extraction procedures, including acid hydrolysis, micro grinding, cryocrushing, electron spinning, and centrifugal spinning. Agricultural resources like cotton, wheat, garlic, ramie, switchgrass, and curaua for cellulose nanocrystal composites extraction of varying properties; hence are applicable for distinct functions. Extraction from agricultural resources adds more profit and advancement in the agricultural sector. Pure cellulose nanocrystal composite possesses a mechanical strength of 7000 MPa, a young modulus of 100-140 GPa, and 250-500 m2/g surface area. The vulnerability of cellulose nanocrystal composites towards moisture due to alcoholic group nullifies by the modification and grafting processes which yield functionalized cellulose nanocrystal composites. Functionalized cellulose nanocrystal composites find applications in various fields, including biomedicine, catalysis, electronics, and laboratories. The review summarises the extraction procedure of cellulose nanocrystal composites from agricultural resources and functionalization methodologies, facilitating cellulose nanocrystal composite's prospective implementation.

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