期刊
CORROSION SCIENCE
卷 190, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109695
关键词
Selective laser melting; Cellular structure; Hydrogen embrittlement; High-entropy alloy; Local plasticity
资金
- National Natural Science Foundation of China [51971248]
- Hunan Special Funding for the Construction of Innovative Province [2019RS1001]
- Postdoctoral Foundation of Central South University [140050030]
This study demonstrates that modifying cellular structures through controlled annealing can effectively improve the hydrogen embrittlement resistance of selective laser melting processed alloys. Annealing preserved cellular structures while reducing dislocation densities, slightly reducing strength but significantly increasing ductility and HE resistance. The delayed crack initiation and propagation were attributed to hydrogen-enhanced local plasticity with formation of nano-twins and dislocation cells in the modified structures.
We demonstrate that modifying the cellular structures by well-controlled annealing can effectively improve the hydrogen embrittlement (HE) resistance of selective laser melting (SLM) processed alloys. Investigations on both as-SLM processed and annealed prototype CoCrFeMnNi high-entropy alloy samples suggest that annealing preserved the cellular structures while effectively reduced the dislocation densities. This slightly reduced the strength but significantly increased the ductility and HE resistance upon slow strain rate tensile tests (1 x 10(-5) s(-1)) under in situ electrochemical hydrogen charging. The crack initiation and propagation were delayed by hydrogen-enhanced local plasticity with the formation of nano-twins and dislocation cells in the modified structures.
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