4.8 Review

Optimizing Catalyst and Reaction Conditions in Gold(I) Catalysis-Ligand Development

期刊

CHEMICAL REVIEWS
卷 121, 期 14, 页码 8559-8612

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AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.0c01320

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  1. UGent BOF
  2. iBOF grant C3
  3. SBO Co2perate

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This review examines the use of phosphine and N-heterocyclic carbene complexes of gold(I) as (pre)catalysts in organic synthesis, categorizing them based on ligand structure and focusing on studies that offer quantitative comparisons with existing systems.
This review considers phosphine and N-heterocyclic carbene complexes of gold(I) that are used as (pre)catalysts for a range of reactions in organic synthesis. These are divided according to the structure of the ligand, with the narrative focusing on studies that offer a quantitative comparison between the ligands and readily available or widely used existing systems.

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