期刊
CHEMICAL RECORD
卷 21, 期 12, 页码 3758-3778出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202100143
关键词
Transition metal; C-H activation; natural product mutation; substrate scope; mechanistic insights
资金
- science and engineering research board (SERB) [PDF/2017/2653]
The article outlines the contribution towards a wide variety of transformations achieved by directed C-H functionalization through the fine tuning of catalytic systems. This method has become an efficient and sustainable alternative for the regioselective construction of C-C and C-heteroatom bonds.
Transition-metal-catalyzed C-H functionalization is one of the fascinating scientific fronts in organic synthesis for the formation of conjugated arenes and has emerged as a benchmark to revolutionize the synthetic enterprise since past decades. In this realm, chelation-guided functionalization of C-H bonds using an exogenous directing group has received considerable attention recently for the expedient regioselective construction of C-C and C-heteroatom bonds as an efficient and sustainable alternative. This article outlines our contribution towards a wide variety of transformations that have been achieved by the directed C-H functionalization through the fine tuning of catalytic systems.
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