期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 290, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2021.120057
关键词
Photocatalysis; H-2 generation; Cocatalyst; Te-rich NiTe; Amorphous
资金
- National Natural Science Foundation of China [22075220, 21771142, 52073263]
- Fundamental Research Funds for the Central Universities [WUT 2019IB002]
The study introduces novel and robust H-2-generation cocatalyst, tellurium-rich amorphous NiTe1+x nanodots, loaded onto TiO2 to significantly enhance its photocatalytic H-2-evolution performance. The small nanodots achieved high H-2 evolution rate by efficiently enhancing electron transfer and accelerating the H-2 generation process.
The exploitation and design of novel low-cost cocatalysts with rich H-2-evolution active centers is quite crucial for markedly promoting the photocatalytic activity. Herein, tellurium-rich amorphous NiTe1+x nanodots as a novel and robust H-2-generation cocatalyst were ingeniously loaded onto the TiO2 to greatly improve its photocatalytic H-2-evoluton performance via a synergistic strategy of tellurium-rich structure and amorphization, with an aim of maximally exposing more H-2-evolution site of tellurium atoms. In this case, tellurium-rich amorphous NiTe1+x nanodots were very small (0.3-1 nm) and uniformly modified onto the TiO2 by the facile photoinduced synthesis route, and the resultant a-NiTe1+x/TiO2(0.5 wt%) achieves the highest H-2-evolution rate (3302 mu mol h(-1) g(-1), AQE = 15.8 %). The superior activity can be attributed to the successful deposition of tellurium-rich amorphous NiTe1+x nanodots, which can not only efficiently enhance the photoinduced electron migrate from TiO2, but also supply abundant active tellurium sites to accelerate the interfacial H-2-evolution process. Significantly, the tellurium-rich a-NiTe1+x can also be utilized as the universal cocatalyst. This research may provide new avenues to develop efficient and low-cost cocatalysts with abundant enriched active-sites for high performance photocatalysts.
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