Article
Chemistry, Physical
Junwei Du, Guanghui Xiong, Hequn Wu, Lulu Bai, Weifeng Yao
Summary: Developing efficient bifunctional transition metal-based electrocatalysts is crucial for reducing the practical costs of water splitting. In this study, a flower-shaped disorderly nickel-iron nitride nanosheets bifunctional electrocatalyst (NiFeNx/NF) was synthesized and demonstrated exceptional performance and stability in the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising candidate for cost-effective and environmentally friendly water splitting catalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Ruizhe Gu, Tao Zhou, Zihao Wang, Zheng Chen, Junwen Tao, Zhewei Fan, Lingyun Guo, Yongsheng Liu
Summary: Designing high-efficiency catalysts for overall water splitting is crucial for reducing the cost of hydrogen fuel as a clean and renewable energy source. This study successfully synthesized Mo-, P-codoped NiFeSe catalysts on nickel foam, which exhibited efficient HER/OER performances with low overpotential and high stability. The catalysts required only 1.53 V to deliver a current density of 10 mA cm-2 in overall water splitting and maintained outstanding durability for 100 h.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Wenhui Luo, Yang Wang, Liuxiong Luo, Shen Gong, Mengni Wei, Yixuan Li, Xueping Gan, Yuyuan Zhao, Zhenghong Zhu, Zhou Li
Summary: This work presents the rational design and fabrication of a highly efficient, cost-effective, and environmentally friendly non-noble-metal bifunctional catalyst for electrocatalytic overall water splitting. The catalyst exhibits excellent catalytic performance, achieving high current density at low cell voltage, and can be reactivated after simple treatment.
Article
Chemistry, Multidisciplinary
Ziqiang Niu, Zhankuan Lu, Zelong Qiao, Shitao Wang, Xiaohua Cao, Xiudong Chen, Jimmy Yun, Lirong Zheng, Dapeng Cao
Summary: Designing robust bifunctional catalysts for OER and HER in all-pH conditions for OWS is a promising strategy. A composite Ru-VO2 with high OWS performance is synthesized, and the synergistic effect between Ru NP and Ru-doped VO2 is revealed. This work provides new insights into the design of pH-universal catalysts for OWS.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Wenhua Zhao, Niandu Wu, Fan Yu, Boye Zhou, Xueyuan Chu, Zhiqiang Wei, Shaoguang Yang
Summary: The utilization of low-cost, porous, and ultrathin CoPS nanosheets as bifunctional electrocatalysts in water splitting allows for lower overpotentials and higher turnover frequencies, demonstrating excellent performance and stability. This promising non-precious-metal-based electrocatalyst shows potential for various applications in water electrolysis.
ACS APPLIED ENERGY MATERIALS
(2021)
Review
Chemistry, Physical
Sang Eon Jun, Jae Kwan Lee, Sangwoo Ryu, Ho Won Jang
Summary: Single atom catalysts (SACs) exhibit remarkable catalytic activity and excellent atomic utilization efficiency in photoelectrocatalytic water splitting. This review summarizes the representative characterization techniques and recent development in SACs for efficient photoelectrochemical water splitting.
Article
Chemistry, Physical
Xiaodong Cai, Qun Song, Danhua Jiao, Huatong Yu, Xia Tan, Rongrong Wang, Shengyun Luo
Summary: In this study, a CoFeP/rGO heterostructure was designed to achieve high-performance bifunctional non-precious electrocatalysts for renewable energy applications. The synergistic effect of superior conductivity, increased catalytic active sites, and regulated electron distribution contributed to the excellent hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activities. The CoFeP/rGO-2 composite exhibited low overpotentials and achieved high current densities, demonstrating its feasibility as a bifunctional electrocatalyst.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Mohammad Zafari, Muhammad Umer, Arun S. Nissimagoudar, Rohit Anand, Mirah Ha, Sohaib Umer, Geunsik Lee, Kwang S. Kim
Summary: In this study, various transition metals implanted on boron-arsenide, boron-phosphide, and boron-antimony were investigated as single-atom catalysts for nitrogen reduction reaction (NRR) using density functional theory. W-BAs showed high catalytic activity and selectivity, while W-BSb and Mo-BSb exhibited high performances. Through the analysis of charge transfer and protonation steps, a crucial obstacle in NRR was successfully overcome. Machine learning descriptors were also introduced to reduce computational cost.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Engineering, Chemical
Chuntian Tan, Feihong Wang, Kai Lv, Yangyang Shi, Binbin Dong, Luyuan Hao, Liangjun Yin, Xin Xu, Yuxi Xian, Simeon Agathopoulos
Summary: This study presents a novel approach to fabricate a bifunctional electrode with efficient catalytic performance in both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The electrode demonstrates excellent stability and has great potential for application in industrial hydrogen production.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Ruisong Li, Wenjun Fan, Peng Rao, Junming Luo, Jing Li, Peilin Deng, Daoxiong Wu, Wei Huang, Chunman Jia, Zhongxin Liu, Zhengpei Miao, Xinlong Tian
Summary: This study successfully synthesized multimetallic single-atom catalysts (MM-SACs) using metal-C(3)N(4) and nitrogen-doped carbon as cornerstones, and verified their atomic dispersion and strong electronic reciprocity between multimetallic sites. It was found that FeCoZn-SACs and FeCoCuZn-SACs exhibited superior oxygen evolution reaction and oxygen reduction reaction activity, as well as outstanding bifunctional durability. The Co sites in FeCoCuZn-SACs were crucial contributors to the efficient catalysis of both ORR and OER. Furthermore, Zn-air batteries with FeCoCuZn-SACs as cathodic catalysts showed high power density, specific capacity, and stability for charging-discharging processes.
Article
Chemistry, Inorganic & Nuclear
Mingshuai Chen, Guangping Wu, Xiaoqiang Du, Xiaoshuang Zhang
Summary: This paper studies a novel seawater splitting catalyst with excellent catalytic performance and stability. By designing the material structure and utilizing the synergistic effects of multiple metals, the efficiency of seawater electrolysis can be optimized.
DALTON TRANSACTIONS
(2023)
Review
Chemistry, Inorganic & Nuclear
Mariam Batool, Arslan Hameed, Muhammad Arif Nadeem
Summary: Transition metal nitrides (TMNs) have emerged as efficient electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and overall water splitting (OWS) due to their noble metal-like structure, high electric conductivity, corrosion resistance, broad pH stability and structural flexibility. Iron and nickel based TMNs, in particular, have been considered as ideal electrocatalysts due to their abundance, low cost and high catalytic activity. However, their single phase structures have shown unsatisfactory performance, leading to the development of advanced heterostructures by doping other metals, metallic compounds, and conductive substrates to enhance catalytic performance. In this review, recent advancements and challenges in Fe and Ni-based TMNs for electrochemical water splitting are highlighted.
COORDINATION CHEMISTRY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Xin Ding, Run Jiang, Jialin Wu, Minghui Xing, Zelong Qiao, Xiaofei Zeng, Shitao Wang, Dapeng Cao
Summary: This study successfully synthesized the heterostructure of nickel nitride and ceria on nickel foam, showing excellent hydrogen evolution and oxygen evolution performance. Ceria plays different roles in the hydrogen evolution and oxygen evolution processes. The study reveals the different catalytic mechanisms of ceria in boosting the hydrogen evolution and oxygen evolution activities of nickel nitride, providing useful guidance for designing high-performance bifunctional catalysts.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Energy & Fuels
Lin Hu, Quan-quan Shen, Xiao Yang, Xian-kun Wu, Rui Luo, Xiao-ju Wen, Zheng-hao Fei
Summary: In this study, ruthenium-based phosphorus-doped carbon (RuOx/P-C) hybrids were synthesized using lignin and phytic acid as carbon and phosphorus sources, forming lignin-phytic acid networks via complexation and electrostatic interaction. The resulting RuOx/P-C catalysts exhibited enhanced catalytic performance for solar-assisted water splitting. For the hydrogen evolution reaction, RuOx/P-C achieved low onset potentials and small Tafel slopes in acidic and alkaline electrolytes. In the photoelectrochemical cell, RuOx/P-C/W:BiVO showed a significantly higher photocurrent compared to pristine W:BiVO, attributed to the synergistic coupling effects among active species.
Article
Chemistry, Inorganic & Nuclear
Wenhao Liao, Xianfeng Tong, Yali Zhai, Haojiang Dai, Yingyan Fu, Min Qian, Geng Wu, Tianyun Chen, Qinghua Yang
Summary: This study successfully synthesized carbon nanotubes with a hollow polyhedral structure. The unique structure provides stability and facilitates mass and charge transfer. The resulting CoP/CNTHPs exhibited excellent bifunctional catalytic activity in hydrogen and oxygen evolution reactions and electrocatalytic water splitting, along with remarkable stability.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Physical
Guohong Fan, Qi Wang, Hong Xu, Xiaohua Wang, Xianxian Tu, Xiangfeng Chu
Summary: The research found that Cr/BNNT single atom catalyst can simultaneously remove N2O and CO gases with high efficiency and application prospects. In the reaction, the Cr atom acts as an electron bridge through its 3d orbital, playing an important role in activating N2O and CO molecules. Meanwhile, BNNT support with high redox stability can act as an electron reservoir, aiding the overall reaction.
APPLIED SURFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Xianxian Tu, Hong Xu, Xiaohua Wang, Chenyin Li, Guohong Fan, Xiangfeng Chu
Summary: The research explores the potential application of borophene as a gas sensor device, with a focus on the impact of Li doping on the sensing performance of borophene towards SO2 and five main atmospheric gases. The introduction of Li adatom significantly enhances the selectivity and sensitivity of borophene to SO2, improving gas adsorption performance and desorption characteristics for SO2 molecule at high temperatures. This study sheds light on the influence of Li doping on borophene and highlights the potential application of Li-borophene as a SO2 gas sensor or scavenger.
Article
Chemistry, Physical
Xianxian Tu, Hong Xu, Chenyin Li, Xin Liu, Guohong Fan, Wenqi Sun
Summary: The drug delivery properties of boron nitride nanomaterials as anticancer drug carriers were investigated using density functional theory. The study included analysis of binding energy, solubility energy, thermodynamic properties, and UV-Vis spectra of drug adsorption on BN nanomaterials. The research also simulated the drug release process and how the drug delivery system is affected by internal biological environments.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2021)
Article
Engineering, Electrical & Electronic
Hong Xu, Xianxian Tu, Xiaohua Wang, Xin Liu, Guohong Fan
Summary: The study demonstrates that metal-doped C24N24 enhances the adsorption capability of gases on fullerene surfaces, with K- and Na-doped C24N24 showing the strongest adsorption capacity for NO2 gas, resulting in significant changes in band gap and charge transfer. As a result, they exhibit high selectivity in NO2 detection.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Nanoscience & Nanotechnology
Xin Liu, Chenyin Li, Fang Xu, Guohong Fan, Hong Xu
Summary: The study investigates the catalytic activity, mechanism, and selectivity of TM embedded nitrogen-doped phosphorene as high-performance nitrogen reduction reaction electrocatalysts through density functional theory calculations. Results show that Mo- and Nb-doped catalysts exhibit excellent catalytic performance, with Mo-N3-BP catalyst demonstrating extremely low overpotential and superior selectivity. The relationship between the d-band center and catalytic activity is explored, with Mo and Nb located near the peak of the volcano-type curve, providing insights for the design of high performance NRR single-atom catalysts in the future.
Article
Chemistry, Physical
Chenyin Li, Xin Liu, Dandan Wu, Hong Xu, Guohong Fan
Summary: This study investigates V, Cr, and Mo@BM-alpha as efficient electrocatalysts for ammonia synthesis via the enzymatic pathway. The results show that these catalysts can effectively activate nitrogen and suppress hydrogen evolution reaction, making them promising for industrial applications.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2022)
Article
Electrochemistry
Chenyin Li, Xin Liu, Fang Xu, Dandan Wu, Hong Xu, Guohong Fan
Summary: The study designs 36 dual-atom catalysts to break the linear scaling relationship of adsorption energy between reaction intermediates in CO2 electrochemical reduction reaction. After several rounds of screening, Mn2@PC6 catalyst is identified as a promising candidate for deep reduction of CO2 to CH4.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Xin Liu, Chenyin Li, Fang Xu, Dandan Wu, Guohong Fan, Hong Xu
Summary: Electrocatalytic reduction of N2 to NH3 under ambient conditions inspired by biological nitrogen fixation is a promising solution for addressing the current energy shortage crisis. This study investigates the catalytic activity, mechanism, and selectivity of N2 reduction using a-Arsenene catalysts anchored with different transition metal atoms and doped with varying numbers of N atoms. The results demonstrate that reducing the coordination atoms can enhance the catalytic activity and selectivity of the catalyst.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Dandan Wu, Fang Xu, Xin Liu, Chenyin Li, Xiangfeng Chu, Guohong Fan, Hong Xu
Summary: This study explores the adsorption and sensor properties of three atmospheric hazardous gases (CO, NO, and SO2) on pristine and Ni3 cluster-doped arsenene monolayer (Ni3-AS) using density functional theory. The results demonstrate that the pristine arsenene monolayer exhibits superior sensor properties for SO2 gas, and the adsorption performance of arsenene monolayer is significantly improved by introducing Ni3 clusters doping. Arsenene and Ni3-AS are expected to be candidate materials for eliminating these hazardous gases.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2022)
Article
Chemistry, Physical
Fang Xu, Xiaohua Wang, Xin Liu, Chenyin Li, Guohong Fan, Hong Xu
Summary: Graphene-like BC6N monolayers supported with TMN4 (TM = Sc to Zn) centers were studied as efficient CO2RR catalysts. High-throughput screening based on structural stability and reaction pathways identified the most promising catalyst candidates. Different charge coordination environments near the TMN4 centers were found to modulate the catalytic activity of the catalyst.
MOLECULAR CATALYSIS
(2022)
Article
Chemistry, Physical
Fang Xu, Dandan Wu, Zhenzhen Wang, Aling Ma, Fanghui Wu, Hong Xu, Guohong Fan
Summary: In this study, the electrocatalytic performance of several transition metal (TM = Ti, V, Cr, Mn, and Fe) anchored boron co-doped graphyne (GY) for CO2 electrochemical reduction reaction (CRR) was systematically examined by first-principle calculations. The results showed that MnB1@GY exhibited the best CRR performance, with low limit potential and high selectivity for the generation of CH4. The synergistic effect of codoped B and TM atoms in MnB1@GY significantly improved the selectivity by breaking the linear-scaling relation of single atom catalyst.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Dandan Wu, Aling Ma, Zhiyi Liu, Zhenzhen Wang, Fang Xu, Guohong Fan, Hong Xu
Summary: In this study, the adsorption and sensor performance of hazardous gases containing sulfur on pristine and doped NbS2 monolayers were investigated using density functional theory. The results showed that doping with Cr and Mo significantly improved the adsorption performance of NbS2, making it suitable for sensing or eliminating sulfur-containing gases in the atmosphere.
Article
Chemistry, Physical
Dandan Wu, Fang Xu, Aling Ma, Zhenzhen Wang, Fanghui Wu, Guohong Fan, Hong Xu
Summary: The adsorption and sensor performance of H2S gas on pristine, Co and Co2-doped arsenene monolayers were investigated using density functional theory. The study revealed that the pristine arsenene monolayer has poor sensor properties, but after doping with Co metal atoms, the adsorption properties are significantly improved. This study suggests that Co monoatomic doping can enhance the sensing performance of arsenene as a gas sensor, while Co2 diatomic doping can enhance its adsorption properties.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Fang Xu, Zhenzhen Wang, Zhiyi Liu, Aling Ma, Dandan Wu, Fanghui Wu, Hong Xu, Guohong Fan
Summary: In this study, the electrocatalytic properties of transition-metal-anchored Phthalocyanine (Pc) monolayers with different heteroatom modifications were systematically investigated using first-principles calculations. The results showed that certain transition-metal-anchored Pc monolayers exhibited excellent catalytic performance, and choosing appropriate coordination atoms was beneficial for adjusting catalytic activity. The findings provide valuable theoretical guidance for designing efficient carbon dioxide reduction catalysts.
MOLECULAR CATALYSIS
(2023)
Article
Chemistry, Physical
Ming-Yi Chen, Ngoc Thanh Thuy Tran, Ahmed Abubakar Alao, Wen-Dung Hsu
Summary: This study demonstrates the significance of surface Pt atom arrangement for the efficiency of ORR in PEMFCs and reveals the correlation between Pt-Pt average distance and O2 dissociation barrier. Furthermore, the study discovers a robust correlation between the level of the catalyst's d-band center and O2 adsorption energy. High-entropy alloy substrates provide potential for controlling Pt arrangement and O2 dissociation barrier.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Eduardo C. Atayde Jr, Babasaheb M. Matsagar, Yu-Cheng Wang, Kevin C. -W. Wu
Summary: This study presents the first application of an acidic MOF, Sulfated MOF-808, in catalyzing the HAA reactions of furan oligomers for the production of biofuel precursors. The catalyst showed high yield, selectivity, and recyclability, making it versatile for different starting materials.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Maria do Carmo Rangel, Francieli Martins Mayer, Soraia Jesus de Oliveira, Sergio Gustavo Marchetti, Fabricio Luiz Faita, Doris Ruiz, Giovanni Saboia, Mariana Kieling Dagostini, Jonder Morais, Maria do Carmo Martins Alves
Summary: This study developed a new catalyst by investigating the effect of magnesium on the catalytic properties of hematite in ethylbenzene dehydrogenation. The catalyst showed important differences in activity, selectivity, and stability, making it a promising candidate for commercial applications.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yanjun Li, Qian Wang, Hui Tian, Mingyuan Zhu, Yuanyuan Liu
Summary: A novel strategy using microwave-assisted precipitation was proposed to prepare defective CsH3PMo11VO40 catalyst for the oxidation of methacrolein to methacrylic acid. Microwave treatment accelerates crystallization, increases vanadyl species content, and forms defective Keggin structures, thereby enhancing the oxidation capacity of the catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Rajeshwari Athavale, Sailee Gardi, Fatima Choudhary, Dayanand Patil, Nandkishor Chandan, Paresh More
Summary: In this study, a novel acidic ionic liquid catalyst was prepared and used for the synthesis of bis-indolyl methane derivatives. The catalyst exhibited short reaction times, easy purification, and reusability.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Masatomo Hattori, Takato Hattori, Masakuni Ozawa
Summary: Cu-added gamma-Al2O3 catalysts were prepared with varying Cu loadings and the effects of copper oxidation states on catalytic activity were investigated. The results showed that the addition of copper increased the catalyst activity, but excessive copper loading decreased catalytic activity. XRD and TEM analysis indicated the formation of a solid solution of copper oxide species on the surface of gamma-Al2O3. XAS and TPR data demonstrated variations in copper oxidation states among the catalysts.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liwei Fang, Shiyang Niu, Shengsen Wang, Yiqing Lu, Yuanhui Cheng
Summary: In this study, PtNi alloy on nitrogen-doped carbon and SnO2 dual-support was designed to modulate the metal-support interaction, resulting in improved catalytic activity and stability for oxygen reduction reaction. The SnO2/PtNi/NC catalyst exhibited a strongly coupled interface, enhanced electron transfer, and higher half-wave potential compared to PtNi/NC and commercial Pt/C.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Shohei Harada, Duanxing Li, Kenta Iyoki, Masaru Ogura
Summary: This study investigates the catalytic performance of a composite catalyst composed of ZnZrOX and H-zeolite for the hydrogenation of CO2. The deactivation of the composite catalyst is influenced by ion exchange of Zn2+ and/or coke, with their effects differing based on the zeolite structure. Separating the grains of the composite catalyst can prevent deactivation.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Laura Proano, Christopher W. Jones
Summary: In this study, NiGa alloy particles supported on CeO2, ZrO2, and ZrO2-CeO2 solid solutions were prepared and characterized. The nature of the support was found to have a significant influence on the catalyst's activity and selectivity, with the crystalline structure of ZrO2 having the greatest impact. Pure ZrO2 showed the highest methanol selectivity and CO2 conversion at high Zr:Ce ratios. In equimolar and Ce-rich conditions, basic sites and oxygen vacancies were found to be the key parameters affecting methanol production.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liyan Zhang, Yinze Yang, Leilei Zhou, Fengyu Zhao, Haiyang Cheng
Summary: 1,6-Hexamethylenediamine was successfully synthesized via the reductive amination of 1,6-hexanediol using a Ru/PRL(x)-Al2O3 catalyst. The highly dispersed and anchored Ru species, formed by 1,10-phenanthroline (PRL), played a crucial role in the catalytic reaction. The formation of new acid-base pairs, electron deficient Ru species, and smaller nanoparticles contributed to the improved catalytic performances of the Ru/PRL-Al2O3 catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Anita Horvath, Miklos Nemeth, Andrea Beck, Gyorgy Safran, Valeria La Parola, Leonarda Francesca Liotta, Gregor Zerjav, Matevz Roskaric, Albin Pintar
Summary: This study investigates the catalytic and structural changes caused by the addition of 0.25 wt% indium in a 3% Ni/CeO2-Al2O3 catalyst prepared by impregnation method. The results show that the addition of indium can decrease the activity of the catalyst, but it improves its stability and reduces coking.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Ankush Kularkar, Vaibhav Vilas Khedekar, Sachin D. Chaudhari, Mudavath Ravi, Sadhana S. Rayalu, Penumaka Nagababu
Summary: Efficiently addressing the challenges of photocatalytic CO2 reduction to CH3OH is crucial. This study developed Zn-BTC MOF and its composites with CaIn2S4, achieving highly efficient and robust photocatalytic CO2 reduction to CH3OH under ambient conditions, using H2O2 as the hydrogen source. Among the composites, ZMCIS4 demonstrated excellent performance with a CH3OH evolution of 49100 μmol/g.cat and a quantum efficiency of approximately 78.41%. The enhanced performance was attributed to the production of nascent hydrogen atoms (H center dot) through the photo-splitting of H2O2 on the ZMCIS surface.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Dan Liu, Yudong Li, Chengyu Wang, Haiyue Yang, Rong Wang, Shujun Li, Xiaohui Yang
Summary: In this study, a self-supporting three-dimensional porous Co3O4 nanobelt array decorated on nickel foam (P-Co3O4 -NBA@NF) electrode with numerous active sites was successfully constructed for the oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-furan dicarboxylic acid (FDCA). The P-Co3O4 -NBA@NF electrode demonstrated high conversion efficiency, selectivity, and Faraday efficiency, as well as remarkable long-term stability. This research provides a promising electrocatalyst for biomass conversion.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yimin Li, Enggah Kurniawan, Fumiya Sato, Takayoshi Hara, Yasuhiro Yamada, Satoshi Sato
Summary: In this study, several silica-alumina catalysts modified with Ag were examined for the dehydration of 1,3-butanediol to 1,3-butadiene. Among them, an amorphous silica-alumina catalyst (SAL-3) modified with Ag showed the highest improvement in catalytic activity and stability when operated in H2 flow. The generation of reversible acid sites was found to be the reason behind the enhanced activity and stability of this Ag/SAL-3 catalyst. The effects of various parameters on the catalytic activity of Ag/SAL-3, such as reaction temperature, contact time, Ag content, and carrier gas, were investigated.
APPLIED CATALYSIS A-GENERAL
(2024)