Hydrogel Ionic Diodes toward Harvesting Ultralow-Frequency Mechanical Energy

Energy harvesting from human motion is regarded as a promising protocol for powering portable electronics, biomedical devices, and smart objects of the Internet of things. However, state-of-the-art mechanical-energy-harvesting devices generally operate at frequencies (>10 Hz) well beyond human activity frequencies. Here, a hydrogel ionic diode formed by the layered structures of anionic and cationic ionomers in hydrogels is presented. As confirmed by finite element analysis, the underlying mechanism of the hydrogel ionic diode involves the formation of the depletion region by mobile cations and anions and the subsequent increase of the built-in potential across the depletion region in response to mechanical pressure. Owing to the enhanced ionic rectification ratio by the embedded carbon nanotube and silver nanowire electrodes, the hydrogel ionic diode exhibits a power density of approximate to 5 mW cm(-2) and a charge density of approximate to 4 mC cm(-2) at 0.01 Hz, outperforming the current energy-harvesting devices by several orders of magnitude. The applications of the self-powered hydrogel ionic diode to tactile sensing, pressure imaging, and touchpads are demonstrated, with sensing limitation is as low as 0.01 kPa. This work is expected to open up new opportunities for ionic-current-based ionotronics in electronics and energy devices.

Automated summary

The hydrogel ionic diode is a new device that efficiently harvests mechanical energy at low frequencies, with high power density and charge density. It has diverse applications in tactile sensing, pressure imaging, touchpads, and opens up new opportunities for ionotronics in electronics and energy devices.