4.7 Article

Macroporous, Freestanding Birnessite H0.08MnO2•0.7H2O Nanobelts/Carbon Nanotube Membranes for Wearable Zinc-Ion Batteries with Superior Rate Capability and Cyclability

期刊

ACS APPLIED ENERGY MATERIALS
卷 4, 期 4, 页码 4138-4149

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsaem.1c00464

关键词

freestanding membrane; birnessite H0.08MnO2 center dot 0.7H(2)O; macroporous structure; binder-free; aqueous zinc-ion battery

资金

  1. National Natural Science Foundation of China [51872051, 51731004]
  2. Science and Technology Committee of Shanghai Municipality [18520723100]
  3. Fundamental Research Funds for the Central Universities

向作者/读者索取更多资源

This work demonstrates excellent zinc-ion-storage behavior in birnessite H0.08MnO2·0.7H(2)O nanobelts for the first time using a well-designed H0.08MnO2·0.7H(2)O/MWCNT composite membrane. The high aspect ratio of the nanobelts facilitates the formation of macropores inside the membrane, leading to high Zn2+ diffusion coefficient, excellent rate capability, and long-term cyclability for over 1000 cycles at 3.0 A g-1.
Rechargeable aqueous zinc-ion batteries (ZIBs) are regarded as an ideal choice for next-generation energy-storage devices. Nevertheless, the ZIB performance is still far from satisfactory due to the lack of suitable cathode materials. In this work, we demonstrated excellent zinc-ion-storage behavior in proton-type birnessite H0.08MnO2 center dot 0.7H(2)O nanobelts for the first time using a well-designed H0.08MnO2 center dot 0.7H(2)O /MWCNT composite membrane. Interestingly, our H0.08MnO2 center dot 0.7H(2)O nanobelts with a very high aspect ratio (similar to 30) facilitate the formation of abundant macropores of 0.5-5.0 mu m size inside the as-constructed membrane, which provides an effective pathway for liquid electrolyte penetration during the long-term charge/discharge cycling. The resultant H0.08MnO2 center dot 0.7H(2)O/MWCNT composite membrane delivers a high Zn2+ diffusion coefficient of similar to 8.18 x 10(-14) cm(2) s(-1), excellent rate capability, and long-term cyclability over 1000 cycles at 3.0 A g(-1). Our study not only reveals H0.08MnO2 center dot 0.7H(2)O as a robust cathode material for aqueous zinc-ion batteries but also demonstrates a macropore-assisted binder-free strategy to realize next-generation energy-storage devices from layered nanostructures with a high aspect ratio.

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