4.8 Article

Mechanical Manipulation of Silicon-based Schottky Diodes via Flexoelectricity

期刊

NANO ENERGY
卷 83, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.nanoen.2021.105855

关键词

Flexoelectricity; Schottky diode; Schottky barrier height; Rectification

资金

  1. National Natural Science Foundation of China [11972139, 11672265]
  2. Natural Science Foundation of Zhejiang Provincial [LR21A020002]
  3. National Key Research and Development Project [2020YFA0711701]
  4. State Key Laboratory of Mechanics and Control of Mechanical Structures (Nanjing University of Aeronautics and astronautics) [MCMS-E0220K01]

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This study utilizes flexoelectricity to control the performance of silicon-based SBDs, finding significant impact on various performance indicators. Current-voltage characteristics of the SBD under different tip forces were measured using C-AFM, confirming the important role of flexoelectricity.
Silicon-based Schottky barrier diodes (SBDs), as a two-terminal circuit element, are widely used in modern industries due to its low cost and better compatibility with the complementary metal oxide semiconductor (CMOS) technology. Flexoelectricity resulting from strain gradient is a distinctive electromechanical coupling phenomenon compared to piezoelectricity resulting from strain. Flexoelectricity can exist in any dielectric due to the non-uniform strain breaking symmetry of materials. In this paper, we utilize the induced flexoelectric polarization to tune the behavior of a SBD made of metal and p-type Silicon. Making use of conductive atomic force microscopy (C-AFM), we measured current-voltage of the fabricated Si-based SBD under different tip forces. In order to conduct a quantitative study on the tuning effect of flexoelectricity on the performance of the fabricated Si-based SBD, we introduce an effective barrier height and provide a modified current equation according to the classical thermionic emission theory. The results show that flexoelectricity plays a significant role in dictating the Schottky barrier height, maximum rectified current (density), reverse saturation current (density), rectification ratio, and open voltage of the fabricated SBD. In addition, based on the Hertzian contact model and the measured data, the nonzero flexoelectric coefficients of the used p-type silicon are obtained.

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