Catalyst-Controlled Regiodivergent Synthesis of 1- and 3-Thiosugars with High Stereoselectivity and Chemoselectivity

Open-Air Stereoselective Construction of C-Aryl Glycosides

(2020) Mengnan Lai et al.   ORGANIC LETTERS

Synthesis of 3-S- and 3-Se-glycals by using R-S-S-R and R-Se-Se-R as the nucleophile precursors promoted by Hf(OTf)4 and the temperature-dependent formation of the above-mentioned 3-S- and 3-Se products

(2020) Peiran Chen et al.   TETRAHEDRON LETTERS

Direct N-Glycosylation of Amides/Amines with Glycal Donors

(2020) Ying Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Protein S-Glyco-Modification through an Elimination–Addition Mechanism

(2020) Ke Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Automated Solution-Phase Synthesis of S-Glycosides for the Production of Oligomannopyranoside Derivatives

(2020) Mallory K. Kern et al.   ORGANIC LETTERS

Synthesis, Reactivity, and Stereoselectivity of 4-Thiofuranosides

(2019) Jerre M. Madern et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed Asymmetric Reverse Prenylation

(2019) Minghe Sun et al.   ORGANIC LETTERS

Practical Route to Neokotalanol and Its Natural Analogues: Sulfonium Sugars with Antidiabetic Activities

(2019) Yuhao Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

(2019) Koji Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Traceless Photolabile Linker Expedites the Chemical Synthesis of Complex Oligosaccharides by Automated Glycan Assembly

(2019) Kim Le Mai Hoang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes

(2019) Rei Tomifuji et al.   ORGANIC LETTERS

Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination

(2019) Samir Ghorai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Photoredox-Dual-Catalyzed Functionalization of 1-Thiosugars

(2019) Mingxiang Zhu et al.   ORGANIC LETTERS

Discovery of MK-8719, a Potent O-GlcNAcase Inhibitor as a Potential Treatment for Tauopathies

(2019) Harold G. Selnick et al.   JOURNAL OF MEDICINAL CHEMISTRY

A Mechanistic Analysis of the Palladium-Catalyzed Formation of Branched Allylic Amines Reveals the Origin of the Regio- and Enantioselectivity through a Unique Inner-Sphere Pathway

(2019) Lingfei Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodirecting Effect of C5-Carboxylate Substituents on the Glycosylation Stereochemistry of 3-Deoxy-d-manno-oct-2-ulosonic Acid (Kdo) Thioglycoside Donors: Stereoselective Synthesis of α- and β-Kdo Glycosides

(2018) Wei Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Challenges in the Conversion of Manual Processes to Machine-Assisted Syntheses: Activation of Thioglycoside Donors with Aryl(trifluoroethyl)iodonium Triflimide

(2018) Regis C. Saliba et al.   ORGANIC LETTERS

Facile Formation of β-thioGlcNAc Linkages to Thiol-Containing Sugars, Peptides, and Proteins using a Mutant GH20 Hexosaminidase

(2018) Gregor Tegl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoretentive C(sp3)–S Cross-Coupling

(2018) Feng Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Early clindamycin for bacterial vaginosis in pregnancy (PREMEVA): a multicentre, double-blind, randomised controlled trial

(2018) Damien Subtil et al.   LANCET

An efficient approach to chloro(organophosphine) gold(i) complexes for the synthesis of auranofin

(2017) Junchang Wang et al.   GREEN CHEMISTRY

Macrocyclic bis-thioureas catalyze stereospecific glycosylation reactions

(2017) Yongho Park et al.   SCIENCE

A minimalist approach to stereoselective glycosylation with unprotected donors

(2017) Kim Le Mai Hoang et al.   Nature Communications

Total synthesis of mycobacterial arabinogalactan containing 92 monosaccharide units

(2017) Yong Wu et al.   Nature Communications

Catalyst-Controlled Stereoselective O-Glycosylation: Pd(0) vs Pd(II)

(2017) Hui Yao et al.   ACS Catalysis

A Visible-Light-Promoted O -Glycosylation with a Thioglycoside Donor

(2016) Mark L. Spell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Selective Galactose–Coumarin-Derived Galectin-3 Inhibitor Demonstrates Involvement of Galectin-3-glycan Interactions in a Pulmonary Fibrosis Model

(2016) Vishal K. Rajput et al.   JOURNAL OF MEDICINAL CHEMISTRY

Remote Activation of Disarmed Thioglycosides in Latent-Active Glycosylation via Interrupted Pummerer Reaction

(2016) Xiong Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hafnium(IV) triflate as a highly efficient catalyst for Ferrier rearrangement of O- and S-nucleophiles with glycals

(2016) Yonghui Liu et al.   TETRAHEDRON LETTERS

A versatile glycosylation strategy via Au(iii) catalyzed activation of thioglycoside donors

(2016) Amol M. Vibhute et al.   Chemical Science

Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst

(2015) Dragana Stevanović et al.   CARBOHYDRATE RESEARCH

Thioglycosides in Carbohydrate Research

(2015) Gaoyan Lian et al.   CARBOHYDRATE RESEARCH

Ruthenium Catalyzed Stereo/Chemo/Regioselective One-Pot Synthesis of C(2)–C(3) Unsaturated and α-d-Mannopyranosyl Sulfones

(2015) Sravanthi Chittela et al.   JOURNAL OF ORGANIC CHEMISTRY

Metabolic coupling of two small-molecule thiols programs the biosynthesis of lincomycin A

(2015) Qunfei Zhao et al.   NATURE

Stereoselective Synthesis of S-Linked Hexasaccharide of Landomycin A via Umpolung S-Glycosylation

(2015) Kedar N. Baryal et al.   ORGANIC LETTERS

Reversing the Stereoselectivity of a Palladium-Catalyzed O-Glycosylation through an Inner-Sphere or Outer-Sphere Pathway

(2014) Shaohua Xiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Co-opting sulphur-carrier proteins from primary metabolic pathways for 2-thiosugar biosynthesis

(2014) Eita Sasaki et al.   NATURE

Sulforaphane treatment of autism spectrum disorder (ASD)

(2014) K. Singh et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect

(2014) Cheng Hou et al.   ACS Catalysis

Umpolung Reactivity in the Stereoselective Synthesis of S-Linked 2-Deoxyglycosides

(2013) Kedar N. Baryal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Iron Porphyrin/Cyclodextrin Dimer Complex that Mimics the Functions of Hemoglobin and Methemoglobin

(2013) Kenji Watanabe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

β-Type Glycosidic Bond Formation by Palladium-Catalyzed Decarboxylative Allylation

(2013) Shaohua Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in the Ferrier Rearrangement

(2013) Ana M. Gómez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 2-Nitroglycals from Glycals Using the Tetrabutylammonium Nitrate–Trifluoroacetic Anhydride–Triethylamine Reagent System and Base-Catalyzed Ferrier Rearrangement of Acetylated 2-Nitroglycals

(2013) Suresh Dharuman et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Thioglycoside Analogues of Maradolipid

(2013) Xiaojun Zeng et al.   JOURNAL OF ORGANIC CHEMISTRY

Applications of Thiyl Radical Cyclizations for the Synthesis of Thiosugars

(2013) Aoife Malone et al.   ORGANIC LETTERS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Synthesis of 3′-S-Phosphonomethyl-Modified Nucleoside Phosphonates with a 3′-Deoxy-3′-thio-α-L-threosyl Sugar Moiety

(2011) Qiuya Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereoelectronic Factors in the Stereoselective Epoxidation of Glycals and 4-Deoxypentenosides

(2011) Laura Alberch et al.   JOURNAL OF ORGANIC CHEMISTRY

The use of ultrastable Y zeolites in the Ferrier rearrangement of acetylated and benzylated glycals

(2010) Pieter Levecque et al.   GREEN CHEMISTRY

Synthesis and biological activity of naturally occurring α-glucosidase inhibitors

(2010) Duncan J. Wardrop et al.   NATURAL PRODUCT REPORTS

Catalyst-free Efficient Synthesis of 3-Thio-2-deoxysugar Derivatives in Water

(2008) Pintu Kumar Mandal et al.   JOURNAL OF CARBOHYDRATE CHEMISTRY

The First Synthesis of a Thioglycoside Analogue of the Immunostimulant KRN7000

(2008) Ravindra T. Dere et al.   ORGANIC LETTERS